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44 条记录 (耗时 0.072 秒)

    Processes for producing epsilon caprolactams
    33.
    发明授权
    Processes for producing epsilon caprolactams 失效
    生产ε己内酰胺的方法

    公开(公告)号：US06300496B1

    公开(公告)日：2001-10-09

    申请号：US09413572

    申请日：1999-10-06

    申请人： Kurt Damar Olson ,  Thomas Carl Eisenschmid ,  David Robert Bryant ,  Arthur Roy Doumaux, Jr.

    发明人： Kurt Damar Olson ,  Thomas Carl Eisenschmid ,  David Robert Bryant ,  Arthur Roy Doumaux, Jr.

    IPC分类号： C07D20108

    CPC分类号： C07D201/08 ,  Y02P20/582

    摘要： This invention relates in part to processes for producing one or more substituted or unsubstituted epsilon caprolactams, e.g., epsilon caprolactam, which comprise (a) converting one or more substituted or unsubstituted hydroxyaldehydes, e.g., 6-hydroxyhexanal, optionally in the presence of a catalyst or a catalyst and promoter, to one or more substituted or unsubstituted hydroxyamides, e.g. 6-hydroxycaproamide, and/or one or more substituted or unsubstituted epsilon caprolactam precursors, e.g., 6-aminocaproamide, epsilon caprolactone, epsilon caprolactone oligomers and esters of 6-hydroxycaproic acid and mixtures thereof, and (b) converting said one or more substituted or unsubstituted hydroxyamides and/or said one or more substituted or unsubstituted epsilon caprolactam precursors, optionally in the presence of a catalyst or a catalyst and promoter, to said one or more substituted or unsubstituted epsilon caprolactams; wherein the amount of byproducts resulting from reduction and/or reductive amination of said one or more substituted or unsubstituted hydroxyaldehydes, e.g., 1,6-hexanediol, aminohexanol, and the like, is no greater than about 10 weight percent, preferably no greater than about 5 weight percent, and more preferably no greater than about 1 weight percent, of the total of said one or more substituted or unsubstituted hydroxyamides and/or one or more substituted or unsubstituted epsilon caprolactam precursors. This invention also relates in part to reaction mixtures containing one or more substituted or unsubstituted epsilon caprolactams as principal product(s) of reaction.

    摘要翻译： 本发明部分地涉及用于制备一种或多种取代或未取代的ε-己内酰胺（例如ε-己内酰胺）的方法，其包括（a）任选在催化剂存在下，将一种或多种取代或未取代的羟基醛例如6-羟基己醛转化 或催化剂和促进剂，与一种或多种取代或未取代的羟基酰胺，例如， 6-羟基己酰胺和/或一种或多种取代或未取代的ε-己内酰胺前体，例如6-氨基己酰胺，ε-己内酯，ε-己内酯低聚物和6-羟基己酸的酯及其混合物，和（b）将所述一种或多种取代的 或所述一种或多种取代或未取代的ε-己内酰胺前体，任选在催化剂或催化剂和促进剂存在下，与所述一种或多种取代或未取代的ε己内酰胺反应; 其中所述一种或多种取代或未取代的羟基醛（例如1,6-己二醇，氨基己醇等）的还原和/或还原胺化产生的副产物的量不大于约10重量％，优选不大于 所述一个或多个取代或未取代的羟基酰胺和/或一个或多个取代或未取代的ε-己内酰胺前体的总量的约5重量％，更优选不大于约1重量％。 本发明还部分涉及含有一种或多种取代或未取代的ε-己内酰胺作为主要反应产物的反应混合物。

    Phosoxophite ligands and use thereof in carbonylation processes
    38.
    发明授权
    Phosoxophite ligands and use thereof in carbonylation processes 有权
    Phosoxophite配体及其在羰基化过程中的应用

    公开(公告)号：US07196230B2

    公开(公告)日：2007-03-27

    申请号：US10504247

    申请日：2003-03-04

    申请人： Wei-Jun Peng ,  David Robert Bryant

    发明人： Wei-Jun Peng ,  David Robert Bryant

    IPC分类号： C07F9/02

    CPC分类号： C07F15/008 ,  C07C45/49 ,  C07C45/50 ,  C07C67/293 ,  C07C67/347 ,  C07F9/65742 ,  C07F9/65744 ,  C07F9/65746 ,  C07C47/19 ,  C07C47/228 ,  C07C69/003 ,  C07C69/716 ,  C07C69/14

    摘要： A novel organophosphorus composition and synthesis thereof, the composition being characterized by one phosphite moiety, one phosoxophite moiety, and a plurality of sterically bulky substituents. The novel composition finds utility as a ligand in Group VIII transition metal phosoxophite complex catalysts and complex catalyst precursors that are used in carbonylation processes, preferably, hydroformylation processes. Additionally, there is disclosed a novel method of preparing a phosphoromonochloridite composition that finds utility as a precursor to the novel phosoxophite composition.

    摘要翻译： 一种新颖的有机磷组合物及其合成，该组合物的特征在于一个亚磷酸酯部分，一个亚磷酸酯部分和多个空间庞大的取代基。 该新型组合物可用作第VIII族过渡金属磷酸盐络合物催化剂和复合催化剂前体中的配体，其用于羰基化方法，优选加氢甲酰化方法。 此外，公开了一种制备可用作新型磷酸盐组合物的前体的一氯代氯酸盐组合物的新方法。