Ethylene/propylene/nonconjugated diene interpolymer composition

    公开(公告)号:US12098268B2

    公开(公告)日:2024-09-24

    申请号:US17607530

    申请日:2019-04-30

    CPC classification number: C08L23/16

    Abstract: The present disclosure provides a composition. In an embodiment, the composition includes a neat ethylene/propylene/nonconjugated polyene interpolymer. The neat ethylene/propylene/nonconjugated polyene interpolymer includes from greater than 0 wt % to 6.0 wt % nonconjugated polyene. The neat ethylene/propylene/nonconjugated polyene interpolymer has the following properties: (i) a molecular weight (Mw) from 240,000 to 270,000; (ii) a Mooney viscosity (ML (1+4), 125° C.) from 80 to 85; (iii) a rheology ratio (RR) from 35 to 65; (iv) a Mw/Mn from 2.2 to 3.5; (v) a tan delta ratio from 0.6 to 0.9; and (vi) an absolute tan delta slope from 5.0 to less than 10.0.

    OIL-EXTENDED PELLET FORM ETHYLENE ALPHA-OLEFIN DIENE INTERPOLYMERS FOR THERMOPLASTIC VULCANIZATES

    公开(公告)号:US20220169841A1

    公开(公告)日:2022-06-02

    申请号:US17599964

    申请日:2019-03-29

    Abstract: Polymer compositions include an interpolymer of ethylene, an α-olefin, and a nonconjugated polyene; and from 10% to 40% by weight oil. The polymer composition has a Mooney viscosity from 20 to 70. The interpolymer may include from 66% to 75% by weight monomer units derived from ethylene; and from 0.5% to 10% by weight monomer units derived from the nonconjugated polyene. The neat interpolymer may have: a weight-average molecular weight Mw from 250 kDa to 300 kDa; a Mooney viscosity from 50 to 200; a rheology ratio V0.1/V100 less than 30; a ratio of molecular weight to low-shear viscosity Mw/V0.1 greater than 4.0; a polydispersity index from 2.0 to 3.5; and a tan δ at 0.1 rad/sand 190° C. greater than 2.0. The polymer compositions may be in the form of pellets having desirable flow characteristics. Thermoplastic vulcanizates may include the polymer compositions. Articles may include the thermoplastic vulcanizates.

    Ethylene/alpha-olefin/nonconjugated polyene based compositions for thermoplastic vulcanizates

    公开(公告)号:US10370524B2

    公开(公告)日:2019-08-06

    申请号:US14411453

    申请日:2013-03-15

    Abstract: The invention provides a composition comprising at least the following components: A) an ethylene/α-olefin/nonconjugated polyene interpolymer that has the following properties: i) a rheology ratio (V0.1/V100 at 190° C.) greater than, or equal to, 35; ii) a weight average molecular weight (Mw) greater than, or equal to, 200,000 g/mol; and iii) a CCDB (Chemical Composition Distribution Breadth) less than 7; B) a thermoplastic polymer; C) a vulcanization agent; and wherein the interpolymer comprises incorporated oil. The invention also provides a composition comprising the following: A) a first composition comprising: a) a first ethylene/α-olefin/nonconjugated polyene interpolymer; b) a second ethylene/α-olefin/nonconjugated polyene interpolymer; and wherein the first composition has the following properties: i) an MWD less than, or equal to, 3.5, ii) a Mooney Viscosity (ML (1+4, 125° C.)) greater than, or equal to, 60, iii) a CCDB from 7 to 15; B) a thermoplastic polymer; C) a vulcanization agent; and wherein the first interpolymer and the second interpolymer comprise incorporated oil.

    Thermoplastic vulcanizate including rubber block interpolymer

    公开(公告)号:US10155862B2

    公开(公告)日:2018-12-18

    申请号:US15539003

    申请日:2015-12-11

    Abstract: A thermoplastic vulcanizate composition includes (a) a crystalline thermoplastic polyolefin comprising alpha-olefin monomers having from 2 to 5 carbon atoms, (b) a rubber block interpolymer comprising a first block and a second block having differing chemical or physical properties from the first block, the first block is derived from ethylene, a first alpha-olefin monomer having from 3 to 10 carbon atoms, and a first diene monomer having from 2 to 25 carbon atoms, the second block is derived from ethylene, a second alpha-olefin monomer having from 3 to 10 carbon atoms, and optionally a second diene monomer having from 2 to 25 carbon atoms, and an amount of the block interpolymer in the composition being greater than an amount of the thermoplastic polyolefin in the composition, and (c) a curative system.

    Composition, thermoplastic vulcanizates made therefrom and articles formed from the same
    40.
    发明授权
    Composition, thermoplastic vulcanizates made therefrom and articles formed from the same 有权
    组合物,由其制成的热塑性硫化橡胶和由其形成的制品

    公开(公告)号:US09403973B2

    公开(公告)日:2016-08-02

    申请号:US14647563

    申请日:2013-12-23

    Abstract: A composition comprising at least the following (A) an ethylene/α-olefin copolymer; (B) an olefin-based polymer; (C) a crosslinking agent; and (D) a multifunctional acrylate coagent; wherein the ethylene/α-olefin copolymer of component A) has the following properties: (i) has a density from 0.855 to 0.875 g/cc; and (ii) a Mooney Viscosity (ML 1+4, 121° C.) from 10 to 100 is provided.

    Abstract translation: 至少包含以下(A)乙烯/α-烯烃共聚物的组合物; (B)烯烃类聚合物; (C)交联剂; 和(D)多官能丙烯酸酯助剂; 其中组分A)的乙烯/α-烯烃共聚物具有以下性质:(i)具有0.855至0.875g / cc的密度; 和(ii)提供10至100的门尼粘度(ML 1 + 4,121℃)。

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