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    Use of metal complex compounds as oxidation catalysts
    31.
    发明申请
    Use of metal complex compounds as oxidation catalysts 失效
    使用金属络合物作为氧化催化剂

    公开(公告)号：US20090068282A1

    公开(公告)日：2009-03-12

    申请号：US12288382

    申请日：2008-10-20

    申请人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josee Dubs ,  Menno Hazenkamp ,  Grit Hansler (-Richter) ,  Brigitte Schmidt ,  Albert Schneider ,  Peter Weingartner

    发明人： Gunther Schlingloff ,  Torsten Wieprecht ,  Frank Bachmann ,  Josef Dannacher ,  Marie-Josee Dubs ,  Menno Hazenkamp ,  Grit Hansler (-Richter) ,  Brigitte Schmidt ,  Albert Schneider ,  Peter Weingartner

    IPC分类号： A01N59/00 ,  A01N25/00 ,  D21C3/20 ,  A01P1/00 ,  C07D213/22

    CPC分类号： B01J31/1815 ,  B01J23/34 ,  B01J2231/70 ,  B01J2231/72 ,  B01J2531/16 ,  B01J2531/46 ,  B01J2531/72 ,  B01J2531/842 ,  B01J2531/845 ,  B01J2531/847 ,  C07D213/61 ,  C07D213/68 ,  C07D213/74 ,  C07F13/005 ,  C11D3/3932 ,  D06L4/10 ,  D06L4/12 ,  D06P5/02 ,  D06P5/153 ,  D21C9/1036 ,  D21C9/163

    摘要： Use of metal complex compounds of formula [LnMemXp]zYq  (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge Y), and L is a ligand of formula wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —N(R13)—NR′13R″13 wherein R13, R′13 and R″13 are as defined above for R13; —NR14R15 or —N⊕R14R15R16 wherein R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15 together with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).

    摘要翻译： 使用式<？in-line-formula description =“In-line Formulas”end =“lead”？> [LnMemXp] zYq（1），<？in-line-formula description =“In-line 其中Me为锰，钛，铁，钴，镍或铜，X为配位基或桥键基团，n和m各自独立地为1〜 8，p为0〜32的整数，z为金属络合物的电荷，Y为抗衡离子，q = z /（电荷Y），L为下式的配体，式中R1， R2，R3，R4，R5，R6，R7，R8，R9，R10和R11各自独立地为氢; 未取代或取代的C 1 -C 18烷基或芳基; 氰基; 卤素; 硝基 -COOR 12或-SO 3 R 12，其中R 12在各种情况下为氢，阳离子或未取代或取代的C 1 -C 18烷基或芳基; -SR 13，-SO 2 R 13或-OR 13，其中R 13各自为氢或未取代或取代的C 1 -C 18烷基或芳基; -N（R13）-NR'13R''13其中R13，R'13和R'13如上对R13所定义; -NR14R15或-N⊕R14R15R16，其中R14，R15和R16各自独立地为氢或未取代或取代的C1-C18烷基或芳基，或者R14和R15与其键合的氮原子一起形成未取代或取代的5 可以任选地含有其它杂原子的6-或7-元环; 条件是R 1，R 2，R 3，R 4，R 5，R 6，R 7，R 8，R 9，R 10和R 11不同时为氢，作为氧化反应的催化剂，并且式（1）和新颖的新型金属络合物 式（2）的配体。

    Use of metal complex compounds as catalysts for oxidation using molecular oxygen or air
    36.
    发明申请
    Use of metal complex compounds as catalysts for oxidation using molecular oxygen or air 审中-公开

    公开(公告)号：US20060019853A1

    公开(公告)日：2006-01-26

    申请号：US10531907

    申请日：2003-10-21

    申请人： Torsten Wieprecht ,  Gunther Schlingloff ,  Juntao Xia ,  Uwe Heinz ,  Abert Schneider ,  Marie-Josee Dubs ,  Frank Bachmann ,  Menno Hazekamp ,  Josef Dannacher

    发明人： Torsten Wieprecht ,  Gunther Schlingloff ,  Juntao Xia ,  Uwe Heinz ,  Abert Schneider ,  Marie-Josee Dubs ,  Frank Bachmann ,  Menno Hazekamp ,  Josef Dannacher

    IPC分类号： C07F15/00 ,  C11D3/28

    CPC分类号： C11D3/3932 ,  C11D3/168

    摘要： Use, as a catalyst for oxidation reactions using molecular oxygen and/or air, of at least one metal complex compound of formula (1) wherein Me is manganese, titanium, iron, cobalt, nickel or copper, X is a coordinating or bridging radical, n and m are each independently of the other an integer having a value of from 1 to 8, p is an integer having a value of from 0 to 32, z is the charge of the metal complex, Y is a counter-ion, q=z/(charge of Y), and L is a ligand of formula (2) wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10 and R11 are each independently of the others hydrogen; unsubstituted or substituted C1-C18alkyl or aryl; cyano; halogen; nitro; —COOR12 or —SO3R12 wherein R12 is in each case hydrogen, a cation or unsubstituted or substituted C1-C18alkyl or aryl; —SR13, —SO2R13 or —OR13 wherein R13 is in each case hydrogen or unsubstituted or substituted C1-C18alkyl or aryl; —NR14R15; —(C1-C6alkylene)-NR14R15; —N(+)R14R15R16; —(C1-C6alkylene)-N(+)R14R15R16; —N(R13)—(C1-C6alkylene)-NR14R15; —N[(C1-C6alkylene)-NR14R15]2; —N(R13)—(C1-C6alkylene)-N(+)R14R15R16; —N[(C1-C6alkylene)-N(+)R14R15R16]2; —N(R13)—N—R14R15 or —N(R13)N″R14R15R16, wherein R13 is as defined above and R14, R15 and R16 are each independently of the other(s) hydrogen or unsubstituted or substituted C1-C18alkyl or aryl, or R14 and R15, together with the nitrogen atom linking them, form an unsubstituted or substituted 5-, 6- or 7-membered ring which may contain further hetero atoms. [LnMemXp]zYq  (1)

    Multifunctional detergent base
    38.
    发明授权
    Multifunctional detergent base 失效
    多功能洗涤剂基

    公开(公告)号：US5885952A

    公开(公告)日：1999-03-23

    申请号：US649938

    申请日：1996-05-15

    申请人： Rolf Kuratli ,  Claude Eckhardt ,  Frank Bachmann ,  Werner Schreiber

    发明人： Rolf Kuratli ,  Claude Eckhardt ,  Frank Bachmann ,  Werner Schreiber

    IPC分类号： C11D10/04 ,  C11D3/37 ,  D06M13/165

    CPC分类号： C11D3/3788

    摘要： A detergent base which is obtainable from the reaction of an ethylenically unsaturated sulfonic acid or carboxylic acid or anhydride thereof with a nonionic surfactant of the formulaR.sub.1 --O-(alkylene-O).sub.n.sbsb.1 --R.sub.2 (1)in whichR.sub.1 is C.sub.8 -C.sub.22 alkyl or C.sub.8 -C.sub.18 alkenyl;R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, a cycloaliphatic radical having at least 6 C atoms or benzyl; andn.sub.1 is a number from 1 to 60;and if appropriate with sugar derivatives.The detergent base has a good calcium-dispersing power, is very stable to electrolytes and heat and has an excellent washing action and anti-redeposition properties. It is therefore suitable for the preparation of powder and liquid detergents.

    摘要翻译： 可从烯属不饱和磺酸或其羧酸或其酸酐与式R1-O-（亚烷基-O）n1-R2（1）的非离子表面活性剂反应获得的洗涤剂基质，其中R1是C8-C22烷基或 C 8 -C 18烯基; R2是氢，C1-C4烷基，具有至少6个C原子的脂环族基团或苄基; n1为1〜60的数; 并酌情与糖衍生物。 洗涤剂基质具有良好的钙分散能力，对电解质和热量非常稳定，具有优异的洗涤作用和抗再沉积性能。 因此适用于制备粉末和液体洗涤剂。