Abstract:
A negative-working imagable composition and element includes an initiator composition, an infrared radiation absorbing compound, a polymeric binder, and a stabilizing composition. The imaged element can be developed on-press and exhibits improved shelf-life under high humidity conditions. The stabilizing composition comprising at least one compound represented by Structure (ST-I) and at least one compound represented by Structure (ST-II): wherein m is 1 or 2, n is 1 to 50, R is hydrogen when m is 1, R1 through R3 are independently hydrogen or methyl, and L is an aliphatic, carbocyclic, heterocyclic, heteroatom divalent linking group, or a combination thereof.
Abstract translation:负性可成像组合物和元素包括引发剂组合物,红外辐射吸收化合物,聚合物粘合剂和稳定化组合物。 成像元件可以在印刷机上显影,并且在高湿度条件下显示改善的保存期限。 所述稳定化组合物包含至少一种由结构(ST-1)表示的化合物和至少一种由结构(ST-II)表示的化合物:其中m为1或2,n为1至50,当m为1时,R为氢 R 1至R 3独立地为氢或甲基,L为脂族,碳环,杂环,杂原子二价连接基团或其组合。
Abstract:
A non-ablative negative-working imageable element has first and second polymeric layers under a crosslinked silicone rubber layer. These elements can be used in a simple method to provide lithographic printing plates useful for waterless printing (no fountain solution). Processing after imaging is relatively simple using either water or an aqueous solution containing very little organic solvent to remove the imaged regions. The crosslinked silicone rubber layer is ink-repelling and only the first layer that is closest to the substrate contains an infrared radiation absorbing compound to provide thermal sensitivity.
Abstract:
A plate-making method of a lithographic printing plate precursor including an image forming layer and a support, includes: (a) a step of preparing a lithographic printing plate precursor containing, in the image forming layer, an infrared absorber, a polymerization initiator, a polymerizable compound, a hydrophobic binder polymer and a compound represented by the formula (1) or (2) as defined herein; (b) a step of imagewise exposing the lithographic printing plate precursor; and (C) a step of developing the exposed lithographic printing plate precursor with an aqueous solution containing at least one water-soluble polymer selected from the group consisting of gum arabic and starch with an automatic processor equipped with a rubbing member.
Abstract:
A lithographic printing plate precursor includes, in the following order: a support; an intermediate layer; and an image-forming layer, and the intermediate layer contains a polymer (A) comprising a repeating unit (a1) represented by the formula (I) as defined herein.
Abstract:
A lithographic printing plate precursor includes a support, an image-recording layer and a protective layer in this order, wherein the protective layer contains a stratiform compound and the image-recording layer contains a polymer compound having a phosphonium structure in a side chain.
Abstract:
The present invention provides a resin composition that includes (A) a polymer compound that has, on a side chain of a main chain polymer, through a linkage group containing a hydrogen-bonding group and a ring structure, a terminal ethylenic unsaturated bond, and is soluble or swelling in water or an alkali aqueous solution, and (B) a compound that generates radicals when exposed to light or heat. The invention further provides a thermo/photosensitive composition that includes (A′) a polymer compound that has a non-acidic hydrogen-bonding group on a side chain and is soluble or swelling in water or an alkali aqueous solution, and (B′) a compound that generates radicals when exposed to light or heat.
Abstract:
A method for preparing a lithographic printing plate includes: exposing imagewise a lithographic printing plate precursor comprising, in the following order, a hydrophilic support, a photosensitive layer containing (A) a sensitizing dye, (B) a polymerization initiator, (C) a polymerizable compound and (D) a binder polymer and a protective layer containing at least one acid-modified polyvinyl alcohol in an amount of 50% by weight or more based on a total solid content of the protective layer; and removing the protective layer and an unexposed area of the photosensitive layer with a developer having pH of from 2 to 8.
Abstract:
Negative lithographic printing plate having on a substrate a photosensitive layer comprising an alkaline soluble polymeric binder, an alkaline insoluble polymeric binder, a polymerizable monomer, and an initiator is described. The photosensitive layer is imagewise exposed with a radiation to cause hardening in the exposed areas, and then developed to remove the non-hardened areas. The combination of both alkaline soluble polymeric binder and alkaline insoluble polymeric hinder in a photosensitive layer can give excellent combined durability, developability, and coatability.
Abstract:
Lithographic printing plates are imaged using an inkjet printer to imagewise apply a chemical or masking agent onto the plate surface. In some embodiments, the chemical causes an affinity change, thereby facilitating lithographic printing.
Abstract:
A polyurethane resin is synthesized from a compound represented by the following Formula (1), a polymerizable composition includes the polyurethane resin, a planographic printing plate precursor includes a photosensitive layer including the composition, and a method produces a diol compound that can be used as a raw material of the polyurethane resin. In Formula (1), R1 and R2 each independently represent a single bond or an alkylene group optionally having a substituent, R3 represents a hydrogen atom or an alkyl group, R4 represents a hydrogen atom or an alkyl group, and A represents a divalent or higher linking group, provided that R1 and R2 are not both a single bond.