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公开(公告)号:US20140106225A1
公开(公告)日:2014-04-17
申请号:US14107713
申请日:2013-12-16
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Shinsuke MATSUNO , Dai Yamamoto , Hideki Satake , Norio Takami
CPC classification number: H01M4/136 , H01M2/023 , H01M4/366 , H01M4/485 , H01M4/5825 , H01M10/0525 , Y02E60/122 , Y02T10/7011
Abstract: A non-aqueous electrolyte secondary battery includes a positive electrode containing active material particles composed of a core section formed of olivine type LiFePO4; an intermediate section that lies on the outer side of the core section and has LiFexPyOz; and a surface section that lies on the outer side of the intermediate section and has LiFeaPbOc; and a negative electrode containing lithium titanate, in which battery the molar concentration ratio of Fe relative to P at the core section is greater than the average of x/y of LiFexPyOz, the average value of a/b of LiFeaPbOc at the surface section of the positive electrode active material particles is smaller than the average of x/y of LiFexPyOz, and the positive electrode active material particles include a region in which x/y of LiFexPyOz at the intermediate section increases continuously or intermittently in the direction from the surface section toward the core section.
Abstract translation: 非水电解质二次电池包括含有由橄榄石型LiFePO 4形成的芯部构成的活性物质粒子的正极; 位于所述芯部的外侧并具有LiFexPyOz的中间部; 以及位于中间部分的外侧并具有LiFeaPbOc的表面部分; 以及含有钛酸锂的负极,其中电池在铁芯部分的Fe相对于P的摩尔浓度比大于LiFexPyOz的x / y的平均值,LiFeaPbOc在表面的平均值a / b的平均值 正极活性物质粒子小于LiFexPyOz的x / y的平均值,正极活性物质粒子包括其中在中间部分的x / y的LiFexPyOz在表面部分的方向上连续或间歇地增加的区域 朝核心部分。
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32.
公开(公告)号:US20240079576A1
公开(公告)日:2024-03-07
申请号:US18458267
申请日:2023-08-30
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Kakuya UEDA , Yoshiaki MURATA , Yasuhiro HARADA , Norio TAKAMI , Shinsuke MATSUNO
IPC: H01M4/485 , H01M10/0525
CPC classification number: H01M4/485 , H01M10/0525 , H01M2004/021 , H01M2220/20
Abstract: A niobium-titanium-based oxide includes niobium-titanium-based oxide particles, wherein an Si2p peak area and an Nb3d peak area, as measured by X-ray photoelectron spectroscopy for the niobium-titanium-based oxide particles, satisfy a ratio A of 0.40≤A≤1.0, provided that the ratio A is the Si2p peak area/the Nb3d peak area.
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公开(公告)号:US20230327097A1
公开(公告)日:2023-10-12
申请号:US17823544
申请日:2022-08-31
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Yasunobu YAMASHITA , Yorikazu YOSHIDA , Yasuhiro HARADA , Norio TAKAMI , Shinsuke MATSUNO
IPC: H01M4/485 , H01M4/505 , H01M4/62 , H01M50/574
CPC classification number: H01M4/485 , H01M4/505 , H01M4/625 , H01M50/574 , H01M2004/021
Abstract: In general, according to one embodiment, an electrode including a mixture layer containing a titanium-containing oxide and a conductive agent is provided. The electrode satisfies expression (1). Where, L* is a lightness of the electrode according to JISZ8722:2009. Also, ri is a particle size for the mixture layer at a volume cumulative frequency dx, where i is a natural number from 1 to 9. The volume cumulative frequency dx is a volume-based cumulative frequency for which accumulation starts with a smaller particle size. The volume cumulative frequency dx takes a value from 10% to 90% in increments of 10%.
7.0
≤
100
−
L
∗
/
∑
1
9
1
r
i
d
i
≤
11.0
(1)-
公开(公告)号:US20220294077A1
公开(公告)日:2022-09-15
申请号:US17446864
申请日:2021-09-03
Applicant: Kabushiki Kaisha Toshiba
Inventor: Yasuyuki HOTTA , Takashi KUBOKI , Shinsuke MATSUNO , Norio TAKAMI
IPC: H01M50/446 , H01M50/431 , H01M50/426
Abstract: An electrode group includes a negative electrode, a positive electrode and a separator. The negative electrode includes a negative electrode active material-containing layer and a mesh negative electrode current collector. The positive electrode includes a positive electrode active material-containing layer. The separator includes a composite membrane containing inorganic solid particles and a polymer material. At least one of a first polymer material constituting the negative electrode active material-containing layer is the same as a second polymer material. A ratio a/b of denseness a and denseness b is greater than 1.05. A peeling strength σ1 is greater than a peeling strength σ2. An air permeability coefficient of a joined body of the composite membrane and the negative electrode is 1×10−19 m2 or more and 1×10−15 m2 or less.
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35.
公开(公告)号:US20210083251A1
公开(公告)日:2021-03-18
申请号:US16804489
申请日:2020-02-28
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Yasuyuki HOTTA , Hayato SEKI , Kazuomi YOSHIMA , Shinsuke MATSUNO , Norio TAKAMI
IPC: H01M2/16 , H01M10/24 , H01M10/054 , H01M10/0562 , H01M10/42 , H01M4/485 , H01M4/66 , H01M2/10
Abstract: According to one embodiment, a separator is provided. The separator includes a composite membrane. The composite membrane includes a substrate layer, a first composite layer, and a second composite layer. The first composite layer is located on one surface of the substrate layer. The second composite layer is located on the other surface of the substrate layer. The composite membrane has a coefficient of air permeability of 1×10−14 m2 or less. The first composite layer has a first surface and a second surface. The first surface is in contact with the substrate layer. The second surface is located on an opposite side to the first surface. Denseness of a portion including the first surface is lower than denseness of a portion including the second surface in the first composite layer.
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公开(公告)号:US20200303783A1
公开(公告)日:2020-09-24
申请号:US16718496
申请日:2019-12-18
Applicant: Kabushiki Kaisha Toshiba
Inventor: Yumiko SEKIGUCHI , Shinsuke MATSUNO , Norio TAKAMI
Abstract: A secondary battery includes a positive electrode, a negative electrode and an electrolyte containing aqueous electrolyte. The negative electrode is provided with a negative electrode current collector having a compound including aluminum, and a negative electrode active material including titanium on a granule surface of the negative electrode current collector. A ratio of an atomic concentration of aluminum atoms to sum of atomic concentrations of aluminum atoms and titanium atoms on a surface of the negative electrode ({Al atomic concentration/(Al atomic concentration+Ti atomic concentration)}×100) is 3 atm % or more and 30 atm % or less.
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公开(公告)号:US20190296357A1
公开(公告)日:2019-09-26
申请号:US16118993
申请日:2018-08-31
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Hayato SEKI , Yumiko SEKIGUCHI , Kazuomi YOSHIMA , Yasuyuki HOTTA , Shinsuke MATSUNO , Norio TAKAMI
Abstract: According to one embodiment, provided is a secondary battery including an aqueous electrolyte, a positive electrode, and a negative electrode. A compound containing an element A is present on at least a part of the surface of the negative electrode. The element A is at least one selected from the group consisting of Hg, Pb, Zn, and Bi. According to scanning electron microscopy, a region where the compound containing the element A is present accounts
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公开(公告)号:US20190296344A1
公开(公告)日:2019-09-26
申请号:US16118967
申请日:2018-08-31
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Hayato SEKI , Yumiko SEKIGUCHI , Kazuomi YOSHIMA , Yasuyuki HOTTA , Shinsuke MATSUNO , Norio TAKAMI
Abstract: According to one embodiment, provided is a secondary battery including an aqueous electrolyte, a positive electrode, and a negative electrode, where the negative electrode includes a negative electrode active material containing a Ti-containing composite oxide. At least one element A selected from the group consisting of Hg, Pb, Zn, and Bi is present on a surface of the negative electrode. An average of molar ratios (A/(A+Ti)) of the element A is more than or equal to 5% and less than or equal to 40%. Each of the molar ratios is a molar amount of the element A to a sum between the molar amount of the element A and a molar amount of Ti on the surface of the negative electrode, according to scanning electron microscopy-energy dispersive X-ray spectroscopy.
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公开(公告)号:US20190288327A1
公开(公告)日:2019-09-19
申请号:US16122248
申请日:2018-09-05
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Yasunobu YAMASHITA , Shinsuke MATSUNO , Norio TAKAMI , Hiroki INAGAKI
IPC: H01M10/0525 , H01M4/485 , H01M10/42 , H01M10/36
Abstract: According to one embodiment, a battery module includes a battery unit. The battery unit includes a nonaqueous lithium ion battery including a nonaqueous electrolyte, and an aqueous lithium ion battery including an electrolytic solution in which an electrolyte is dissolved in an aqueous solvent. In the battery unit, the aqueous lithium ion battery is connected in parallel to the nonaqueous lithium ion battery.
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公开(公告)号:US20170271682A1
公开(公告)日:2017-09-21
申请号:US15457167
申请日:2017-03-13
Applicant: KABUSHIKI KAISHA TOSHIBA
Inventor: Shinsuke MATSUNO , Norio TAKAMI , Yasunobu YAMASHITA , Hiroki INAGAKI
CPC classification number: H01M4/661 , B60L7/16 , B60L11/18 , B60L11/1864 , H01M4/02 , H01M4/366 , H01M4/48 , H01M4/485 , H01M4/62 , H01M4/662 , H01M4/667 , H01M10/24 , H01M10/36 , H01M10/4207 , H01M10/425 , H01M10/44 , H01M10/486 , H01M2220/20 , H01M2300/0002
Abstract: According to one embodiment, a secondary battery is provided. The secondary battery includes a positive electrode, a negative electrode, and an electrolyte solution. The negative electrode includes a negative electrode current collector including elemental zinc, and a negative electrode layer disposed on the negative electrode current collector. The negative electrode layer includes a negative electrode active material including at least one compound selected from the group consisting of an oxide of titanium, a lithium-titanium oxide, and a lithium-titanium composite oxide. The electrolyte solution includes an aqueous solvent and an electrolyte.
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