PROCESSES FOR CATALYZED RING-OPENING OF CYCLOPARAFFINS

    公开(公告)号:US20220213394A1

    公开(公告)日:2022-07-07

    申请号:US17528516

    申请日:2021-11-17

    Abstract: Embodiments of the disclosure include processes for selective ring-opening of cycloparaffins in hydrocarbon feeds to produce hydrocracked cycloparaffins. In particular, the process comprises contacting a hydrocarbon feed comprising cycloparaffins with hydrogen and a catalyst comprising an unsulfided, low-acidity, metal-containing zeolite under hydrocracking conditions; wherein the metal is selected from the group consisting of platinum, nickel, rhodium and mixtures thereof. The processes are useful for upgrading petroleum streams to lubricant base stocks.

    Molecular sieve SSZ-114, its synthesis and use

    公开(公告)号:US10913659B1

    公开(公告)日:2021-02-09

    申请号:US16908804

    申请日:2020-06-23

    Abstract: A novel synthetic crystalline aluminogermanosilicate molecular sieve material, designated SSZ-114, is provided. SSZ-114 can be synthesized by treating an aluminogermanosilicate molecular sieve of CTH framework topology with water or an aqueous solution of a mineral acid under conditions sufficient to degermanate at least a portion of aluminogermanosilicate molecular sieve to form a degermanated molecular sieve and calcining the degermanated molecular sieve under conditions sufficient to convert the degermanated molecular sieve to SSZ-114. Molecular sieve SSZ-114 may be used in organic compound conversion reactions and/or sorptive processes.

    Alkylation reaction using delaminated zeolite supports as catalysts

    公开(公告)号:US10253270B2

    公开(公告)日:2019-04-09

    申请号:US14919626

    申请日:2015-10-21

    Abstract: Provided is an improved alkylation process using a delaminated SSZ-70 catalyst. The process comprises contacting a hydrocarbon feedstock comprising olefins and isoparaffins with a catalyst comprising delaminated SSZ-70 under alkylating reaction conditions. The delaminated SSZ-70 offers a zeolite layer with a single unit cell of thickness in one dimension, allowing an elimination of mass transfer in comparison with regular SSZ-70. This prevents coke formation inside zeolite channels and improves catalyst stability.

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