利索-全球专利检索

  1. 登录
  2. 注册

搜索结果

84 条记录 (耗时 0.02 秒)

    3-Tetrahaloethyl-cyclopropane-1-carboxylate esters
    31.
    发明授权
    3-Tetrahaloethyl-cyclopropane-1-carboxylate esters 失效
    3-四氢乙基 - 环丙烷-1-羧酸酯

    公开(公告)号：US4315012A

    公开(公告)日：1982-02-09

    申请号：US205245

    申请日：1980-11-10

    申请人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute

    发明人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute

    IPC分类号： A01N53/00 ,  A01N53/04 ,  A01N53/08 ,  C07D213/64 ,  C07D213/647 ,  C07D213/70 ,  A61K31/44 ,  C07D213/55

    CPC分类号： C07D213/647 ,  A01N53/00 ,  C07D213/70

    摘要： Novel esters in the form of their stereoisomers or mixtures thereof of the formula ##STR1## X.sub.1 is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, X.sub.2 is selected from the group consisting of fluorine, chlorine and bromine, X.sub.3 is selected from the group consisting of chlorine and bromine, each Z is independently selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy and alkylthio of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, --CF.sub.3, 3,4-methylenedioxy, chlorine, fluorine and bromine, n is 0, 1 or 2, Y is selected from the group consisting of oxygen and sulfur and R is selected from the group consisting of hydrogen, --CN and ethynyl, the acid moiety having a structure selected from the group consisting of 1R, cis; 1S, cis; 1R, trans; and 1S, trans and the alcohol moiety having a configuration of (R), (S) or (RS) and the asymetric carbon in the 1-position of the 3-ethyl side chain exists in the form of isomer A and isomer B having insecticidal and acaricidal activity and their preparation.

    摘要翻译： 其立体异构体形式的新型酯或其混合物式如下：选自氢，氟，氯和溴，X 2选自氟，氯和溴，X 3为 选自氯和溴，每个Z独立地选自1至4个碳原子的烷基，1至4个碳原子的烷氧基和烷硫基，1至4个碳原子的烷基磺酰基，-CF 3，3 ，4-亚甲二氧基，氯，氟和溴，n为0,1或2，Y选自氧和硫，R选自氢，-CN和乙炔基，酸部分具有 选自以下的结构：1R，顺式; 1S，顺式; 1R，反式; 和1S，反式和具有（R），（S）或（RS）构型的醇部分和3-乙基侧链的1-位中的不对称碳以异构体A和异构体B的形式存在，具有 杀虫和杀螨活性及其制备。

    Preparation of optically active allethrolone
    32.
    发明授权
    Preparation of optically active allethrolone 失效
    光学活性依托罗酮的制备

    公开(公告)号：US4307251A

    公开(公告)日：1981-12-22

    申请号：US155754

    申请日：1980-06-02

    申请人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute

    发明人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute

    IPC分类号： C07C49/743 ,  C07B57/00 ,  C07C27/00 ,  C07C27/02 ,  C07C45/00 ,  C07C45/65 ,  C07C45/67 ,  C07C51/00 ,  C07C61/04 ,  C07C61/13 ,  C07C61/40 ,  C07C62/18 ,  C07C67/00

    CPC分类号： C07C45/673

    摘要： A novel process for the preparation of (R) or (S) 2-allyl-3-methyl-4-hydroxy-2-cyclopentene-1-one comprising reacting a boron halide with an ester of a chiral carboxylic acid of the formula ##STR1## where A is organic group of a chiral carboxylic acid and (R) or (S) 2-allyl-3-methyl-4-hydroxy-2-cyclopentene-1-one and treating the reaction mixture with water to obtain allethrolone with the same configuration of the starting ester in high yields without undesired by-products produced in known methods.

    摘要翻译： 一种制备（R）或（S）2-烯丙基-3-甲基-4-羟基-2-环戊烯-1-酮的新方法，包括使卤化硼与下式的手性羧酸的酯反应： 其中A是手性羧酸的有机基团和（R）或（S）2-烯丙基-3-甲基-4-羟基-2-环戊烯-1-酮的有机基团，并用水处理反应混合物以获得具有 起始酯的相同构型以高产率形成，而没有在已知方法中生产的不需要的副产物。

    Process for the preparation of esters
    33.
    发明授权
    Process for the preparation of esters 失效
    制备酯的方法

    公开(公告)号：US4277617A

    公开(公告)日：1981-07-07

    申请号：US951184

    申请日：1978-10-13

    申请人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute ,  Andre Teche

    IPC分类号： C07C69/007 ,  A01N37/10 ,  A01N53/02 ,  A01N53/06 ,  A01N53/08 ,  C07C43/225 ,  C07C67/00 ,  C07C69/74 ,  C07C69/743 ,  C07C69/747 ,  C07C69/76 ,  C07C255/16 ,  C07C255/38 ,  C07C255/53 ,  C07C313/00 ,  C07C319/20 ,  C07C323/12 ,  C07D209/49 ,  C07D307/42

    CPC分类号： C07C255/00 ,  C07C43/225

    摘要： Novel esters in the form of their stereoisomers and mixtures of stereoisomers of the formula ##STR1## wherein X is selected from the group consisting of fluorine, chlorine and bromine R.sub.1 is selected from the group consisting of ##STR2## Y.sub.1 and Y.sub.2 may both be methyl and when Y.sub.1 is hydrogen, Y.sub.2 is selected from the group consisting of ##STR3## and Y.sub.3 and Y.sub.4 are individually selected from the group consisting of fluorine, bromine and chlorine or the group consisting of hydrogen and methyl, Z is selected from the group consisting of hydrogen, fluorine, chlorine, bromine, alkyl of 1 to 4 carbon atoms and alkoxy of 1 to 4 carbon atoms, and when Y.sub.2 is ##STR4## R.sub.2 is selected from the group consisting of ##STR5## A is selected from the group consisting of ##STR6## and when Y.sub.2 is --CHBr--CCl.sub.2 Br, R.sub.2 is m-phenoxy-phenyl and when R.sub.1 is R.sub.1 ' and Y.sub.2 is ##STR7## the said acid moiety may be in the cis or trans form or mixtures thereof or optically active isomeric form or racemic mixtures thereof and when R.sub.1 is R.sub.1 ", the said acid moiety is optically active isomeric form or racemic mixtures thereof and the compounds may be in one of two diastereoisomeric forms due to the existence of the asymetrical carbon atoms to which X is attached having insecticidal activity and their preparation.

    摘要翻译： 其立体异构体形式的新型酯和式IA的立体异构体的混合物，其中X选自氟，氯和溴。R1选自下组：Y1和Y2可以是 甲基，当Y1为氢时，Y2选自和Y3，Y4分别选自氟，溴和氯或由氢和甲基组成的组，Z选自 由氢，氟，氯，溴，1至4个碳原子的烷基和1至4个碳原子的烷氧基组成，当Y2是 R2时，选自 + TR A选自 + TR ，当Y2为-CHBr-CCl2Br时，R2为间苯氧基 - 苯基，当R1为R1'且Y2为时， 所述酸部分可以是顺式或反式或其混合物或旋光异构形式 或其外消旋混合物，并且当R 1为R 1“时，所述酸部分为光学活性异构体形式或其外消旋混合物，并且由于X附着的非对称碳原子的存在，所述化合物可为两种非对映异构形式之一 具有杀虫活性及其制备方法。

    Process for resolving amino acids using substituted lactones
    36.
    发明授权
    Process for resolving amino acids using substituted lactones 失效
    使用取代的内酯拆分氨基酸的方法

    公开(公告)号：US5136050A

    公开(公告)日：1992-08-04

    申请号：US154799

    申请日：1988-02-11

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： C07D207/16

    CPC分类号： C07D207/16

    摘要： Novel substituted lactones of amino acids in all their possible stereoisomeric forms or mixtures thereof of the formula ##STR1## wherein A is a hydrocarbon chain of 1 to 10 chain members containing one or more heteroatoms and one or more unsaturations and the chain members being a mono- or polycyclic system or comprises a system of spiro or endo type and may contain one or more chiral atoms or the lactone copula can present a supplementary chirality due to the asymetric spatial configuration of the molecule make up and R is selected from the group consisting of ##STR2## wherein Z is the organic remainder of an amino acid of the formula ##STR3## Y is derived from a primary, secondary or tertiary alcohol of the formula Y-OH and B is the remainder of a heterocycle amino acid of 3 to 6 carbon atoms of the formula ##STR4## and their preparation and their use for the resolution of amino acids.

    摘要翻译： 新颖的氨基酸的取代的内酯以其所有可能的立体异构体形式或其混合物，其中A为具有1至10个含有一个或多个杂原子和一个或多个不饱和基团的链成员的烃链，链成员为 单环或多环系统或包含螺或内型的系统，并且可以含有一个或多个手性原子，或由于分子组成的不对称空间构型，内酯共聚物可呈现辅助手性，并且R选自 其中Z是下式的氨基酸的有机剩余部分III1衍生自式Y-OH的伯，仲或叔醇，B是 其余的具有式（III）III2的3至6个碳原子的杂环氨基酸及其制备及其在分解氨基酸中的用途。

    Certain cyclopropanedicarboxylates with an unsaturated side chain having insecticidal activity
    37.
    发明授权
    Certain cyclopropanedicarboxylates with an unsaturated side chain having insecticidal activity 失效

    公开(公告)号：US4883806A

    公开(公告)日：1989-11-28

    申请号：US100284

    申请日：1987-09-23

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： A01N53/00 ,  A23K1/16 ,  A61K31/22 ,  C07D209/48 ,  C07D213/64 ,  C07D213/647 ,  C07D233/72 ,  C07D307/20 ,  C07D307/45 ,  C07D309/12

    CPC分类号： C07D213/647 ,  A01N53/00 ,  A23K20/105 ,  A23K20/111 ,  A23K20/132 ,  A61K31/22 ,  C07D209/48 ,  C07D233/72 ,  C07D307/20 ,  C07D307/42 ,  C07D309/12

    摘要： Novel isomers and mixtures thereof of cyclopropane carboxylic acid derivatives with a 3-unsaturated side chain of the formula ##STR1## wherein A' is selected from the group consisting of (1) alkyl of 1 to 18 carbon atoms, (2) benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy or halogen, ##STR2## wherein R.sub.1 is selected from the group consisting of hydrogen and methyl and R.sub.2 is selected from the group consisting of --CH.sub.2 --C.tbd.CH and monocyclic aryl, ##STR3## wherein a is selected from the group consisting of hydrogen and methyl and R.sub.3 is an aliphatic group of 2 to 6 carbon atoms containing at least one carbon-carbon unsaturation ##STR4## wherein a and and R.sub.3 have the above definition and R.sub.1 ' and R.sub.2 ' are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, cyano and alkoxy carbonyl of 2 to 5 carbon atoms, (6) ##STR5## wherein B is selected from the group consisting of ##STR6## --O-- and --S--, R.sub.4 is selected from the group consisting of hydrogen, --CH.sub.3, --C.tbd.N--CONH.sub.2, --CSNH.sub.2 and --C.tbd.CH, n is an integer form 0, 1 or 2 and R.sub.5 is selected from the group consisting of halogen and --CH.sub.3 ##STR7## wherein R.sub.6, R.sub.7 , R.sub.8 and R.sub.9 are selected from the group consisting of hydrogen, chlorine and methyl and S/I symbolizes an aromatic ring or dihydro or tetrahydro ring, ##STR8## wherein R.sub.10 is selected from the group consisting of hydrogen and --CN, R.sub.12 is selected from the group consisting of --CH.sub.2 -- and --O-- and R.sub.11 is selected from the group consisting of thiazolyl and thiadiazolyl with the bond the bond to ##STR9## being in anyone of the positions, R.sub.12 being bonded to R.sub.11 by the carbon atom included between a sulfur atom and a nitrogen atom, ##STR10## wherein R.sub.13 is selected from the group consisting of hydrogen and --CN ##STR11## wherein R.sub.13 has the above definition and the benzoyl is in the 3- or 4-position; ##STR12## wherein R.sub.14 is; selected from the group consisting of hydrogen, methyl, ethynyl and --CN and R.sub.15 and R.sub.16 are individually selected from the group consisting of hydrogen, bromine and fluorine and ##STR13## wherein R.sub.14 has the above definition, p is 0, 1 or 2, each R.sub.17 is selected from the group consisting of alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, --CF.sub.3 3,4-methylenedioxy, chlorine, bromine and fluorine, B is selected from the group consisting of --O-- and --S-- and R is selected from the group consisting of alkyl of 1 to 18 carbon atoms substituted with one or more, optionally different functional groups, aryl of 6 to 14 carbon atoms optionally substituted with one or more optionally different functional groups, the double bond having Z or E geometry having insecticidal and nematocidal activity as well as plant and animal acaricidal activity and their preparation.

    Process for resolution of chiral alcohols or phenols or chiral lactonic compounds
    38.
    发明授权
    Process for resolution of chiral alcohols or phenols or chiral lactonic compounds 失效
    手性醇或酚或手性内酯化合物的拆分方法

    公开(公告)号：US4540797A

    公开(公告)日：1985-09-10

    申请号：US447442

    申请日：1982-12-06

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： B01J31/02 ,  C07B31/00 ,  C07B57/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/10 ,  C07C29/88 ,  C07C37/86 ,  C07C41/18 ,  C07C43/295 ,  C07C45/57 ,  C07C51/487 ,  C07C62/02 ,  C07C62/04 ,  C07C67/00 ,  C07D307/33 ,  C07D307/88 ,  C07D307/93 ,  C07D315/00 ,  C07D307/77

    CPC分类号： C07D307/33 ,  C07C29/10 ,  C07C41/26 ,  C07C43/295 ,  C07C45/57 ,  C07D307/93 ,  C07D315/00 ,  C07B2200/07 ,  C07C2101/14

    摘要： Novel ethers of organic compounds containing chiral atoms of the formula ##STR1## wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymmetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymmetric carbon atom, a phenol moiety substituted comprising at least one asymmetric carbon atom and a substituted alcohol or phenol moiety with a chirality due to the dissymmetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) .alpha.-cyano-3-phenoxy-benzyl when A is ##STR2## which are useful for the resolution of compounds of the formulae ##STR3## wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms.

    摘要翻译： 含有式（I）的手性原子的有机化合物的新型醚，其中A是1至10个基团的烃化链，所述链含有一个或多个杂原子，一个或多个不饱和基团，构成链的基团的组合 代表单环或多环系统，包括螺或内型的系统，链A可以含有一个或多个手性原子，或者内酯部分可以由于整个分子和Z的不对称空间构型而呈现手性 选自含有至少不对称碳原子的伯，仲或叔醇部分，被至少一个不对称碳原子取代的苯酚部分和具有由于不对称空间构型引起的手性的取代的醇或苯酚部分 整个分子，条件是Z不是（R）或（S）α-氰基-3-苯氧基 - 苄基，当A是，它们对分辨率o有用 f化合物，其中A和Z具有上述定义，X选自氢和1至4个碳原子的烷基。

    Novel chiral ethers and their use in resolution of alcohols and phenols
    40.
    发明授权
    Novel chiral ethers and their use in resolution of alcohols and phenols 失效
    新型手性醚及其在醇和酚的拆分中的应用

    公开(公告)号：US4265817A

    公开(公告)日：1981-05-05

    申请号：US21833

    申请日：1979-03-19

    申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

    IPC分类号： B01J31/02 ,  C07B31/00 ,  C07B57/00 ,  C07B61/00 ,  C07C27/00 ,  C07C29/10 ,  C07C29/88 ,  C07C37/86 ,  C07C41/18 ,  C07C43/295 ,  C07C45/57 ,  C07C51/487 ,  C07C62/02 ,  C07C62/04 ,  C07C67/00 ,  C07D307/33 ,  C07D307/88 ,  C07D307/93 ,  C07D315/00 ,  C07D307/77

    CPC分类号： C07D307/33 ,  C07C29/10 ,  C07C41/26 ,  C07C43/295 ,  C07C45/57 ,  C07D307/93 ,  C07D315/00 ,  C07B2200/07 ,  C07C2101/14

    摘要： Novel ethers of organic compounds containing chiral atoms of the formula ##STR1## wherein A is a hydrocarbonated chain of 1 to 10 groups, the said chain containing one or more heteroatoms, one or more unsaturations, the assembly of the groups constituting the chain may represent a mono- or polycyclic system, including a system of the spiro or endo type, the chain A can contain one or more chiral atoms or the lactone moiety can present a chirality due to the dissymetric spatial configuration of the whole of the molecule and Z is selected from the group consisting of primary, secondary or tertiary alcohol moiety containing at least an asymetric carbon atom, a phenol moiety substituted comprising at least one asymetric carbon atom and an substituted alcohol or phenol moiety with a chirality due to the dissymetric spatial configuration of the whole of the molecule, with the proviso Z is not (R) or (S) .alpha.-cyano-3-phenoxy-benzyl when A is ##STR2## which are useful for the resolution of compounds of the formulae ##STR3## wherein A and Z have the above definitions and X is selected from the group consisting of hydrogen and alkyl of 1 to 4 carbon atoms.

    摘要翻译： 含有式（I）的手性原子的有机化合物的新型醚，其中A是1至10个基团的烃化链，所述链含有一个或多个杂原子，一个或多个不饱和基团，构成链的基团的组合 代表单环或多环系统，包括螺或内型的系统，链A可以含有一个或多个手性原子，或者内酯部分可以呈现手性，这是由于整个分子的不对称空间结构和Z 选自包含至少一个不对称碳原子的伯，仲或叔醇部分，被至少一个不对称碳原子取代的苯酚部分和具有手性的取代的醇或苯酚部分，这些部分具有由于不对称空间构型的手性 整个分子，条件是Z不是（R）或（S）α-氰基-3-苯氧基 - 苄基，当A是，其可用于分辨c 其中A和Z具有上述定义并且X选自氢和1至4个碳原子的烷基的式的化合物。