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    Reactive dyestuffs containing a triazinylamino group and one or two groups of the vinylsulfone series
    31.
    发明授权
    Reactive dyestuffs containing a triazinylamino group and one or two groups of the vinylsulfone series 失效
    含有三嗪基氨基和一个或两个乙烯基砜系列的反应性染料

    公开(公告)号：US5334709A

    公开(公告)日：1994-08-02

    申请号：US993360

    申请日：1992-12-18

    申请人： Jorg Dannheim ,  Werner H. Russ

    发明人： Jorg Dannheim ,  Werner H. Russ

    IPC分类号： C09B62/505 ,  C09B62/44 ,  C09B62/503 ,  C09B62/515 ,  D06P1/38 ,  D06P1/384

    CPC分类号： C09B62/503 ,  C09B62/4403

    摘要： Fiber-reactive dyestuffs, such as, for example, azo dyestuffs and heavy metal complex derivatives thereof, anthraquinone dyestuffs, phthalocyanine dyestuffs and formazan dyestuffs, which contain a fiber-reactive group of the vinylsulfone series and furthermore a group of the general formula ##STR1## in which R.sup.x is hydrogen or lower alkyl, which can be substituted by substituents customary in dyestuffs, and Q.sup.1 and Q.sup.2 both independently of one another are each lower alkyl, which is substituted by 1 or 2 lower alkanoyl groups or 1 or 2 lower alkoxycarbonyl groups or by one such alkoxycarbonyl and alkanoyl group, or an amino group, which is substituted by optionally substituted aryl and/or alkyl radicals, or an optionally substituted alkoxy, aryloxy, alkylthio or arylthio radical or a cyanamido radical, are described. The novel dyestuffs dye material containing hydroxy and/or carboxamide groups, such as cellulose fiber materials, wool and polyamides, in deep shades, and moreover are suitable for discharge and resist printing.

    摘要翻译： 纤维反应性染料，例如偶氮染料和其重金属络合物衍生物，蒽醌染料，酞菁染料和甲an染料，其含有乙烯基砜系列的纤维反应性基团，此外还有通式（3）其中Rx是氢或可以被染料中常规取代的低级烷基，并且Q1和Q2彼此独立地是低级烷基，其被1或2个低级烷酰基取代，或1或2个 2个低级烷氧基羰基或一个这样的烷氧基羰基和烷酰基，或被任选取代的芳基和/或烷基或任选取代的烷氧基，芳氧基，烷硫基或芳硫基或氰酰氨基取代的氨基。 。 含有羟基和/或羧酰胺基团的新型染料染料，例如纤维素纤维材料，羊毛和聚酰胺，深色调，并且还适用于放电和抗蚀印刷。

    Water-soluble compounds having a fiber-reactive group of the vinyl sulfone monoazo series bonded to an alkanoylamino of benzoylamino grouping, suitable as dyestuffs
    32.
    发明授权
    Water-soluble compounds having a fiber-reactive group of the vinyl sulfone monoazo series bonded to an alkanoylamino of benzoylamino grouping, suitable as dyestuffs 失效
    具有与苯甲酰氨基的烷酰基氨基键合的乙烯基砜单偶氮系的纤维反应性基团的水溶性化合物适合作为染料

    公开(公告)号：US5292871A

    公开(公告)日：1994-03-08

    申请号：US965072

    申请日：1992-10-22

    申请人： Ludwig Schlafer ,  Werner H. Russ

    发明人： Ludwig Schlafer ,  Werner H. Russ

    IPC分类号： C09B62/51 ,  D06P1/384

    CPC分类号： C09B62/51

    摘要： Water-soluble monoazo compounds conforming to the general formula (1) ##STR1## where D is monosulfo- or disulfo-phenyl, which may each be substituted by lower alkyl, lower alkoxy, halogen, carboxy and/or lower alkanoylamino, or is mono- or di- or trisulfonaphthyl, K as the radical of a coupling component is para-phenylene, which may be substituted by lower alkyl, lower alkoxy, halogen, lower alkanoylamino, ureido, carbamoyl and/or sulfo, or is 1,4-naphthylene, which may be substituted by 1 or 2 sulfo groups and/or a lower alkoxy group, R is hydrogen or lower alkyl, A is phenylene or a direct bond, W is a direct bond or lower alkylene or an amino group substituted by lower alkyl, although A and W are not both a direct bond, and the group --SO.sub.2 --X is a fiber-reactive group of the vinyl sulfone series.The azo compounds of the formula (1) are fiber-reactive and have very good dyestuff properties. They dye hydroxy- and/or carboxamido-containing material, in particular fiber material, for example cellulose fiber materials, wool and synthetic polyamide fibers, in strong, bright, fast shades. In particular they are suitable for discharge and resist printing.

    摘要翻译： 符合通式（1）的水溶性单偶氮化合物其中D为单磺酰基或二磺基 - 苯基，其各自可被低级烷基，低级烷氧基，卤素，羧基和/或低级烷酰基氨基取代， 或者是单 - 或二 - 或三 - 磺基萘基，作为偶合组分的基团的K为对亚苯基，其可以被低级烷基，低级烷氧基，卤素，低级烷酰基氨基，脲基，氨基甲酰基和/或磺基取代，或为1 可以被1或2个磺基和/或低级烷氧基取代的4-亚萘基，R是氢或低级烷基，A是亚苯基或直接键合，W是直接键或低级亚烷基或氨基 被低级烷基取代，尽管A和W不是直接键，而基团-SO 2 -X是乙烯基砜系列的纤维反应性基团。 式（1）的偶氮化合物是纤维反应性的并且具有非常好的染料性质。 它们以强烈，明亮，快速的色调染料含羟基和/或羧酰氨基的材料，特别是纤维材料，例如纤维素纤维材料，羊毛和合成聚酰胺纤维。 特别是它们适用于放电和抗蚀印刷。

    Fiber reactive dyes which contain a sulfonamido-triazinyl group and one or two groups or the vinyl sulfone series
    33.
    发明授权
    Fiber reactive dyes which contain a sulfonamido-triazinyl group and one or two groups or the vinyl sulfone series 失效
    含有磺酰胺 - 三亚胺基和一个或两个基团或乙烯磺酸酯系列的纤维反应性染料

    公开(公告)号：US5231172A

    公开(公告)日：1993-07-27

    申请号：US964516

    申请日：1992-10-21

    申请人： Thomas Beck ,  Werner H. Russ ,  Wilhelm Muhlig

    发明人： Thomas Beck ,  Werner H. Russ ,  Wilhelm Muhlig

    IPC分类号： C09B62/503 ,  C09B62/505 ,  C09B62/51 ,  C09B62/513 ,  C09B62/515 ,  C09B62/517 ,  D06P3/14 ,  D06P3/24 ,  D06P3/66

    CPC分类号： C09B62/503

    摘要： There are described water-soluble fiber-reactive dye-stuffs which possess a triazinylamino radical to which is bonded as second substituent an amino group or an N-containing heterocyclic group which, bonded via an arylene, alkylene or aralkyl radical, possesses a fiber-reactive grouping of the vinyl sulfone series, and to which is bonded as third substituent a sulfonamide group, wherein the sulfone radical is substituted by optionally substituted aryl, alkylenearyl or arylenealkyl or optionally substituted amino groups.The dyestuffs are used for dyeing hydroxy - and/or carboxamido-containing material, in particular fiber material, such as cellulose fibers, wool and synthetic polyamide.

    摘要翻译： 描述了具有作为第二取代基键合的三嗪基氨基的水溶性纤维反应性染料，氨基或含氮杂环基，其通过亚芳基，亚烷基或芳烷基键合，具有纤维 - 乙烯基砜系列的反应性分组，并且作为第三取代基与磺酰胺基团键合，其中砜基被任选取代的芳基，亚烷基硬脂基或亚芳基烷基或任选取代的氨基取代。 染料用于染色含羟基和/或羧酰胺的材料，特别是纤维材料，如纤维素纤维，羊毛和合成聚酰胺。

    Fiber reactive dyes which contain a cyanoaminotriazinyl group and one or two groups of the vinyl sulfone series
    34.
    发明授权
    Fiber reactive dyes which contain a cyanoaminotriazinyl group and one or two groups of the vinyl sulfone series 失效
    含有氰基氨基亚氨基的纤维反应性染料和一种或两种乙烯基磺酸酯系列

    公开(公告)号：US5225544A

    公开(公告)日：1993-07-06

    申请号：US975429

    申请日：1992-11-12

    申请人： Jorg Dannheim ,  Werner H. Russ

    发明人： Jorg Dannheim ,  Werner H. Russ

    IPC分类号： C09B62/503 ,  C09B62/44 ,  D06P3/24 ,  D06P3/66

    CPC分类号： C09B62/4403

    摘要： Water-soluble dyes are described, such as azo dyes, metal complex dyes, anthraquinone, phthalocyanine and formazan dyes, which contain a fiber-reactive group of the vinyl sulfone series which, if desired, is bound via a bridging member, and furthermore contain a 4-cyanamido-1,3,5-triazin-6-ylamino radical which is substituted in the 2 position by a group of the formula (2) ##STR1## in which R.sup.z is hydrogen or a lower alkyl group which is unsubstituted or substituted by alkyl, hydroxy, cyano, lower alkoxy, carboxyl, sulfamoyl, sulfo or sulfato or by a substituted or unsubstituted phenyl radical or is a cyclohexyl radical or a substituted or unsubstituted phenyl radical, W is an aryl, alkylenearyl, arylenealkyl, alkylenearylenealkyl or arylenealkylenearyl radical substituted by 1 to 4 water-solubilizing substituents, it being possible for these aryl, arylene, alkyl and alkylene radicals to be additionally substituted and/or interrupted by hetero groups, A is the number zero or 1, and B is the number 1 or 2, the sum of (A+B) being the number 2. The dyes are fiber-reactive and are suitable for the dyeing of hydroxy- and/or carboxamido-containing material, in particular fiber material, such as cotton, wool, silk and synthetic polyamide, by the procedures known for fiber-reactive dyes.

    摘要翻译： 描述了水溶性染料，例如偶氮染料，金属络合物染料，蒽醌，酞菁和甲an染料，其含有乙烯基砜系列的纤维反应性基团，如果需要，其通过桥连构件结合，并且还含有 在2位被式（2）的基团取代的4-氰氨基-1,3,5-三嗪-6-基氨基，其中R z是氢或低级烷基， 被烷基，羟基，氰基，低级烷氧基，羧基，氨磺酰基，磺基或硫酸根取代或被取代或未取代的苯基取代，或者是环己基或取代或未取代的苯基，W是芳基，亚烷基硬脂基，亚芳基 ，被1至4个水溶性取代基取代的亚烷基亚烷基烷基或亚芳基亚烷基烯基，这些芳基，亚芳基，烷基和亚烷基可以另外被杂原子取代和/或中断，A是数字0或1，B 是数字1或2，（A + B）的数量为数字2.染料是纤维反应性的，适用于染色含羟基和/或含羧酰氨基的材料，特别是纤维材料，例如 棉，羊毛，丝绸和合成聚酰胺，通过纤维活性染料已知的程序。

    Water-soluble triphendioxazine compounds and their use as dyestuffs
    35.
    发明授权
    Water-soluble triphendioxazine compounds and their use as dyestuffs 失效
    水溶性三苯并二恶嗪化合物及其作为染料的用途

    公开(公告)号：US5585489A

    公开(公告)日：1996-12-17

    申请号：US434682

    申请日：1995-05-04

    申请人： Werner H. Russ ,  Christian Schumacher

    发明人： Werner H. Russ ,  Christian Schumacher

    IPC分类号： C09B62/503 ,  C07D498/04 ,  C09B62/44 ,  C09B19/00 ,  C09B62/04

    CPC分类号： C07D498/04 ,  C09B62/4405

    摘要： Triphendioxazine compounds corresponding to the formula (1) ##STR1## in which Z is a radical of the formula (2) ##STR2## in which Y.sup.1 and Y.sup.2 each vinyl .beta.-hydroxyethyl or an ethyl radical which contains a substituent which can be eliminated under alkaline conditions in the .beta.-position, and in which Y.sup.1 and Y.sup.2 are not simultaneously .beta.-hydroxyethyl, W.sup.1 and W.sup.2 are both allyene having 2 to 6 carbon atoms, A is a covalent bond of a group of the formula --B.sup.1 --N(R.sup.3)--, in which R.sup.3 has one of the meanings of R.sup.1 and B.sup.1 is an aliphatic or aromatic bridge member, and in which the group--N(R.sup.1) --B.sup.1 --N(R.sup.3)-- can also be in total a bivalent saturated heterocyclic radical, and Z.sup.0 is hydrogen or a group of the formula (4) ##STR3## in which A.sup.0 is a covalent bond or a radical or the formula --N(R.sup.4)--B.sup.2 -- having the meaning corresponding to the above formula --B.sup.1 (NR.sup.3)-- are described. The triphendioxazine compounds of the formula (1) are used as fiber-reactive dyestuffs for dyeing material containing hydroxy, amino and/or carboxamide groups.

    摘要翻译： 对应于式（1）的三苯并二恶嗪化合物其中Z是式（2）的基团，其中Y1和Y2各自是乙烯基的β-羟乙基或乙基，其含有 取代基，其可以在碱性条件下在β-位上被去除，并且其中Y1和Y2不同时是β-羟乙基，W1和W2都是具有2至6个碳原子的烯丙烯，A是一组的共价键 式（B-N（R 3） - ）其中R 3具有R 1和R 1之一的含义是脂族或芳族桥连，其中-N（R 1）-B 1 -N（R 3） - 基团也可以 总共为二价饱和杂环基，Z 0为氢或式（4）的基团（4）其中A0为共价键或基团，或式-N（R4）-B2-具有 描述对应于上述式-B1（NR3）的含义。 式（1）的三苯并二恶嗪化合物用作用于含有羟基，氨基和/或羧酰胺基团的染色材料的纤维反应性染料。

    Water-soluble azo compounds containing a sulfo-naphthol as a coupling component and having fiber-reactive groups of the vinylsulfone series, suitable as dyestuffs
    39.
    发明授权
    Water-soluble azo compounds containing a sulfo-naphthol as a coupling component and having fiber-reactive groups of the vinylsulfone series, suitable as dyestuffs 失效
    含有作为联结组分的SULFO-NAPHTHOL的水溶性AZO化合物，并且具有适合作为试剂的乙烯基砜系列的纤维反应性组

    公开(公告)号：US5070189A

    公开(公告)日：1991-12-03

    申请号：US397993

    申请日：1989-08-24

    申请人： Ludwig Schlafer ,  Werner H. Russ

    发明人： Ludwig Schlafer ,  Werner H. Russ

    IPC分类号： C09B62/51 ,  C09B62/45 ,  D06P1/384

    CPC分类号： C09B62/45

    摘要： Water-soluble azo compounds which have fiber-reactive dyestuff properties and dye materials containing carboxamide and/or hydroxyl groups, such as fiber materials, in particular cellulose fiber materials, in strong, fast, predominantly bluish-tinged red to orange shades; they correspond to the general formula (1) ##STR1## in which: M is a hydrogen atom or an alkali metal;R is alkyl having 1 to 4 carbon atoms;D is a group of the formula ##STR2## in which R.sup.1 is hydrogen, alkyl having 1 to 4 carbon atoms, hydroxy, nitro, alkoxy having 1 to 4 carbon atoms, chlorine, bromine or carboxy, R.sup.2 is hydrogen, alkyl having 1 to 4 carbon atoms, alkoxy having 1 to 4 carbon atoms, chlorine or sulfo,R.sup.3 is hydrogen or sulfo;k is the number zero or 1;p is the number zero, 1 or 2;m is the number zero or 1;n is the number zero or 1; andX and Y are both independently of one another vinyl, .beta.-thiosulfatoethyl or .beta.-sulfatoethyl.

    摘要翻译： 具有纤维反应性染料性质的水溶性偶氮化合物和含有羧酰胺和/或羟基的染料，如纤维材料，特别是纤维素纤维材料，强烈，快速，主要呈蓝蓝色的红色至橙色色调; 它们对应于通式（1）其中：M是氢原子或碱金属; R是具有1至4个碳原子的烷基; D是其中R 1是氢，具有1至4个碳原子的烷基，羟基，硝基，具有1至4个碳原子的烷氧基，氯，溴或羧基，R 2是氢，烷基 具有1至4个碳原子，具有1至4个碳原子的烷氧基，氯或磺基，R 3是氢或磺基; k是数字0或1; p是数字零，1或2; m是数字0或1; n是数字0或1; X和Y彼此独立地为乙烯基，β-硫代硫代乙基或β-磺基乙基。

    Water-soluble monoazopyrazolone dyestuffs having fiber reactive groups of the vinylsulfone series
    40.
    发明授权
    Water-soluble monoazopyrazolone dyestuffs having fiber reactive groups of the vinylsulfone series 失效
    具有乙烯基砜系列的纤维反应性基团的水溶性单吡唑酮染料

    公开(公告)号：US4960872A

    公开(公告)日：1990-10-02

    申请号：US151720

    申请日：1988-02-03

    申请人： Ludwig Schlafer ,  Gunther Schwaiger ,  Werner H. Russ

    发明人： Ludwig Schlafer ,  Gunther Schwaiger ,  Werner H. Russ

    IPC分类号： C09B62/51

    CPC分类号： C09B62/51

    摘要： Water-soluble monoazo compounds corresponding to the following general formula (1) which have valuable fiber-reactive dyestuff properties and which dye materials, in particular cellulose fibers, containing carboxamide and/or hydroxy groups in fast, yellow shades. ##STR1## in which the symbols have the following meanings: D is a benzene ring or a radical of the formula ##STR2## R.sup.1 and R.sup.3, independently of one another, are both hydrogen, methyl, ethyl, methoxy, ethoxy, chlorine, bromine, carboxy or sulfo,R.sup.2 and R.sup.4, independently of one another, are each hydrogen, methyl, ethyl, methoxy, ethoxy, chlorine or bromine,R is carboxy or lower carboalkoxy, andX and Y, independently of one another, are each .beta.-thiosulfatoethyl or .beta.-sulfatoethyl or vinyl, but, in the event that x and/or Y is vinyl, the radicals R.sup.1 and/or R.sup.2 are necessarily sulfo.

    摘要翻译： 对应于具有有价值的纤维反应性染料性质的以下通式（1）的水溶性单偶氮化合物，以及具有快速黄色阴影的含有羧酰胺和/或羟基的染料，特别是纤维素纤维。 其中符号具有以下含义：D是苯环或下式的基团R 1和R 3彼此独立地是氢，甲基，乙基，甲氧基，乙氧基， 氯，溴，羧基或磺基，R 2和R 4各自独立地为氢，甲基，乙基，甲氧基，乙氧基，氯或溴，R为羧基或低级烷氧羰基，X和Y彼此独立地为氢， 各自为β-硫代硫代乙基或β-磺基乙基或乙烯基，但是在x和/或Y为乙烯基的情况下，基团R 1和/或R 2必须是磺基。