公开(公告)号：US4652662A

公开(公告)日：1987-03-24

申请号：US733562

申请日：1985-05-14

申请人： Gunther von Au ,  Karl Braunsperger ,  Karl Huhn ,  Ingomar Kovar

发明人： Gunther von Au ,  Karl Braunsperger ,  Karl Huhn ,  Ingomar Kovar

IPC分类号： C08G77/00 ,  C08G77/06 ,  C08G77/08 ,  C08G77/28 ,  C08G77/38 ,  C07F7/08 ,  C07D303/02 ,  C07F7/10

CPC分类号： C08G77/08 ,  C08G77/06

摘要： A process for preparing organofunctional organopolysiloxanes which comprises reacting a cyclic diorganopolysiloxane with a silane having a SiC-bonded monovalent organic radical with at least one functional group and at least one SiOC-bonded monovalent hydrocarbon radical which can be substituted by an ether oxygen atom, or with an oligomer of such a silane having a maximum of 10 silicon atoms per molecule, in the presence of a quaternary ammonium hydroxide.

摘要翻译： 一种制备有机官能有机聚硅氧烷的方法，其包括使环状二有机聚硅氧烷与具有与SiC键合的一价有机基团的硅烷与至少一个官能团和至少一个可被醚氧原子取代的SiOC键合的一价烃基反应，或 在季铵氢氧化物的存在下，每分子具有最多10个硅原子的硅烷的低聚物。

公开(公告)号：US4559385A

公开(公告)日：1985-12-17

申请号：US648416

申请日：1984-09-10

申请人： Karl Huhn ,  Kurt Ullrich

发明人： Karl Huhn ,  Kurt Ullrich

IPC分类号： D06M13/50 ,  C08J3/03 ,  C08L83/04 ,  D06M13/02 ,  D06M13/51 ,  D06M15/643 ,  C08L83/00

CPC分类号： C08J3/03 ,  C08L83/04 ,  D06M15/6436 ,  C08G77/16 ,  C08G77/18 ,  C08G77/20 ,  C08G77/26 ,  C08G77/70 ,  C08J2383/04 ,  Y10T428/31663

摘要： Aqueous emulsions for impregnating organic fibers, comprising, in addition to water and dispersants, (1) a diorganopolysiloxane having a Si-bonded hydroxyl group in each terminal unit and whose organic radicals are free of basic nitrogen atoms; (2) an organopolysiloxane containing diorganosiloxane units in which the two organic radicals are monovalent hydrocarbon radicals and also contains at least two monovalent SiC-bonded organic radicals per molecule having a basic nitrogen atom in which the organopolysiloxane is present in the emulsion in an amount of from 5 to 50 weight percent based on the weight of the diorganopolysiloxane (1); (3) an organosilicon compound selected from an organosilane containing at least two SiOC-bonded monovalent organic radicals consisting of carbon, hydrogen and possibly oxygen and/or partial hydrolyzates thereof, in which the organosilicon compound is present in the emulsion in an amount of from 2 to 6 weight percent based on the total weight of the diorganopolysiloxane (1) and organopolysiloxane (2); and (4) a condensation catalyst, which is present in an amount of from 0.2 to 1 weight percent based on the total weight of the diorganopolysiloxane (1) and organopolysiloxane (2).These aqueous emulsions are prepared by mixing the organosilicon compound (3) with an emulsion of diorganopolysiloxane (1) and organopolysiloxane (2) and thereafter mixing the resultant mixture with the condensation catalyst (4).

摘要翻译： 用于浸渍有机纤维的水乳液，除了水和分散剂之外，还包含（1）在每个末端单元中具有与Si键合的羟基的二有机聚硅氧烷，其有机基团不含碱性氮原子; （2）含有二有机硅氧烷单元的有机聚硅氧烷单元，其中两个有机基团是单价烃基，并且每分子含有至少两个具有碱性氮原子的单价SiC键合的有机基团，其中有机聚硅氧烷以乳液中的量存在于乳液中 基于二有机基聚硅氧烷（1）的重量为5至50重量％; （3）选自含有由碳，氢和可能的氧和/或部分水解产物组成的至少两个SiOC键合的一价有机基团的有机硅烷的有机硅化合物，其中有机硅化合物以乳液的量存在于乳液中 基于二有机聚硅氧烷（1）和有机基聚硅氧烷（2）的总重量计，2至6重量％; 和（4）缩合催化剂，其以基于二有机聚硅氧烷（1）和有机聚硅氧烷（2）的总重量的0.2至1重量％的量存在。 通过将有机硅化合物（3）与二有机聚硅氧烷（1）和有机聚硅氧烷（2）的乳液混合，然后将所得混合物与缩合催化剂（4）混合来制备这些水性乳液。

公开(公告)号：US4555419A

公开(公告)日：1985-11-26

申请号：US627125

申请日：1984-07-02

申请人： Karl Huhn ,  Gunter von Au

发明人： Karl Huhn ,  Gunter von Au

IPC分类号： D06M13/02 ,  D06M13/51 ,  D06M13/513 ,  D06M15/643 ,  B05D3/02

CPC分类号： D06M15/6436

摘要： A method for impregnating textile materials made from organic fibers which comprises impregnating the textile materials with a composition containing a crosslinkable diorganopolysiloxane, an organopolysiloxane containing at least 3 Si-bonded hydrogen atoms per molecule, a crosslinking catalyst, and an organo(poly)siloxane containing 1 or 2 Si-bonded hydrogen atoms and 2 to 8 silicon atoms per molecule, in which the composition is free of a filler having a surface area greater than 50 g/m.sup.2 in an amount greater than 1 weight percent based on the weight of the organosilicon compounds and thereafter crosslinking the crosslinkable diorganopolysiloxane to form a coating thereon.

摘要翻译： 一种用于浸渍由有机纤维制成的纺织材料的方法，其包括用含有可交联的二有机聚硅氧烷，每分子含有至少3个Si键合氢原子的有机聚硅氧烷，含有有机聚硅氧烷的有机聚硅氧烷 1或2个Si键合的氢原子和每个分子2至8个硅原子，其中组合物不含表面积大于50g / m 2的填料，其量大于1重量％，基于 有机硅化合物，然后交联可交联的二有机基聚硅氧烷以在其上形成涂层。

公开(公告)号：US4423092A

公开(公告)日：1983-12-27

申请号：US328976

申请日：1981-12-09

申请人： Karl Huhn ,  Helga Lampelzammer ,  Wolfgang Kaiser

发明人： Karl Huhn ,  Helga Lampelzammer ,  Wolfgang Kaiser

IPC分类号： D06M13/02 ,  D06M13/244 ,  D06M13/282 ,  D06M13/292 ,  D06M13/295 ,  D06M13/322 ,  D06M13/46 ,  D06M13/463 ,  D06M13/50 ,  D06M13/51 ,  D06M13/513 ,  D06M15/643 ,  D06M15/647 ,  B05D3/02

CPC分类号： D06M13/46 ,  D06M13/295 ,  D06M15/643 ,  Y10S524/912

摘要： A lubricating composition to improve the sliding properties of organic fibers comprising an organosilicon compound having at least one OSiR.sub.2 unit and a compound selected from the group consisting ofO.dbd.P[(OCHR.sup.1 CHR.sup.1).sub.n OR.sup.2 ].sub.3, NR.sub.4.sup.2+ x.sup.-and mixtures thereof, where R is a hydrocarbon radical or a substituted hydrocarbon radical, R.sup.1 represents hydrogen or the methyl group, with the proviso that in each --OCHR.sup.1 CHR.sup.1 unit at least one R.sup.1 must be hydrogen, R.sup.2 represents hydrogen or a monovalent hydrocarbon radical having from 1 to 20 carbon atoms, with the proviso that in each compound of the formula NR.sub.4.sup.2+ x.sup.- at least two of the R.sup.2 radicals must represent hydrocarbon radicals, n is either O or an integer having a value of from 1 to 15, with the proviso that when R.sup.2 is hydrogen in each of the phosphorus compounds, n must be at least 1 and that at least one --OCHR.sup.1 CHR.sup.1 unit must be present in each of the phosphorus compounds and x.sup.- represents an anion of an organic or inorganic acid. These compounds not only improve the sliding properties of organic fibers, but also impart antielectrostatic properties to the treated fibers.

摘要翻译： 一种用于改善有机纤维的滑动性能的润滑组合物，其包含具有至少一个OSiR2单元的有机硅化合物和选自O = P [（OCHR1CHR1）nOR2] 3，NR42 + x-的化合物及其混合物，其中 R是烃基或取代的烃基，R 1表示氢或甲基，条件是在每个-OCHR1CHR1单元中，至少一个R1必须是氢，R2表示氢或具有1至20碳的一价烃基 原子，条件是在式NR42 + x的每个化合物中 - 至少两个R2基团必须表示烃基，n是0或具有1至15的整数，条件是当R 2 是每个磷化合物中的氢，n必须至少为1，并且在每个磷化合物中必须存在至少一个-OCHR1CHR1单元，x代表有机或无机酸的阴离子。 这些化合物不仅改善有机纤维的滑动性能，而且还赋予处理纤维抗静电性能。

公开(公告)号：US4720520A

公开(公告)日：1988-01-19

申请号：US039811

申请日：1987-04-09

申请人： Karl Huhn ,  Ingomar Kovar

发明人： Karl Huhn ,  Ingomar Kovar

IPC分类号： C08L83/04 ,  D06M15/643 ,  D06M101/00 ,  D06M101/16 ,  C08L83/08

CPC分类号： D06M15/6436

摘要： A method for impregnating organic fibers which comprises applying a composition containing (1) an organopolysiloxane having silicon-bonded condensable groups and containing diorganosiloxane units in which the two SiC-bonded organic radicals are monovalent hydrocarbon radicals and also contains two monovalent SiC-bonded radicals having a basic nitrogen group; (2) an organopolysiloxane having at least 3 Si-bonded hydrogen atoms per molecule; and (3) a catalyst which promotes the condensation of the silicon-bonded condensable groups, in which the SiC-bonded radicals having a basic nitrogen group are present in the organopolysiloxane (1) as monoorganosiloxane units and as diorganosiloxane units.

摘要翻译： 一种浸渍有机纤维的方法，其包括将含有（1）具有硅键合的可缩合基团并且含有二有机硅氧烷单元的有机聚硅氧烷的组合物，其中两个SiC键合的有机基团是一价烃基，并且还含有两个一价SiC键合基团， 碱性氮基; （2）每分子具有至少3个Si键合氢原子的有机聚硅氧烷; 和（3）促进硅键合的可缩合基团的缩合的催化剂，其中具有碱性氮基团的SiC键合基团作为单有机硅氧烷单元存在于有机聚硅氧烷单元中，并作为二有机硅氧烷单元存在。

公开(公告)号：US4625010A

公开(公告)日：1986-11-25

申请号：US763865

申请日：1985-08-09

申请人： Karl Huhn ,  Rudolf Kaufmann

发明人： Karl Huhn ,  Rudolf Kaufmann

IPC分类号： C08G77/00 ,  C08G77/06 ,  C08G77/14 ,  C08G77/22 ,  C08G77/38 ,  C08L83/12 ,  D06M13/02 ,  D06M13/51 ,  D06M13/513 ,  D06M15/65 ,  C08G77/12

CPC分类号： D06M15/65 ,  C08G77/38

摘要： Novel organopolysiloxanes are described in which the organopolysiloxanes are terminated by units of the formula R.sub.3 SiO.sub.1/2 and comprise units of the formulas RR.sup.1 SiO, RR.sup.2 SiO, RR.sup.3 SiO, RHSiO and R.sub.2 SiO, where R represents the same or different alkyl radicals having from 1 to 4 carbon atoms per radical, or phenyl radicals, R.sup.1 represents the same or different alkyl radicals having at least 6 carbon atoms per radical, R.sup.2 represents the same or different aralkyl radicals and R.sup.3 represents the same or different, SiC-bonded, monovalent organic radicals having at least one vicinal epoxy group per radical. These organopolysiloxanes are preferably prepared by reacting organopolysiloxanes which contain units of the formulas R.sub.3 SiO.sub.1/2 and RHSiO and optionally units of the formula R.sub.2 SiO, wherein R is the same as above, with an organic compound that has a terminal C.dbd.C-bond and at least one vicinal epoxy group per molecule, at least one alkene having at least 6 carbon atoms per molecule, and at least one aralkene in the presence of a catalyst which promotes the addition of Si-bonded hydrogen to the aliphatic C.dbd.C bond. These organopolysiloxanes may be applied simultaneously with a polymer having perfluoroalkyl groups with at least 3 carbon atoms per alkyl group to fibers to render them oil and water repellent.

公开(公告)号：US5302659A

公开(公告)日：1994-04-12

申请号：US35108

申请日：1993-03-19

申请人： Johann Bindl ,  Hans-Juergen Lautenschlager ,  Karl Huhn ,  Kiyoshi Ninomiya

发明人： Johann Bindl ,  Hans-Juergen Lautenschlager ,  Karl Huhn ,  Kiyoshi Ninomiya

IPC分类号： B01F17/54 ,  B01J13/00 ,  C08G77/38 ,  C08G77/388 ,  C08L83/02 ,  C08L83/08 ,  D06M13/02 ,  D06M13/188 ,  D06M15/643 ,  C08L83/00

CPC分类号： D06M15/6433 ,  C08G77/388 ,  D06M15/6436

摘要： Emulsions which are prepared by reacting (A) an organopolysiloxane which has at least one monovalent SiC-bonded radical with primary and/or secondary amino groups, with (B) a carboxylic acid anhydride in the presence of (C) an emulsifier and (D) an aqueous phase. These emulsions are suitable as textile treating agents.

摘要翻译： 通过使（A）在（C）乳化剂和（D）的存在下使（A）具有至少一个一价SiC键合的基团与伯和/或仲氨基的有机聚硅氧烷与（B）羧酸酐反应制备的乳液 ）水相。 这些乳液适合作为纺织品处理剂。

公开(公告)号：US5302657A

公开(公告)日：1994-04-12

申请号：US891901

申请日：1992-06-01

申请人： Karl Huhn ,  Christine Seidl ,  Kurt Ullrich

发明人： Karl Huhn ,  Christine Seidl ,  Kurt Ullrich

IPC分类号： A61K8/72 ,  A61K8/89 ,  A61K8/891 ,  C08J3/03 ,  C08L83/02 ,  C08L83/04 ,  C08L83/08 ,  D06M15/643 ,  D06M101/00 ,  C08L83/00

CPC分类号： C08J3/03 ,  B01D19/0409 ,  D06M15/643 ,  D06M15/6436 ,  C08J2383/04 ,  Y10T428/2962

摘要： The invention relates to a process for preparing polyorganosiloxane-containing emulsions having a mean particle size of less than 0.3 .mu.m in which, in a first step,(A) a concentrate is prepared by mixing a polyorganosiloxane with water and an emulsifier which is soluble in the polyorganosiloxane.and, in a second step,(B) the concentrate thus obtained is diluted with water to the desired polyorganosiloxane concentration.These emulsions can be used for impregnating fibres and fabrics.

摘要翻译： 本发明涉及一种制备平均粒径小于0.3（my）m的含聚有机硅氧烷的乳液的方法，其中在第一步中，（A）通过将聚有机硅氧烷与水和乳化剂混合制备浓缩物， 可溶于聚有机硅氧烷。 在第二步中，（B）将由此获得的浓缩物用水稀释至所需的聚有机硅氧烷浓度。 这些乳液可用于浸渍纤维和织物。

公开(公告)号：US4874662A

公开(公告)日：1989-10-17

申请号：US240040

申请日：1988-08-26

申请人： Karl Huhn

发明人： Karl Huhn

IPC分类号： C08G77/26 ,  D06M15/643 ,  D06M101/00 ,  D06M101/02 ,  D06M101/16

CPC分类号： D06M15/6436 ,  Y10T428/31663 ,  Y10T442/2762 ,  Y10T442/2803 ,  Y10T442/2877 ,  Y10T442/291 ,  Y10T442/2918

摘要： The invention is a process wherein organic fibers are impregnated with organopolysiloxane (1) containing, in addition to diorganosiloxane units in which the two SiC-bonded organic radicals are monovalent hydrocarbon radicals, at least two monovalent SiC-bonded radicals containing basic nitrogen, at least some of the SiC-bonded radical containing basic nitrogen comprising SiC-bonded N-cyclohexylaminoalkyl radicals. The SiC-bonded N-cyclohexylaminoalkyl radicals are in monoorganosiloxane and/or diorganosiloxane and/or triorganosiloxane units. The preferred SiC-bonded N-cyclohexylaminoalkyl radical is the SiC-bonded N-cyclohexyl-3-aminopropyl radical. The organopolysiloxane (1) contains optionally condensable groups which are bonded directly to silicon. The organopolysiloxane (1) containing condensable groups bonded directly to silicon can be employed together with an organopolysiloxane (2a) containing at least 3 Si-bonded hydrogen atoms per molecule, or together with trialkoxy- or tetraalkoxysilanes (2b), and if appropriate, together with a catalyst (3) for the condensation of condensable groups bonded directly to silicon.

摘要翻译： 本发明是一种方法，其中有机聚硅氧烷（1）除了含有两个SiC键合的有机基团是一价烃基的二有机硅氧烷单元外还含有至少两个含有碱性氮的一价SiC键合基团， 一些含有键合键的自由基含有包含SiC键合的N-环己基氨基烷基的碱性氮。 SiC键合的N-环己基氨基烷基在单有机硅氧烷和/或二有机硅氧烷和/或三有机硅氧烷单元中。 优选的SiC键合的N-环己基氨基烷基是与SiC键合的N-环己基-3-氨基丙基。 有机聚硅氧烷（1）含有直接与硅键合的可冷凝基团。 含有直接与硅结合的可缩合基团的有机聚硅氧烷（1）可以与每分子含有至少3个Si键合的氢原子或与三烷氧基 - 或四烷氧基硅烷（2b）一起使用的有机聚硅氧烷（2a）一起使用，如果合适， 具有用于将直接键合到硅上的可冷凝基团的缩合的催化剂（3）。

公开(公告)号：US4533477A

公开(公告)日：1985-08-06

申请号：US536476

申请日：1983-09-28

申请人： Gerhard Preiner ,  Karl Huhn ,  Johann Muller ,  Heinrich Marwitz ,  Kurt Ullrich

发明人： Gerhard Preiner ,  Karl Huhn ,  Johann Muller ,  Heinrich Marwitz ,  Kurt Ullrich

IPC分类号： C08G77/00 ,  C08G77/22 ,  C08G77/46 ,  D06M13/02 ,  D06M13/51 ,  D06M13/513 ,  D06M15/647 ,  B05D3/02

CPC分类号： C08G77/46 ,  D06M15/647

摘要： Organopolysiloxanes having SiC-bonded oxyalkylene units and Si-bonded hydroxyl groups, in which an average of at least 15 mol percent of the siloxane units contain only one SiC-bonded monovalent organic radical and the silicon valences which are not satisfied by the SiC-bonded monovalent organic radical are satisfied by siloxane oxygen atoms or oxygen atoms of hydroxyl groups. These organopolysiloxanes are preferably prepared by reacting triorganosiloxy end-blocked organopolysiloxanes consisting of diorganosiloxane units, in which at least part of these units contain SiC-bonded oxyalkylene units and, if appropriate, organohydrogensiloxane units or organohydroxyl siloxane units or organoalkoxysiloxane units of mixtures of at least two such monoorganosiloxy units with water in the presence of an acid or base or, and subsequently with a silane or simultaneously with water and a silane in which the silane contains one SiC-bonded monovalent organic radical, or partially hydrolyzed products of the silane. The new organopolysiloxanes are applied to textile fibers to impart hydrophilic properties thereto.

摘要翻译： 具有SiC键合的氧化烯单元和Si键合的羟基的有机聚硅氧烷，其中平均至少15摩尔％的硅氧烷单元仅含有一个与SiC键合的一价有机基团和不符合SiC键合的硅价态 硅氧烷氧原子或羟基氧原子满足一价有机基团。 这些有机聚硅氧烷优选通过使由二有机硅氧烷单元组成的三有机甲硅烷氧基封端的有机聚硅氧烷反应制备，其中这些单元的至少一部分含有SiC键合氧化烯单元，以及如果合适的话，有机氢硅氧烷单元或有机羟基硅氧烷单元或有机烷氧基硅氧烷单元至少 两个这样的单有机基甲硅烷氧基单元与酸在酸或碱的存在下反应，或随后与硅烷或水同时与硅烷混合，其中硅烷含有一个与SiC键合的一价有机基团或硅烷的部分水解产物。 将新的有机聚硅氧烷应用于纺织纤维以赋予其亲水性。