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公开(公告)号:US20190224655A1
公开(公告)日:2019-07-25
申请号:US16252779
申请日:2019-01-21
Applicant: Chevron U.S.A. Inc.
Inventor: Stacey Ian Zones , Tracy Margaret Davis , Dan Xie , Cong-Yan Chen , Howard Steven Lacheen
IPC: B01J29/70 , B01J20/18 , B01J20/30 , B01J37/00 , B01J37/03 , B01J35/10 , B01J20/28 , C01B39/48 , C07C5/27
CPC classification number: B01J29/70 , B01J20/18 , B01J20/28061 , B01J20/28071 , B01J20/3057 , B01J20/3085 , B01J35/1019 , B01J35/1038 , B01J37/0018 , B01J37/031 , C01B39/48 , C01P2002/72 , C07C5/2708 , C07C2529/70
Abstract: An aluminosilicate molecular sieve of STW framework type, designated herein as SSZ-110, and having a molar ratio of SiO2/Al2O3 of less than 100, is provided. SSZ-110 may be synthesized using an organic structure directing agent selected from one or more of 1,4-bis(2,3-dimethyl-1H-imidazolium)butane dications, 1,5-bis(2,3-dimethyl-1H-imidazolium)pentane dications, and 1,6-bis(2,3-dimethyl-1H-imidazolium)hexane dications. SSZ-110 may be used in organic compound conversion reactions and sorptive processes.
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公开(公告)号:US10010877B2
公开(公告)日:2018-07-03
申请号:US15182093
申请日:2016-06-14
Applicant: Chevron U.S.A. Inc.
Inventor: Kandaswamy Jothimurugesan , Howard Steven Lacheen , Mark Muraoka
IPC: B01J21/02 , B01J21/04 , B01J23/75 , B01J27/198 , B01J35/02 , C10G2/00 , B01J37/08 , B01J37/16 , B01J37/02
CPC classification number: B01J27/198 , B01J21/04 , B01J23/22 , B01J23/75 , B01J23/83 , B01J23/8472 , B01J27/1853 , B01J35/006 , B01J35/1014 , B01J35/1019 , B01J35/1038 , B01J35/1042 , B01J35/1061 , B01J37/0203 , B01J37/16 , C10G2/333
Abstract: A process has been developed for preparing a Fischer-Tropsch catalyst precursor and a Fischer-Tropsch catalyst made from the precursor. The process includes preparing a catalyst precursor by contacting a boehmite material with a stabilizer containing vanadium-phosphorus. The boehmite material includes two or more different crystalline boehmites having the same average crystallite size to the nearest whole nanometer and having differing properties selected from surface area, pore volume, density and combinations thereof. The boehmite material is subjected to at least one heat treatment at a temperature of at least 500° C., either before or after the contacting step to obtain a stabilized catalyst support having a pore volume of at least 0.3 cc/g. A catalytic metal or a compound containing cobalt is applied to the stabilized catalyst support to form the catalyst precursor. Finally, the catalyst precursor is reduced to activate the catalyst precursor to obtain the Fischer Tropsch catalyst. The catalyst has enhanced hydrothermal stability as measured by losing no more than 6% of its pore volume when exposed to water vapor.
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公开(公告)号:US09687826B2
公开(公告)日:2017-06-27
申请号:US14961998
申请日:2015-12-08
Applicant: Chevron U.S.A. Inc.
Inventor: Kandaswamy Jothimurugesan , Howard Steven Lacheen
CPC classification number: B01J27/198 , B01J21/04 , B01J35/002 , B01J35/0053 , B01J35/023 , B01J35/1038 , B01J37/0203 , B01J37/0207 , B01J37/0236 , B01J37/024 , B01J37/0244 , B01J37/08 , B01J37/18 , C10G2/332
Abstract: Provided is a Fischer Tropsch catalyst prepared according to a process comprising: a. preparing a catalyst precursor by: i. impregnating an alumina catalyst support material with a first solution comprising ammonium metavanadate and phosphoric acid, to obtain a treated catalyst support material; ii. calcining the treated catalyst support material at a temperature of at least 500° C. to obtain a modified catalyst support having a modified support surface area and a pore volume of at least 0.4 cc/g; wherein the modified catalyst support loses no more than 8% of the pore volume when exposed to a water vapor; and iii. contacting the modified catalyst support with a second solution comprising a precursor compound of an active cobalt catalyst component and glutaric acid to obtain the catalyst precursor; and b. reducing the catalyst precursor to activate the catalyst precursor to obtain the Fischer Tropsch catalyst.
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公开(公告)号:US10589260B2
公开(公告)日:2020-03-17
申请号:US16252779
申请日:2019-01-21
Applicant: Chevron U.S.A. Inc.
Inventor: Stacey Ian Zones , Tracy Margaret Davis , Dan Xie , Cong-Yan Chen , Howard Steven Lacheen
IPC: C01B39/48 , B01J20/18 , B01J29/70 , B01J20/30 , B01J37/00 , B01J37/03 , B01J35/10 , B01J20/28 , C07C5/27
Abstract: An aluminosilicate molecular sieve of STW framework type, designated herein as SSZ-110, and having a molar ratio of SiO2/Al2O3 of less than 100, is provided. SSZ-110 may be synthesized using an organic structure directing agent selected from one or more of 1,4-bis(2,3-dimethyl-1H-imidazolium)butane dications, 1,5-bis(2,3-dimethyl-1H-imidazolium)pentane dications, and 1,6-bis(2,3-dimethyl-1H-imidazolium)hexane dications. SSZ-110 may be used in organic compound conversion reactions and sorptive processes.
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公开(公告)号:US10167200B2
公开(公告)日:2019-01-01
申请号:US15729707
申请日:2017-10-11
Applicant: Chevron U.S.A. Inc.
Inventor: Stacey Ian Zones , Cong-Yan Chen , Howard Steven Lacheen , Kaustav Chaudhuri
Abstract: A method is disclosed for synthesizing zincoaluminosilicate molecular sieve SSZ-41 having high aluminum content from a combined source of silicon oxide and aluminum oxide selected from one or more a FAU framework type zeolite and a colloidal aluminosilicate.
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公开(公告)号:US10113963B1
公开(公告)日:2018-10-30
申请号:US16018143
申请日:2018-06-26
Applicant: Chevron U.S.A. Inc.
Inventor: Huping Luo , Hye-Kyung Cho Timken , Toni Zhang Miao , Howard Steven Lacheen , Bi-Zeng Zhan
IPC: G01J3/00 , G01N21/552 , G01N21/3577 , G01N1/34 , G01N21/15 , G01N21/35
Abstract: An integrated system for monitoring a chemical concentration in an ionic liquid, comprising: a. an online FTIR instrument with an ATR window; b. a sample conditioning station that removes light hydrocarbons and produces a degassed ionic liquid that is analyzed by FTIR; and c. a solvent flushing system that flows solvent across the ATR window. Also, a process for monitoring the chemical concentration, comprising: a. degassing the ionic liquid in the sample conditioning station; b. passing the degassed ionic liquid over an ATR window; c. periodically redirecting a flow of the degassed ionic liquid via a bypass line or an on-off valve that isolates the ATR window from the process unit that elutes the ionic liquid; and d. flowing a solvent and a purging gas over the ATR window during the periodically redirecting step c); and e. resuming the passing of the degassed ionic liquid over the ATR window.
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公开(公告)号:US20180162738A1
公开(公告)日:2018-06-14
申请号:US15729707
申请日:2017-10-11
Applicant: Chevron U.S.A. Inc.
Inventor: Stacey Ian Zones , Cong-Yan Chen , Howard Steven Lacheen , Kaustav Chaudhuri
CPC classification number: C01B39/48 , B01J29/048 , B01J29/74 , B01J37/0018 , B01J37/04 , B01J37/30 , B01J2229/183 , C01B39/026 , C07C5/2724 , C07C2523/44
Abstract: A method is disclosed for synthesizing zincoaluminosilicate molecular sieve SSZ-41 having high aluminum content from a combined source of silicon oxide and aluminum oxide selected from one or more a FAU framework type zeolite and a colloidal aluminosilicate.
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公开(公告)号:US11753355B2
公开(公告)日:2023-09-12
申请号:US16862813
申请日:2020-04-30
Applicant: Chevron U.S.A. Inc.
Inventor: Howard Steven Lacheen , Hye-Kyung Cho Timken
IPC: C07C2/12 , B01J20/10 , B01J20/28 , B01J27/125 , B01J31/02 , C10G7/00 , C10G7/06 , C10G25/00 , C10G50/02 , C10G69/12
CPC classification number: C07C2/12 , B01J20/103 , B01J20/28061 , B01J20/28071 , B01J20/28083 , B01J27/125 , B01J31/0284 , C10G7/003 , C10G7/06 , C10G25/003 , C10G50/02 , C10G69/126 , C10G2300/302 , C10G2300/304 , C10G2300/70
Abstract: Described herein is a base oil synthesis via ionic catalyst oligomerization further utilizing a hydrophobic process for removing an ionic catalyst from a reaction mixture with a silica gel composition, specifically a reaction mixture comprising an oligomerization reaction to produce PAO utilizing an ionic catalyst wherein the ionic catalyst is removed post reaction.
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公开(公告)号:US10913659B1
公开(公告)日:2021-02-09
申请号:US16908804
申请日:2020-06-23
Applicant: CHEVRON U.S.A. INC.
Inventor: Christopher Michael Lew , Stacey Ian Zones , Dan Xie , Howard Steven Lacheen , Tao Wei
Abstract: A novel synthetic crystalline aluminogermanosilicate molecular sieve material, designated SSZ-114, is provided. SSZ-114 can be synthesized by treating an aluminogermanosilicate molecular sieve of CTH framework topology with water or an aqueous solution of a mineral acid under conditions sufficient to degermanate at least a portion of aluminogermanosilicate molecular sieve to form a degermanated molecular sieve and calcining the degermanated molecular sieve under conditions sufficient to convert the degermanated molecular sieve to SSZ-114. Molecular sieve SSZ-114 may be used in organic compound conversion reactions and/or sorptive processes.
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公开(公告)号:US20200171471A1
公开(公告)日:2020-06-04
申请号:US16775760
申请日:2020-01-29
Applicant: Chevron U.S.A. Inc.
Inventor: Stacey Ian Zones , Tracy Margaret Davis , Dan Xie , Cong-Yan Chen , Howard Steven Lacheen
IPC: B01J29/70 , B01J35/10 , C07C5/27 , C01B39/48 , B01J20/28 , B01J37/03 , B01J37/00 , B01J20/30 , B01J20/18
Abstract: An aluminosilicate molecular sieve of STW framework type, designated herein as SSZ-110, and having a molar ratio of SiO2/Al2O3 of less than 100, is provided. SSZ-110 may be synthesized using an organic structure directing agent selected from one or more of 1,4-bis(2,3-dimethyl-1H-imidazolium)butane dications, 1,5-bis(2,3-dimethyl-1H-imidazolium)pentane dications, and 1,6-bis(2,3-dimethyl-1H-imidazolium)hexane dications. SSZ-110 may be used in organic compound conversion reactions and sorptive processes.
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