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公开(公告)号：US4571349A
公开(公告)日：1986-02-18
申请号：US687397
申请日：1984-12-28
IPC分类号： C08G77/00 , C08G77/06 , C08G77/10 , C08G77/20 , C08G77/28 , C09D5/00 , C09D183/04 , C09D183/08 , D21H27/00 , B05D3/06
CPC分类号： D21H27/001 , C08G77/20 , C08G77/28 , C09D183/08
摘要： Organopolysiloxanes which are crosslinked by high energy radiation consisting essentially of siloxane units of the formulas:(a) HR.sup.1 C.dbd.CR.sup.2 COOR.sup.3 SiR.sub.2 O.sub.1/2,(b) HSR.sup.4 SiRO and(c) R.sub.2.sup.5 SiOwhere R is a monovalent hydrocarbon radical or a halogenated monovalent hydrocarbon radical, R.sup.1 is hydrogen or a phenyl radical or a halogenated phenyl radical, R.sup.2 is hydrogen or an alkyl radical having from 1 to 4 carbon atoms per radical and R.sup.3 is a hydrocarbon radical or a halogenated hydrocarbon radical, R.sup.4 is a divalent hydrocarbon radical, R.sup.5 is the same as R or a hydrocarbon radical substituted with the HR.sup.1 C.dbd.CR.sup.2 COO group, where R.sup.1 and R.sup.2 are the same as above, in which two siloxane units of the formulaHR.sup.1 C.dbd.CR.sup.2 COOR.sup.3 SiR.sub.2 O.sub.1/2are present per molecule. These organopolysiloxanes are prepared by equilibrating the corresponding siloxanes in accordance with the conventional methods known in the art.These organopolysiloxanes can be crosslinked by high energy radiation, for example, ultraviolet radiation, to form coatings on paper for releasing tacky substances or as coatings on optic fibers and as photocuring sealants for electronic components.
摘要翻译： 通过高能辐射交联的有机聚硅氧烷基本上由下式的硅氧烷单元组成：（a）HR1C = CR2COOR3SiR2O1 / 2，（b）HSR4SiRO和（c）R25SiO，其中R是一价烃基或卤代一价烃基，R1 是氢或苯基或卤代苯基，R 2是氢或每个基团具有1至4个碳原子的烷基，R 3是烃基或卤代烃基，R 4是二价烃基，R 5是 与R相同或被HR1C = CR2COO基团取代的烃基，其中R1和R2与上述相同，其中每个分子存在两个式HR1C = CR2COOR3SiR2O1 / 2的硅氧烷单元。 这些有机聚硅氧烷通过根据本领域已知的常规方法使相应的硅氧烷平衡来制备。 这些有机聚硅氧烷可以通过高能量辐射（例如紫外线辐射）交联，以在纸上形成用于释放粘性物质的涂层或作为光纤上的涂层和用作电子部件的光固化密封剂。
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32.发明授权Organopolysiloxanes having SiC-bonded oxyalkylene units and a method for preparing the same 失效具有SiC键合的氧化烯单元的有机聚硅氧烷及其制备方法
公开(公告)号：US4533477A
公开(公告)日：1985-08-06
申请号：US536476
申请日：1983-09-28
申请人： Gerhard Preiner , Karl Huhn , Johann Muller , Heinrich Marwitz , Kurt Ullrich
发明人： Gerhard Preiner , Karl Huhn , Johann Muller , Heinrich Marwitz , Kurt Ullrich
IPC分类号： C08G77/00 , C08G77/22 , C08G77/46 , D06M13/02 , D06M13/51 , D06M13/513 , D06M15/647 , B05D3/02
CPC分类号： C08G77/46 , D06M15/647
摘要： Organopolysiloxanes having SiC-bonded oxyalkylene units and Si-bonded hydroxyl groups, in which an average of at least 15 mol percent of the siloxane units contain only one SiC-bonded monovalent organic radical and the silicon valences which are not satisfied by the SiC-bonded monovalent organic radical are satisfied by siloxane oxygen atoms or oxygen atoms of hydroxyl groups. These organopolysiloxanes are preferably prepared by reacting triorganosiloxy end-blocked organopolysiloxanes consisting of diorganosiloxane units, in which at least part of these units contain SiC-bonded oxyalkylene units and, if appropriate, organohydrogensiloxane units or organohydroxyl siloxane units or organoalkoxysiloxane units of mixtures of at least two such monoorganosiloxy units with water in the presence of an acid or base or, and subsequently with a silane or simultaneously with water and a silane in which the silane contains one SiC-bonded monovalent organic radical, or partially hydrolyzed products of the silane. The new organopolysiloxanes are applied to textile fibers to impart hydrophilic properties thereto.
摘要翻译： 具有SiC键合的氧化烯单元和Si键合的羟基的有机聚硅氧烷，其中平均至少15摩尔％的硅氧烷单元仅含有一个与SiC键合的一价有机基团和不符合SiC键合的硅价态 硅氧烷氧原子或羟基氧原子满足一价有机基团。 这些有机聚硅氧烷优选通过使由二有机硅氧烷单元组成的三有机甲硅烷氧基封端的有机聚硅氧烷反应制备，其中这些单元的至少一部分含有SiC键合氧化烯单元，以及如果合适的话，有机氢硅氧烷单元或有机羟基硅氧烷单元或有机烷氧基硅氧烷单元至少 两个这样的单有机基甲硅烷氧基单元与酸在酸或碱的存在下反应，或随后与硅烷或水同时与硅烷混合，其中硅烷含有一个与SiC键合的一价有机基团或硅烷的部分水解产物。 将新的有机聚硅氧烷应用于纺织纤维以赋予其亲水性。
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公开(公告)号：US4515976A
公开(公告)日：1985-05-07
申请号：US578389
申请日：1984-02-08
申请人： Gerhard Preiner , Johann Muller
发明人： Gerhard Preiner , Johann Muller
IPC分类号： C07F7/08
CPC分类号： C07F7/0874
摘要： Asymmetrical disiloxanes are prepared by reacting (a) a silane containing three SiC-bonded monovalent organic radicals in which at least one may be substituted with Si-bonded hydrogen and an SiOC-bonded monovalent organic radical with (b) a symmetrical disiloxane which is different from the disiloxane obtained from the hydrolysis of silane (a), and contains at least two identical substituents in the presence of water and an acid at a temperature of from -10.degree. to about 50.degree. C.
摘要翻译： 通过使（a）含有三个与SiC键合的一价有机基团的硅烷反应来制备非对称二硅氧烷，其中至少一个可以被Si键合的氢和SiOC键合的一价有机基团取代，（b）对称的二硅氧烷是不同的 由硅烷（a）的水解得到的二硅氧烷，在-10℃〜50℃的温度下，在水和酸的存在下，含有至少两个相同的取代基。
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公开(公告)号：US4377955A
公开(公告)日：1983-03-29
申请号：US192605
申请日：1980-09-30
申请人： Johann Muller
发明人： Johann Muller
摘要： A wrench having a handle with an actuating lever arm pivoted for operation to rotate a nut engaging ring geometrically configured to accept a nut or bolt head. The nut engaging ring includes two tappets extending in the plane of rotation of the lever arm. A torque applied to the lever arm engages these tappets and thereby causes the nut engaging ring to rotate with increased force.
摘要翻译： 具有手柄的扳手具有枢转的操作杆臂，用于操作以旋转几何构造成接受螺母或螺栓头的螺母接合环。 螺母接合环包括在杠杆臂的旋转平面中延伸的两个挺杆。 施加到杠杆臂的扭矩与这些挺杆接合，从而使螺母接合环以增加的力旋转。
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公开(公告)号：US4292423A
公开(公告)日：1981-09-29
申请号：US134407
申请日：1980-03-27
摘要： Organopolysiloxanes having substituted carbamoyloxy groups (.tbd.SiOCO--NH--) bonded to silicon via oxygen, which are prepared by reacting an organopolysiloxane containing Si-bonded hydroxyl groups with an organic isocyanate in the presence of an organic tin compound.The stability of the organopolysiloxanes containing carbamoyloxy groups may be improved if the organopolysiloxane having Si-bonded hydroxyl groups is reacted with an organic isocyanate in the presence of an organic tin compound which is supported on a solid carrier and then the reaction product is filtered under anhydrous conditions to remove the supported organic tin compound.
摘要翻译： 在有机锡化合物的存在下，通过使含有Si键合的羟基的有机聚硅氧烷与有机异氰酸酯反应而制备的具有通过氧键接合到硅上的氨基甲酰氧基（3BOND SiOCO-NH-）的有机聚硅氧烷。 如果在负载在固体载体上的有机锡化合物存在下，如果具有Si键合的羟基的有机聚硅氧烷与有机异氰酸酯反应，则可以改善含有氨基甲酰氧基的有机聚硅氧烷的稳定性，然后将反应产物在无水 去除负载有机锡化合物的条件。
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公开(公告)号：US4183260A
公开(公告)日：1980-01-15
申请号：US807526
申请日：1977-06-17
CPC分类号： B25B21/005 , Y10T74/2133 , Y10T74/2135 , Y10T74/2137 , Y10T74/2138 , Y10T74/214 , Y10T74/2141
摘要： This disclosure relates to a tool for rotating elements, such as nuts, bolts, screws or like fasteners, and includes a ring having ratchet teeth, the ring being driven by a lever, a pawl carried by the lever for engaging the ratchet teeth, a flexible tension-applying member in at least partial surrounding relationship to the ring, means for supporting the pawl, and the tension-applying member being disposed between the supporting means and the lever whereby upon movement of the lever in a first direction the pawl rotates the ring through the engagement of a tooth of the ring and the tension-applying member deforms slightly to frictionally grip the ring.
摘要翻译： 本公开涉及一种用于旋转元件的工具，例如螺母，螺栓，螺钉或类似的紧固件，并且包括具有棘齿的环，该环由杠杆驱动，由杠杆承载的棘爪用于接合棘轮齿， 与所述环至少部分环绕的弹性张力施加构件，用于支撑所述棘爪的装置，以及所述张力施加构件设置在所述支撑装置和所述杆之间，由此当所述杆沿第一方向移动时， 通过环的齿的接合和张力施加构件稍微变形以摩擦地夹紧环。
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公开(公告)号：US4117735A
公开(公告)日：1978-10-03
申请号：US776745
申请日：1977-03-11
CPC分类号： B25B21/002 , B25B23/0078 , Y10T74/18232
摘要： A power wrench having at least a partially annular drive head connected at first and second pivots through a first of a pair of telescopic members and to a third member, respectively, the third member being connected by a third pivot to the second member, and upon a relative linear telescopic motion of the first and second members, the drive head is rotated through a predetermined arc under the control of the third member.
摘要翻译： 一种电动扳手，其具有至少部分环形的驱动头，其分别通过一对伸缩构件中的第一和第三构件在第一和第二枢轴处连接，第三构件通过第三枢轴连接到第二构件，并且在 第一和第二构件的相对线性伸缩运动，驱动头在第三构件的控制下旋转预定的弧。
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