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公开(公告)号：US06420588B1
公开(公告)日：2002-07-16
申请号：US09911440
申请日：2001-07-24
申请人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Daniel Joseph Brunelle , Elliott West Shanklin , Paul Michael Smigelski, Jr. , Ganesh Kailasam
发明人： Patrick Joseph McCloskey , Timothy Brydon Burnell , Daniel Joseph Brunelle , Elliott West Shanklin , Paul Michael Smigelski, Jr. , Ganesh Kailasam
IPC分类号： C07C6996
摘要： High yields of ester-substituted diary carbonates such as bis-methyl salicyl carbonate were obtained by the condensation of methyl salicylate with phosgene in the presence of a phase transfer catalyst (PTC) in an interfacial reaction system in which the pH of the aqueous phase was greater than 9.3. Using the method of the present invention conversions of greater than 99% were obtained whereas under standard conditions using triethylamine as the catalyst conversions were limited to 70-75% of the methyl salicylate starting material even with a 20 mole % excess of added phosgene. The optimized conditions of the of the present invention use only a slight excess of phosgene and represent an attractive route for the manufacture of bis methyl salicyl carbonate and ester-substituted diaryl carbonates generally.
摘要翻译： 通过在界面反应体系中存在相转移催化剂（PTC）的情况下，通过水杨酸甲酯与光气的缩合得到高产率的酯取代的二元碳酸酯，其中水相的pH为 大于9.3。 使用本发明的方法获得大于99％的转化率，而在使用三乙胺的标准条件下，即使使用20摩尔％过量的加入的光气，催化剂转化率也限于水杨酸甲酯起始原料的70-75％。 本发明的优化条件仅使用轻微过量的光气，并且代表通常用于制造碳酸双甲基水杨酸酯和酯取代的二芳基碳酸酯的有吸引力的途径。
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公开(公告)号：US5917005A
公开(公告)日：1999-06-29
申请号：US893596
申请日：1997-07-14
IPC分类号： C08G73/10
CPC分类号： C08G73/1064 , C08G73/1042 , C08G73/105 , C08G73/106
摘要： Polyetherimides are prepared by conventional means from hindered diamines such as the isomeric methyl-4,6-diethyl-1,3-phenylenediamines and bis(2-chloro-4-amino-3,5-diethylphenyl)methane. They have unusually high glass transition temperatures.
摘要翻译： 聚醚酰亚胺通过常规方法由受阻二胺如异构甲基-4,6-二乙基-1,3-苯二胺和双（2-氯-4-氨基-3,5-二乙基苯基）甲烷制备。 它们具有非常高的玻璃化转变温度。
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33.发明授权公开(公告)号：US08623971B2
公开(公告)日：2014-01-07
申请号：US13361684
申请日：2012-01-30
IPC分类号： C08G75/23 , C08F283/06 , C08L81/00
摘要： Polyethersulfones having Tg greater than about 225° C. and a notched Izod value greater than about 1 ft-lb/in, as measured by ASTM D256, comprise from about 5 mol % to less than about 40 mol % structural units of formula 1; and from greater than about 60 mol % to about 95 mol % structural units of formula 2 wherein R1, R2, and R3 are independently at each occurrence a halogen atom, a nitro group, a cyano group, a C1-C12aliphatic radical, C3-C12cycloaliphatic radical, or a C3-C12aromatic radical; n, m, q are independently at each occurrence integers from 0 to 4; and Q is a C3-C20cycloaliphatic radical, or a C3-C20aromatic radical.
摘要翻译： Tg大于约225℃的聚醚砜和通过ASTM D256测量的大于约1ft-lb / in的缺口伊佐德值包含约5mol％至小于约40mol％的式1结构单元; 和大于约60mol％至约95mol％的式2的结构单元，其中R 1，R 2和R 3在每次出现时独立地为卤素原子，硝基，氰基，C 1 -C 12脂族基，C 3 -C 12脂族基， C 12环脂族基或C 3 -C 12芳族基; n，m，q各自独立地为0至4的整数; Q为C 3 -C 20环脂族基或C 3 -C 20芳族基。
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34.发明申请公开(公告)号：US20120130043A1
公开(公告)日：2012-05-24
申请号：US13361684
申请日：2012-01-30
IPC分类号： C08G75/23
摘要： Polyethersulfones having Tg greater than about 225° C. and a notched Izod value greater than about 1 ft-lb/in, as measured by ASTM D256, comprise from about 5 mol % to less than about 40 mol % structural units of formula 1; and from greater than about 60 mol % to about 95 mol % structural units of formula 2 wherein R1, R2, and R3 are independently at each occurrence a halogen atom, a nitro group, a cyano group, a C1-C12aliphatic radical, C3-C12cycloaliphatic radical, or a C3-C12aromatic radical; n, m, q are independently at each occurrence integers from 0 to 4; and Q is a C3-C20cycloaliphatic radical, or a C3-C20aromatic radical.
摘要翻译： Tg大于约225℃的聚醚砜和通过ASTM D256测量的大于约1ft-lb / in的缺口伊佐德值包含约5mol％至小于约40mol％的式1结构单元; 和大于约60mol％至约95mol％的式2的结构单元，其中R 1，R 2和R 3在每次出现时独立地为卤素原子，硝基，氰基，C 1 -C 12脂族基，C 3 -C 12脂族基， C 12环脂族基或C 3 -C 12芳族基; n，m，q各自独立地为0至4的整数; Q为C 3 -C 20环脂族基或C 3 -C 20芳族基。
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公开(公告)号：US07902316B2
公开(公告)日：2011-03-08
申请号：US11388710
申请日：2006-03-24
摘要： A polyethersulfone composition is disclosed which comprises structural units derived from bisphenol-A and 4,4′-biphenol, the structural units derived from 4,4′-biphenol being present in an amount corresponding to greater than 65 mole percent based on total moles of structural units derived from diphenolic monomers, wherein the polyethersulfone has a weight average molecular weight (Mw) of at least 54,000 grams per mole as measured by gel permeation chromatography. The polyethersulfone compositions of the invention display outstanding impact strength as measured using ASTM D256. Surprisingly, the polyethersulfone compositions of the invention show enhanced impact strength relative to known polyethersulfones such as RADEL R, a commercially available polyethersulfone engineering thermoplastic comprised of structural units derived from a dihalodiarylsulfone and 4,4′-biphenol and having a Notched Izod impact strength of about 700 Joules per meter.
摘要翻译： 公开了一种聚醚砜组合物，其包含衍生自双酚A和4,4'-联苯酚的结构单元，衍生自4,4'-联苯酚的结构单元的存在量相当于基于总共摩尔数 衍生自二元酚单体的结构单元，其中聚醚砜的重均分子量（Mw）通过凝胶渗透色谱法测定为至少54,000克/摩尔。 本发明的聚醚砜组合物显示出优异的冲击强度，使用ASTM D256测量。 令人惊奇的是，本发明的聚醚砜组合物相对于已知的聚醚砜如RADEL R显示出增强的冲击强度，RADEL R是由二卤代芳基砜和4,4'-联苯酚衍生的结构单元的市售聚醚砜工程热塑性塑料，其具有缺口伊佐德冲击强度 约700焦耳/米。
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公开(公告)号：US07273919B1
公开(公告)日：2007-09-25
申请号：US11286181
申请日：2005-11-21
CPC分类号： C08G75/23
摘要： High heat polyethersulfone compositions are provided which possess unexpectedly high glass transition temperatures. The polyethersulfone compositions comprise structural units derived from phthalimide bisphenols such as 3,3-bis(4 -hydroxyphenyl)-N-phenylphthalimide, and structural units derived from at least one biphenyl-bissulfone such as 4,4′-bis((4-chlorophenyl)sulfonyl)-1,1′-biphenyl. The novel polyethersulfone compositions may further comprise structural units derived from one or more biphenols such as 4,4′-biphenol, bisphenols such as BPA, or other electrophilic sulfone monomers, such as bis(4-chlorophenyl)sulfone. In one embodiment, the polyethersulfone composition of the present invention comprises structural groups derived exclusively from 3,3-bis(4-hydroxyphenyl)-N-phenylphthalimide, and 4,4′-bis((4-chlorophenyl)sulfonyl)-1,1′-biphenyl and exhibits a single glass transition of greater than 300° C.
摘要翻译： 提供了具有出人意料的高玻璃化转变温度的高热聚醚砜组合物。 聚醚砜组合物包含衍生自邻苯二甲酰亚胺双酚的结构单元，例如3,3-双（4-羟基苯基）-N-苯基邻苯二甲酰亚胺，以及衍生自至少一种联苯基 - 砜的结构单元，例如4,4'-双（（4- 氯苯基）磺酰基）-1,1'-联苯。 新型聚醚砜组合物还可以包含衍生自一种或多种双酚的结构单元，例如4,4'-联苯酚，双酚如BPA或其它亲电子砜单体如双（4-氯苯基）砜。 在一个实施方案中，本发明的聚醚砜组合物包含仅由3,3-双（4-羟基苯基）-N-苯基邻苯二甲酰亚胺衍生的结构基团和4,4'-双（（4-氯苯基）磺酰基） 1'-联苯并且表现出大于300℃的单一玻璃化转变。
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公开(公告)号：US07268237B2
公开(公告)日：2007-09-11
申请号：US11078022
申请日：2005-03-11
IPC分类号： C07D493/02
CPC分类号： C07C51/367 , C07C65/24
摘要： This invention is related to a method for making diether dianhydrides by the reaction of halophthalic anhydride and a metal salt of an aromatic dihydroxy compound in the presence of a solvent and a phase transfer catalyst. Typical phase transfer catalyst include guanidium salts, aminopyridinium salts, or phosphazenium salts.
摘要翻译： 本发明涉及通过卤代邻苯二甲酸酐和芳族二羟基化合物的金属盐在溶剂和相转移催化剂的存在下反应制备二醚二酸酐的方法。 典型的相转移催化剂包括胍盐，氨基吡啶鎓盐或磷氮烯基鏻盐。
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公开(公告)号：US06861482B2
公开(公告)日：2005-03-01
申请号：US10307873
申请日：2002-12-02
IPC分类号： B32B27/06 , B32B27/18 , C08G63/64 , C08G63/676 , C08G63/695 , C08F8/04 , C08G63/00
CPC分类号： B32B27/06 , B32B27/18 , C08G63/64 , C08G63/676 , C08G63/6956 , Y10T428/31565
摘要： The present invention describes the incorporation of several types of soft-block materials into resorcinol phthalate-co-polycarbonate polymers. In preferred embodiments, the soft-block materials contain aliphatic moieties or silicones as flexibilizing units. Several methods of incorporation into the copolymer structure are described including co-reaction of diols with iso/terephthaloyl chloride, replacement of the normal chainstopper with a p-alkylphenol, replacement of a portion of the bisphenol A with an aliphatic ester-bisphenol, and co-reaction of aliphatic diacid chlorides. The polymers of the present invention have good flow characteristics at temperatures generally used for coating, and have good thermostability and weatherability.
摘要翻译： 本发明描述了将几种类型的软嵌段材料并入间苯二酚邻苯二甲酸酯共共聚物聚合物中。 在优选的实施方案中，软嵌段材料含有脂族部分或硅氧烷作为柔性单元。 描述了掺入共聚物结构的几种方法，包括二醇与异对苯二甲酰氯的共反应，正链链断裂与对烷基苯酚的取代，双酚A的一部分与脂肪族酯 - 双酚的取代，以及共 - 脂肪族二酸氯化物的反应。 本发明的聚合物在通常用于涂布的温度下具有良好的流动特性，并具有良好的热稳定性和耐候性。
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39.发明授权
公开(公告)号：US6028203A
公开(公告)日：2000-02-22
申请号：US210707
申请日：1998-12-14
IPC分类号： B01J31/02 , B01J31/04 , C07B61/00 , C07D209/48 , C07D307/89 , C07D405/00 , C07D209/02 , C07D307/77
CPC分类号： C07D307/89
摘要： Oxybisphthalic compounds such as 4,4'-oxybis(N-methylphthalimide) and 4,4'-oxybis(phthalic anhydride) are prepared from the corresponding nitro- or halo-substituted phthalic compounds by reaction with an alkanoate or carbonate salt in a non-polar solvent and in the presence of a hexaalkylguanidinium salt as phase transfer catalyst. A carboxylic acid such as 4-chlorobenzoic acid may be used as an additional catalyst. Reaction rates and yields are higher than with other phase transfer catalysts.
摘要翻译： 由相应的硝基 - 或卤素取代的邻苯二甲酸化合物通过与非酸性的烷基酯或碳酸盐反应制备4,4'-氧双（4-甲基邻苯二甲酰亚胺）和4,4'-氧双（邻苯二甲酸酐） 在六烷基胍鎓盐作为相转移催化剂存在下进行。 可以使用羧酸如4-氯苯甲酸作为另外的催化剂。 反应速率和产率高于其他相转移催化剂。
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40.发明授权Method for preparing brominated polycarbonates, and products obtained thereby 失效制备溴化聚碳酸酯的方法及由此获得的产物
公开(公告)号：US5977265A
公开(公告)日：1999-11-02
申请号：US922105
申请日：1997-09-02
申请人： Patrick Joseph McCloskey , Gary Charles Davis , David Michel Dardaris , Daniel Joseph Brunelle , Robert Russell Gallucci , Mahari Tjahjadi , David Whalen , Kevin Mitchell Snow
发明人： Patrick Joseph McCloskey , Gary Charles Davis , David Michel Dardaris , Daniel Joseph Brunelle , Robert Russell Gallucci , Mahari Tjahjadi , David Whalen , Kevin Mitchell Snow
IPC分类号： C08L23/00 , C08G64/10 , C08G64/42 , C08L33/06 , C08L67/00 , C08L69/00 , H01R13/46 , H01R13/73 , C08C19/22
摘要： High flow brominated polycarbonates, useful as flame retardant additives for other polymers such as polyesters, are obtained by equilibration of a brominated aromatic polycarbonate such as a tetrabromobisphenol A homo- or copolycarbonate with a di- or polyhydroxy aromatic compound such as bisphenol A, or a diaryl carbonate, and an equilibration catalyst, under conditions such that the weight average molecular weight of the brominated polycarbonate is reduced by at least 35%. Preferred equilibration catalysts are Group I metal carboxylates, such as sodium stearate, and hexaalkylguanidinium salts.
摘要翻译： 通过将溴代芳族聚碳酸酯例如四溴双酚A均聚物或共聚碳酸酯与二羟基芳族化合物或多羟基芳族化合物如双酚A或其混合物平衡，可获得用作其它聚合物如聚酯的阻燃添加剂的高流动溴化聚碳酸酯， 碳酸二芳酯和平衡催化剂，使得溴化聚碳酸酯的重均分子量降低至少35％的条件下进行。 优选的平衡催化剂是I族金属羧酸盐，例如硬脂酸钠和六烷基胍盐。
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