Amines, processes for their preparation and their use in compositions
which can undergo free radical polymerization
    34.
    发明授权
    Amines, processes for their preparation and their use in compositions which can undergo free radical polymerization 失效
    胺,它们的制备方法及其在可以进行自由基聚合的组合物中的用途

    公开(公告)号:US4628112A

    公开(公告)日:1986-12-09

    申请号:US675689

    申请日:1984-11-28

    摘要: Compounds of the formula ##STR1## in which R represents hydrogen or a methyl group,Y.sup.1 represents an optionally branched alkylene radical with 1 to 6 C atoms,Y.sup.2 represents an optionally branched alkylene radical with 2 to 8 C atoms,X denotes oxygen or an --NH-- group,R.sup.1 and R.sup.2 are identical or different and denote hydrogen, or an alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl, aralkyl or alkylaryl group which has 1 to 11 C atoms and is optionally substituted by one or more,hydroxyl, amino, epoxide, urethane, urea, ester or ether groups, orR.sup.1 and R.sup.2 together form a 3-membered to 6-membered ring, which optionally contains nitrogen, oxygen or sulphur as hetero-atoms,R.sup.3 has the meaning of R.sup.1 or represents a group ##STR2## or R.sup.2 and R.sup.3, together with the ##STR3## group, form a 5-membered or 6-membered ring, which optionally contains oxygen as a further hetero-atom, andR.sup.4 and R.sup.5 are identical or different and represent hydrogen, an alkyl or alkenyl group which has 1 to 10 C atoms and is optionally substituted by halogen, or halogen,function as activators in the free radical polymerization of olefinically unsaturated monomers.

    摘要翻译: 其中R表示氢或甲基的式“IMAGE”的化合物,Y1表示具有1至6个C原子的任选支化的亚烷基,Y2表示具有2至8个C原子的任选支化的亚烷基,X表示氧或 -NH-基团,R 1和R 2相同或不同,表示氢或具有1至11个C原子并且任选被一个或多个羟基取代的烷基,烯基,环烷基,环烯基,芳基,芳烷基或烷芳基, 氨基,环氧化物,氨基甲酸酯,脲,酯或醚基团,或R 1和R 2一起形成3元至6元环,其任选地含有氮,氧或硫作为杂原子,R 3具有R 1的含义或表示 一组或R2和R3与基团一起形成5元或6元环,其任选地含有氧作为另一个杂原子,并且R 4和R 5相同或不同,并且表示 氢,具有1至10个C原子的烷基或烯基,并且是op 被卤素或卤素取代,在烯属不饱和单体的自由基聚合中用作活化剂。