Radically coupled resins and methods of making and using same

    公开(公告)号:US10577440B2

    公开(公告)日:2020-03-03

    申请号:US14933847

    申请日:2015-11-05

    Abstract: A radically coupled polymer having a density of from about 0.915 g/ml to about 0.975 g/ml characterized by a crossover modulus measured in Pascals (Pa) that is equal to or less than ymn where ymn=180,000e−0.15x and x is the number average molecular weight of the radically coupled polymer divided by 1,000. An ethylene polymer having a level of short chain branching ranging from about 0 to about 10 mol. %; a level of long chain branching ranging from about 0.001 LCB/103 carbons to about 1.5 LCB/103 carbons as determined by SEC-MALS; and characterized by a crossover modulus measured in Pa that is equal to or less than ymn where ymn=180,000−0.15x and x is the number average molecular weight of the radically coupled polymer divided by 1,000.

    METHODS OF PREPARING A CATALYST
    32.
    发明申请

    公开(公告)号:US20200010587A1

    公开(公告)日:2020-01-09

    申请号:US16571281

    申请日:2019-09-16

    Abstract: A method of preparing a catalyst comprising a) contacting a non-aqueous solvent, a carboxylic acid, and a chromium-containing compound to form an acidic mixture; b) contacting a titanium-containing compound with the acidic mixture to form a titanium treatment solution; c) contacting a pre-formed silica-support comprising from about 0.1 wt. % to about 20 wt. % water with the titanium treatment solution to form a pre-catalyst; and d) thermally treating the pre-catalyst to form the catalyst. A method of preparing a catalyst comprising a) contacting a non-aqueous solvent and a carboxylic acid to form an acidic mixture; b) contacting a titanium-containing compound with the acidic mixture to form a titanium treatment solution; c) contacting a pre-formed chrominated silica-support comprising from about 0.1 wt. % to about 20 wt. % water with the titanium treatment solution to form a pre-catalyst; and d) thermally treating the pre-catalyst to form the catalyst.

    Methods of preparing a catalyst
    33.
    发明授权

    公开(公告)号:US10513570B2

    公开(公告)日:2019-12-24

    申请号:US15816145

    申请日:2017-11-17

    Abstract: A method of preparing a catalyst comprising a) contacting a non-aqueous solvent, a carboxylic acid, and a chromium-containing compound to form an acidic mixture; b) contacting a titanium-containing compound with the acidic mixture to form a titanium treatment solution; c) contacting a pre-formed silica-support comprising from about 0.1 wt. % to about 20 wt. % water with the titanium treatment solution to form a pre-catalyst; and d) thermally treating the pre-catalyst to form the catalyst. A method of preparing a catalyst comprising a) contacting a non-aqueous solvent and a carboxylic acid to form an acidic mixture; b) contacting a titanium-containing compound with the acidic mixture to form a titanium treatment solution; c) contacting a pre-formed chrominated silica-support comprising from about 0.1 wt. % to about 20 wt. % water with the titanium treatment solution to form a pre-catalyst; and d) thermally treating the pre-catalyst to form the catalyst.

    Methods of preparing a catalyst
    40.
    发明授权

    公开(公告)号:US09988468B2

    公开(公告)日:2018-06-05

    申请号:US15281538

    申请日:2016-09-30

    Abstract: A method of preparing a catalyst comprising a) contacting (i) a silica-support, (ii) an oxotitanium compound, (iii) a chromium-containing compound, and (iv) an optional solvent to form a first aqueous mixture comprising a pre-catalyst and a reaction media having from about 1 wt. % to about 99 wt. % water; b) thermally treating the pre-catalyst by heating to a temperature of from about 400° C. to about 1000° C. for a time period of from about 1 minute to about 24 hours to form the catalyst. A method of preparing a catalyst comprising contacting a hydrated support material comprising silica with a chromium-containing compound to form a first aqueous mixture comprising a chrominated support; contacting the first aqueous mixture comprising a chrominated support with a solution comprising (i) a solvent and (ii) an oxotitanium compound to form a second aqueous mixture comprising a pre-catalyst; and thermally treating the pre-catalyst to form the catalyst.

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