公开(公告)号：US10385478B2

公开(公告)日：2019-08-20

申请号：US16094647

申请日：2017-03-20

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Roberto De Palo ,  Claudio Cavalieri

IPC: C08F10/02 ,  C08F10/06 ,  C08F210/02 ,  D01F6/30 ,  C08F210/06 ,  B33Y70/00 ,  B29C64/118 ,  B33Y30/00 ,  B33Y80/00 ,  C08F210/16

Abstract: The present disclosure provides a filament for use in an extrusion-based additive manufacturing system made from or containing a propylene ethylene copolymer having: ethylene derived units content ranging from about 3.0 wt % to about 12.0 wt %, based upon the weight of the propylene ethylene copolymer; MFR L (Melt Flow Rate according to ISO 1133, condition L, at 230° C. and 2.16 kg load) from about 4 to about 20 g/10 min; and xylene solubles measured at 25° C. from about 3 wt % to about 30 wt %, based upon the weight of the propylene ethylene copolymer. The disclosure further provides an extrusion-based additive manufacturing system made from or containing the filament as well as 3D printed articles prepared from the system.

公开(公告)号：US20190232554A1

公开(公告)日：2019-08-01

申请号：US16340958

申请日：2017-09-22

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： ROBERTO DE PALO ,  CLAUDIO CAVALIERI

IPC: B29C64/118 ,  C08L23/16

CPC classification number: B29C64/118 ,  B29C64/106 ,  B29C64/209 ,  B29K2023/16 ,  B33Y10/00 ,  B33Y70/00 ,  C08F210/06 ,  C08L23/10 ,  C08L23/16 ,  C08L2203/12 ,  C08L2207/02 ,  D01F6/30

Abstract: A consumable filament for use in an extrusion-based additive manufacturing system made from or containing a heterophasic propylene ethylene copolymer having a xylene soluble content ranging from 15 wt % to 50 wt % and a melt flow rate MFR L (Melt Flow Rate according to ISO 1133, condition L, i.e. 230° C. and 2.16 kg load) ranging from 0.5 to 100 g/10 min.

公开(公告)号：US10351641B2

公开(公告)日：2019-07-16

申请号：US14899296

申请日：2014-06-10

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Diego Brita ,  Gianni Collina ,  Giampiero Morini

IPC: C08F4/64 ,  C08F10/02 ,  C08F110/06

Abstract: The present technology relates to a pre-polymerized catalyst component for the polymerization of olefins, characterized by a non-stereospecific solid catalyst component comprising Ti, Mg and a halogen and an amount of a (co)polymer of an alpha-olefin CH2═CHR1, where R1 is a C1-C12 hydrocarbon group ranging from 0.1 to 500 g per g of said solid catalyst component. In some embodiments, the (co)polymer is characterized by an isotacticity, expressed in terms isotactic pentads, of higher than 60 molar % and an intrinsic viscosity, measured in tetraline at 135° C., of at least 1.0 dL/g.

公开(公告)号：US10316123B2

公开(公告)日：2019-06-11

申请号：US14896430

申请日：2014-05-06

Applicant: BASELL POLYOLEFINE ITALIA S.R.L.

Inventor： Mara Destro ,  Marco Ciarafoni ,  Paola Massari ,  Stefano Squarzoni ,  Thomas Bohm

IPC: B65D1/02 ,  C08F210/14 ,  C08F210/06 ,  C08F210/16

Abstract: A container comprising a propylene, ethylene, 1-hexene terpolymer wherein: (i) the content of ethylene derived units ranges from 0.2 wt % to 1.0 wt %; (ii) the content of 1-hexene derived units ranges from 3.5 wt % to 5.5 wt %; (iii) the content of ethylene derived units fulfills the following equation (I); C2

公开(公告)号：US10246532B2

公开(公告)日：2019-04-02

申请号：US15557704

申请日：2016-03-08

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Reynald Chevalier ,  Alessandro Mignogna ,  Giampiero Morini

IPC: C08F110/06 ,  C07F7/28

Abstract: A solid catalyst component which exhibits high activity and stereospecificity in the polymerization of olefins made from or containing Mg, Ti and an electron donor of formula (I) where R and R1 are selected from the group consisting of C1-C20 hydrocarbon groups, C6-C14 aryl or alkylaryl groups hydrocarbon groups, optionally containing a heteroatom selected from the group consisting of halogens, P, S, N, and O; R2 to R11 groups, equal to or different from each other, are hydrogen, halogen or C1-C15 hydrocarbon groups which can be optionally fused together to form one or more cycles with the proviso that R6 and R11 cannot join together to form a phenyl ring.

公开(公告)号：US10214625B2

公开(公告)日：2019-02-26

申请号：US15591979

申请日：2017-05-10

Applicant: BASELL POLIOLEFINE ITALIA S.r.l.

Inventor： Giuseppe Ferrara ,  Enrico Costantini ,  Marco Consalvi

IPC: C08K3/26 ,  C08L23/20 ,  C08L51/06

Abstract: A polyolefin nanocomposite material comprising the following components: (A) a crystalline or semi-crystalline polyolefin resin; and (B) a nanosized mineral filler comprising or substantially consisting of a hydrotalcite, wherein the amount of the hydrotalcite is from 0.02 to 6 parts by weight per 100 parts by weight of the nanocomposite material, and the ratio MFR (1)/MFR (2) of the melt flow rate value MFR (1) of component (A) to the melt flow rate value MFR (2) of the polyolefin nanocomposite material is of at least 1.02, charachterized in that the said polyolefin nanocomposite material includes a compatibilizer the dispersion of the mineral filler (B) and compatibilizer in the polyolefin resin is produced at shear mixing rates from 30 to 300 sec−1.

公开(公告)号：US20190055330A1

公开(公告)日：2019-02-21

申请号：US15759143

申请日：2016-08-30

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： FABRIZIO PIEMONTESI ,  GIANNI VITALE ,  DARIO LIGUORI ,  GIAMPIERO MORINI

IPC: C08F10/06

Abstract: A catalyst for the homopolymerization or copolymerization of CH2═CHR olefins, made from or containing the product obtained by contacting: (i) a solid catalyst component made from or containing Ti, Mg, Cl, and an internal electron donor compound, wherein the solid catalyst component contains from about 0.1 to about 50 wt % of Bi, based upon the total weight of the solid catalyst component; (ii) an alkyl aluminum compound and, (iii) an external electron donor compound having the formula: (R1)aSi(OR2)b wherein R1 and R2 are independently selected from the group consisting of alkyl radicals with 1-8 carbon atoms and a is 0 or 1 and a+b=4.

公开(公告)号：US10208135B2

公开(公告)日：2019-02-19

申请号：US15516651

申请日：2015-09-28

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Simona Guidotti ,  Dario Liguori ,  Giampiero Morini

IPC: C08F4/649 ,  C08F4/645 ,  C08F4/642 ,  C08F10/06

Abstract: A catalyst component comprising Ti, Mg, Cl, and an electron donor compound having porosity of at least 0.2 cm3/g and characterized by the fact that it further comprises Cu oxide, with the proviso that when the electron donor compound is selected from esters of phthalic acids, the porosity is of at least 0.45 cm3/g.

公开(公告)号：US10155888B2

公开(公告)日：2018-12-18

申请号：US15400734

申请日：2017-01-06

Applicant: BASELL POLIOLEFINE ITALIA S.R.L.

Inventor： Massimo Covezzi ,  Gabriele Mei ,  Maria Di Diego ,  Piero Gessi ,  Pietro Baita ,  Roberta Pica

IPC: C09J151/06 ,  C08F10/00 ,  C08F110/02 ,  B32B7/12 ,  B32B15/085 ,  B32B27/06 ,  C08L23/06 ,  C08L23/20 ,  C08L51/06 ,  C09J5/02 ,  C09J123/06 ,  C09J123/20

Abstract: The present technology relates to a method of introducing a supported antistatic compound that does not comprise a transition-metal-based catalyst component for use in an olefin polymerization reactor. In some embodiments, the methods disclosed herein avoid the formation of polymer agglomerates in the reactor and minimize potentially negative effects on catalyst yield.

公开(公告)号：US10150828B2

公开(公告)日：2018-12-11

申请号：US12733016

申请日：2008-07-29

Applicant: Claudio Cavalieri ,  Camillo Cagnani ,  Alessandro Guidicini

Inventor： Claudio Cavalieri ,  Camillo Cagnani ,  Alessandro Guidicini

IPC: C08F2/34 ,  C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08F2/00

Abstract: The present invention relates to a process for producing a propylene terpolymer comprising comonomer units derived from ethylene and from one alpha-olefin selected from the group of C4-C8 alpha-olefins and being characterized by a total content of comonomer units not less than 8% wt and a value of the ratio of ethylene to the C4-C8 alpha-olefins ranging from 0.1 to 0.8, said process being carried out in a gas-phase reactor comprising two interconnected polymerization zones.The present invention further relates to the propylene terpolymer obtained by said process particularly suitable to be used as films such as cast films, bi- or mono-oriented films and heat-sealable films having good optical properties and excellent sealing properties combined with good shrinkage properties and softness.