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    Hydroxylamine derivatives which are intermediates for making herbicidal compounds
    31.
    发明授权
    Hydroxylamine derivatives which are intermediates for making herbicidal compounds 失效
    作为制造除草剂化合物的中间体的羟甲基胺衍生物

    公开(公告)号：US5081301A

    公开(公告)日：1992-01-14

    申请号：US429160

    申请日：1989-10-30

    Applicant: Jochen Wild ,  Albrecht Harreus ,  Ulrich Schirmer ,  Norbert Meyer ,  Juergen Kast ,  Dieter Kolassa

    Inventor： Jochen Wild ,  Albrecht Harreus ,  Ulrich Schirmer ,  Norbert Meyer ,  Juergen Kast ,  Dieter Kolassa

    IPC: C07C239/20 ,  C07C323/19 ,  C07D209/48

    CPC classification number: C07D209/48 ,  C07C239/20

    Abstract: Hydroxylamine derivatives have the general formula IAryl--A--O--B IwhereAryl is an unsubstituted or substituted, mononuclear or binuclear, isocyclic radical;A is a 1,4-butenylene group of the general formulae IIa or IIb ##STR1## where R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are each hydrogen, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkenyl;B is NH.sub.2 or a dicarboximide group of the general formula III ##STR2## where Z is unsubstituted or substituted phenylene, naphthylene, pyridinylene, cyclopentylene, cyclohexylene, cyclohexenylene, C.sub.2 -C.sub.4 -alkenylene or C.sub.2 -C.sub.4 -alkylene. The dicarboximides are intermediates for the compounds wherein B is NH.sub.2. The latter are used in synthesizing herbicidal compounds.

    Abstract translation: 羟胺衍生物具有通式I Aryl-A-O-B I，其中芳基是未取代或取代的单核或双核，环状基团; A是通式IIa或IIb的1,4-亚丁烯基IIa其中R 1，R 2，R 3，R 4和R 5各自是氢，卤素，C 1 -C 6烷基或C 1 -C 6 - 烯基; B是NH 2或通式III III的二羧酰亚胺基，其中Z是未取代或取代的亚苯基，亚萘基，亚
    苄基，亚环戊基，亚环己基，亚环己烯基，C 2 -C 4亚烯基或C 2 -C 4亚烷基。 二羧酰亚胺是其中B是NH 2的化合物的中间体。 后者用于合成除草化合物。

    Pyrimido(5,4-e)-as-triazine-5,7(6H,8H)-diones
    34.
    发明授权
    Pyrimido(5,4-e)-as-triazine-5,7(6H,8H)-diones 失效
    嘧啶并（5,4-e）-as-三嗪-5,7（6H，8H） - 二酮

    公开(公告)号：US5069708A

    公开(公告)日：1991-12-03

    申请号：US547160

    申请日：1990-07-03

    Applicant: Norbert Meyer ,  Ulrich Shirmer ,  Peter Plath ,  Bruno Wuerzer ,  Karl-Otto Westphalen

    Inventor： Norbert Meyer ,  Ulrich Shirmer ,  Peter Plath ,  Bruno Wuerzer ,  Karl-Otto Westphalen

    IPC: A01N43/90 ,  C07D487/04

    CPC classification number: A01N43/90

    Abstract: Herbicidal agents containing a pyrimido[5,4-e]-as-triazine-5,7-(6H,8H)-dione Ia ##STR1## (R.sup.1, R.sup.2 .dbd.H, C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -cycloalkyl, C.sub.2 -C.sub.8 -alkenyl, phenyl or benzyl, R.sup.3 .dbd.H, halogen, nitro, C.sub.1 -C.sub.8 -alkyl which may carry up to three further substituents, C.sub.2 -C.sub.6 -alkenyl, phenyl-C.sub.2 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -cycloalkyl which may carry up to 3 C.sub.1 -C.sub.4 -alkyl substituents, a 5- or 6-membered heterocyclic structure where up to 2 of the ring members are O, S or NR.sup.4 ; --CO--R.sup.4 or --CO--O--R.sup.4 ; phenyl or hetaryl, which may carry up to 3 further substituents; or ZR.sup.6 ; R.sup.4 .dbd.H, C.sub.1 -C.sub.6 -alkyl; Z.dbd.O, S or --N(R.sup.7)--; R.sup.6 .dbd.H, C.sub.1 -C.sub.6 -alkyl, phenyl or benzyl, which may carry up to 3 further substituents; R.sup.7 .dbd.H, C.sub.1 -C.sub.6 -alkyl or R.sup.6 and R.sup.7 together with nitrogen form a 5- or 6-membered ring which may contain O; n=0 or 1) or a salt of Ia with a mineral acid.

    Abstract translation: 含有嘧啶并[5,4-e] -as-三嗪-5,7-（6H，8H） - 二酮Ia（Ia）（R1，R2 = H，C1-C6-烷基，C3- C 2 -C 6环烷基，C 2 -C 8 - 烯基，苯基或苄基，R 3 = H，卤素，硝基，可带有至多三个其它取代基的C 1 -C 8烷基，C 2 -C 6 - 链烯基，苯基-C 2 -C 6 - 烯基， 可含有3个C 1 -C 4烷基取代基的C 3 -C 6环烷基，其中至多2个环成员为O，S或NR 4的5或6元杂环结构; -CO-R 4或-CO- R 4 = H，C 1 -C 6 - 烷基; Z = O，S或-N（R 7） - ; R 6 = H，C 1 -C 6烷基; - 烷基，苯基或苄基，其可以带有多达3个其它取代基; R 7 = H，C 1 -C 6 - 烷基或者R 6和R 7与氮一起形成5-或6-元环，其可以含有O; n = 0或 1）或Ia与无机酸的盐。

    N-substituted 3,4,5,6-tetrahydrophthalimides and their intermediates
    35.
    发明授权
    N-substituted 3,4,5,6-tetrahydrophthalimides and their intermediates 失效
    N-取代的3,4,5,6-四氢去唾液酸及其中间体

    公开(公告)号：US5062884A

    公开(公告)日：1991-11-05

    申请号：US463817

    申请日：1990-01-16

    Applicant: Peter Plath ,  Karl Eicken ,  Norbert Goetz ,  Jochen Wild ,  Norbert Meyer ,  Bruno Wuerzer

    Inventor： Peter Plath ,  Karl Eicken ,  Norbert Goetz ,  Jochen Wild ,  Norbert Meyer ,  Bruno Wuerzer

    IPC: A01N37/10 ,  A01N37/18 ,  A01N37/32 ,  A01N37/46 ,  A01N43/36 ,  A01N43/38 ,  C07C201/12 ,  C07C205/07 ,  C07C205/44 ,  C07C205/56 ,  C07C227/04 ,  C07C229/36 ,  C07C229/40 ,  C07C231/12 ,  C07C233/05 ,  C07C233/65 ,  C07C237/30 ,  C07C255/32 ,  C07C255/34 ,  C07C255/41 ,  C07D209/48

    CPC classification number: C07D209/48 ,  A01N37/46 ,  C07C205/44 ,  C07C205/56 ,  C07C255/00

    Abstract: N-substituted 3,4,5,6-tetrahydrophthalimides and their intermediates of the general formula I ##STR1## where A is --NO.sub.2, --NH.sub.2 or ##STR2## corresponding to the compounds Ia, Ib and Ic, B is --CH.sub.2 --, --CH.sub.2 --CHR.sup.1 --, --CH.sub.2 --CHR.sup.1 --CH.sub.2 --, --CH.dbd., --CH.dbd.CR.sup.1 -- or --CH.dbd.CR.sup.1 --CH.dbd., R.sup.1 being --H, --Cl, --Br or --CH.sub.3, D is ##STR3## depending on the terminal group B, X is --H, --Cl or --Br, Y is --H, C.sub.1 -C.sub.7 --alkyl, --Cl, --Br, --CN, --CONH.sub.2 --CO.sub.2 R.sup.2, where R.sup.2 is H, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -- or C.sub.6 -cycloalkyl, C.sub.1 -C.sub.4 -alkoxy-C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkylmercapto-C.sub.2 -C.sub.4 -alkyl, propargyl, benzyl, .alpha.-phenylethyl, .alpha.-phenylpropyl, C.sub.2 -C.sub.4 -alkyl which is monosubstituted, disubstituted or trisubstituted by F or Cl, or CH.sub.3 -substituted or Cl-substituted allyl, and Z is --COOR.sup.2, --CONR.sup.3 R.sup.4, ##STR4## where R.sup.3 and R.sup.4 are each H or C.sub.1 -C.sub.4 -alkyl or together form a 5-membered or 6-membered cycloaliphatic ring whose carbon chain may be interrupted by an oxygen atom.

    Abstract translation: B）是N-取代的3,4,5,6-四氢邻苯二甲酰亚胺及其中间体，其中A是与化合物Ia，Ib和Ic相对应的-NO 2，-NH 2或 -CH 2 - ， - CH 2 -CHR 2 - ， - CH =， - CH = CR 1或-CH = CR 1 -CH =，R 1是-H，-Cl，-Br或-CH 3， D是取代基末端基团B，X是-H，-Cl或-Br，Y是-H，C 1 -C 7 - 烷基，-Cl，-Br，-CN，-CONH 2 -CO 2 R 2，其中R 2 是C 1 -C 6烷基，C 5 - 或C 6 - 环烷基，C 1 -C 4 - 烷氧基-C 1 -C 4烷基，C 1 -C 4烷基巯基-C 2 -C 4 - 烷基，炔丙基，苄基，α-苯乙基，α- 苯基丙基，被F或Cl单取代或三取代的C 2 -C 4 - 烷基，Z是-COOR 2，-CONR 3 R 4，其中R 3和R 4各自为H或C 1 -C 1-4 - 烷基或一起形成其碳链可以被氧原子间隔开的5元或6元环脂族环。

    3-phenylpropionic acid derivatives
    36.
    发明授权
    3-phenylpropionic acid derivatives 失效
    3-苯基丙酸衍生物

    公开(公告)号：US5013354A

    公开(公告)日：1991-05-07

    申请号：US217167

    申请日：1988-07-11

    Applicant: Barbara Schwalge ,  Peter Plath ,  Karl Eicken ,  Norbert Meyer ,  Bruno Wuerzer

    Inventor： Barbara Schwalge ,  Peter Plath ,  Karl Eicken ,  Norbert Meyer ,  Bruno Wuerzer

    IPC: A01N37/32 ,  A01N37/36 ,  A01N37/42 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N53/00 ,  C07D209/48

    CPC classification number: C07D209/48 ,  A01N37/32 ,  A01N37/36 ,  A01N37/42 ,  A01N43/08 ,  A01N43/10 ,  A01N43/16 ,  A01N43/18 ,  A01N53/00

    Abstract: 3-phenylpropionic acid derivatives of the general formula I ##STR1## where R.sup.1 is hydrogen or halogen, R.sup.2 is halogen, R.sup.3 is unsubstituted or halogen-, C.sub.1 -C.sub.4 -alkoxy- or C.sub.1 -C.sub.4 -alkylthio-substituted C.sub.2 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl-substituted C.sub.1 -C.sub.6 -alkyl, further C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl or, together with R.sup.4, a C.sub.2 -C.sub.4 -alkylene chain, R.sup.4 is hydrogen or unsubstituted or halogen-, C.sub.1 -C.sub.4 -alkoxy-, C.sub.1 -C.sub.4 -alkylthio- or C.sub.5 -C.sub.7 -cycloalkyl-substituted C.sub.1 -C.sub.6 -alkyl; C.sub.3 -C.sub.7 -cycloalkyl; unsubstituted or halogen-substituted C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl or halogen or R.sup.4, together with R.sup.5 and the carbon atom of this substituent, is C.sub.3 -C.sub.6 -cycloalkyl which may be interrupted by an oxygen or a sulfur atom, R.sup.5 is unsubstituted C.sub.1 -C.sub.6 -alkyl or halogen-, C.sub.1 -C.sub.4 -alkoxy- or C.sub. 1 -C.sub.4 -alkylthio-substituted C.sub.2 -C.sub.6 -alkyl; cyano or acyl (COR.sup.6) or alkoxycarbonyl (CO.sub.2 R.sup.7), R.sup.6 denoting C.sub.1 -C.sub.6 -alkyl or, together with R.sup.4, a C.sub.3 -C.sub.5 -alkylene chain and R.sup.7 denoting unsubstituted or halogen-, C.sub.1 -C.sub.4 -alkoxy- or C.sub.1 -C.sub.4 -alkylthio-substituted C.sub.2 -C.sub.6 -alkyl or unsubstituted or C.sub.5 -C.sub.7 -cycloalkyl-substituted C.sub.1 -C.sub.6 -alkyl, further C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, with the proviso that R.sup.1 and R.sup.4 do not simultaneously denote hydrogen when R.sup.5 is cyano or CO.sub.2 R.sup.7, processes for their manufacture, and their use as herbicides.

    Abstract translation: 其中R 1是氢或卤素，R 2是卤素，R 3是未取代的或卤素，C 1 -C 4 - 烷氧基 - 或C 1 -C 4 - 烷硫基取代的C 2 -C 6 - 烷基，C 5 -C 7 - 环烷基取代的C 1 -C 6 - 烷基，另外的C 5 -C 7 - 环烷基，C 3 -C 6 - 烯基或C 3 -C 6 - 炔基，或与R 4一起形成C 2 -C 4亚烷基链，R 4是氢 或未取代的或卤素，C 1 -C 4 - 烷氧基 - ，C 1 -C 4 - 烷硫基 - 或C 5 -C 7 - 环烷基取代的C 1 -C 6 - 烷基; C 3 -C 7 - 环烷基; 未取代的或卤素取代的C 3 -C 6 - 烯基或C 3 -C 6 - 炔基或卤素或R 4与R 5和该取代基的碳原子一起是可被氧或硫原子间隔的C 3 -C 6 - 环烷基， R 5是未取代的C 1 -C 6烷基或卤素，C 1 -C 4 - 烷氧基 - 或C 1 -C 4 - 烷硫基取代的C 2 -C 6 - 烷基; 氰基或酰基（COR 6）或烷氧基羰基（CO 2 R 7），R 6表示C 1 -C 6 - 烷基或与R 4一起为C 3 -C 5亚烷基链，R 7表示未取代或卤素，C 1 -C 4 - 烷氧基 - 或C 1 -C 4 - 烷硫基取代的C 2 -C 6 - 烷基或未取代的C 5 -C 7环烷基取代的C 1 -C 6烷基，另外C 5 -C 7 - 环烷基，C 3 -C 6 - 烯基或C 3 -C 6炔基，条件是R 1和 当R 5为氰基或CO 2 R 7时，R 4不同时表示氢，其制备方法及其作为除草剂的用途。

    Substituted N-phenylpyridazone derivatives
    39.
    发明授权
    Substituted N-phenylpyridazone derivatives 失效
    取代的N-苯基哒嗪酮衍生物

    公开(公告)号：US4844729A

    公开(公告)日：1989-07-04

    申请号：US54994

    申请日：1987-05-28

    Applicant: Rainer Becker ,  Ulrich Wriede ,  Ulrich Schirmer ,  Adolf Parg ,  Bruno Wuerzer ,  Norbert Meyer

    Inventor： Rainer Becker ,  Ulrich Wriede ,  Ulrich Schirmer ,  Adolf Parg ,  Bruno Wuerzer ,  Norbert Meyer

    IPC: A01N43/58 ,  C07D237/14 ,  C07D237/16

    CPC classification number: A01N43/58 ,  C07D237/14

    Abstract: Substituted N-phenylpyridazone derivatives of the general formula I ##STR1## where R.sup.1, R.sup.2 and R.sup.3 are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, halogen, cyano, phenyl, phenoxy, or phenylthio and Z is a straight-chain, saturated alkylene group of 1 to 5 carbon atoms, herbicides containing these compounds, and a process for combating the growth of unwanted plants.

    Abstract translation: 取代的通式I（I）的N-苯基哒嗪酮衍生物其中R 1，R 2和R 3各自为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 卤代烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 卤代烷氧基， C 1 -C 4烷硫基，C 1 -C 4卤代烷硫基，C 1 -C 4烷基亚磺酰基，C 1 -C 4烷基磺酰基，卤素，氰基，苯基，苯氧基或苯硫基，Z为1至5个碳的直链饱和亚烷基 原子，含有这些化合物的除草剂，以及防治不需要的植物生长的方法。

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