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    METHOD OF MAKING FLUOROPOLYMER DISPERSION
    35.
    发明申请
    METHOD OF MAKING FLUOROPOLYMER DISPERSION 有权
    制备氟聚合物分散体的方法

    公开(公告)号：US20070015864A1

    公开(公告)日：2007-01-18

    申请号：US11420386

    申请日：2006-05-25

    申请人： Klaus Hintzer ,  Michael Jurgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Lochhaas ,  Andreas Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael Dadalas ,  George Moore ,  Jay Schulz ,  Richard Flynn

    发明人： Klaus Hintzer ,  Michael Jurgens ,  Harald Kaspar ,  Herbert Koenigsmann ,  Kai Lochhaas ,  Andreas Maurer ,  Werner Schwertfeger ,  Tilman Zipplies ,  Ludwig Mayer ,  Michael Dadalas ,  George Moore ,  Jay Schulz ,  Richard Flynn

    IPC分类号： C08L27/12

    CPC分类号： C08L27/12 ,  C08L71/02 ,  Y02C20/30 ,  C08L2666/22

    摘要： A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+  (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3; Then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.

    摘要翻译： 首先提供含氟聚合物颗粒和一种或多种选自氟化羧酸或其盐的含氟表面活性剂的含氟聚合物分散体的制备氟聚合物分散体的方法，所述氟化聚合物分散体具有以下通式：<？in-line-formula description =“In-Line Formulas” （I）结束=“引导”→[R f> OL O> - ））））））））））））））））））））））））） <？in-line-formula description =“In-line formula”end =“tail”？>其中L表示线性部分或完全氟化的亚烷基或脂族烃基，R f表示 线性部分或全氟化的脂族基团或被一个或多个氧原子间隔的线性部分或完全氟化的脂肪族基团，表示i为i且i为1,2或3的阳离子; 然后加入一种或多种选自阴离子和非离子表面活性剂的非氟化表面活性剂，然后将一种或多种氟化表面活性剂的总量减少至不超过500ppm，例如不超过250ppm，基于 分散体的总重量，同时保持或增加分散体中固体的量。

    Aqueous Dispersions of Polytetrafluoroethylene Having a Low Amount of Fluorinated Surfactant
    36.
    发明申请
    Aqueous Dispersions of Polytetrafluoroethylene Having a Low Amount of Fluorinated Surfactant 有权
    具有少量氟化表面活性剂的聚四氟乙烯的水性分散体

    公开(公告)号：US20060128872A1

    公开(公告)日：2006-06-15

    申请号：US11275959

    申请日：2006-02-07

    申请人： Tilman Zipplies ,  Klaus Hintzer ,  Michael Dadalas ,  Gernot Loehr

    发明人： Tilman Zipplies ,  Klaus Hintzer ,  Michael Dadalas ,  Gernot Loehr

    IPC分类号： C08G18/62

    CPC分类号： C09D127/18 ,  C08F6/16 ,  C08F214/26 ,  C08L27/18 ,  C08L71/02 ,  C08L2666/02 ,  C08L2666/22

    摘要： An aqueous non-melt processible polytetrafluoroethylene dispersion having non-melt processible polytetrafluoroethylene particles in an amount of 30 to 70% by weight and an amount of non-ionic surfactant between 2 and 15% by weight based on the weight of polytetrafluoroethylene solids. The dispersion is free of fluorinated surfactant or contains fluorinated surfactant in amounts of not more than 200 ppm based on the amount of polytetrafluoroethylene solids. At least part of the non-melt processible polytetrafluoroethylene particles comprise an effective amount of ionic end groups in the polytetrafluoroethylene polymer chains.

    摘要翻译： 一种水溶性可熔融加工的聚四氟乙烯分散体，其具有30至70重量％的非熔体加工的聚四氟乙烯颗粒和基于聚四氟乙烯固体重量的2至15重量％的非离子表面活性剂的量。 该分散体不含氟化表面活性剂，或含有基于聚四氟乙烯固体量不大于200ppm的含氟表面活性剂。 至少部分不可熔融加工的聚四氟乙烯颗粒在聚四氟乙烯聚合物链中包含有效量的离子端基。

    Fluoropolymer for making a fluoroelastomer
    37.
    发明申请
    Fluoropolymer for making a fluoroelastomer 审中-公开
    用于制造含氟弹性体的含氟聚合物

    公开(公告)号：US20060052557A1

    公开(公告)日：2006-03-09

    申请号：US11198991

    申请日：2005-08-08

    申请人： Harald Kaspar ,  Klaus Hintzer

    发明人： Harald Kaspar ,  Klaus Hintzer

    IPC分类号： C08F214/18

    CPC分类号： C08F214/18 ,  C08F214/186

    摘要： In accordance with one aspect of the invention, there is provided (i) an amorphous fluoropolymer that has one or more cure site components, the cure site components being contained in the amorphous fluoropolymer in an amount between 0.1 and 0.5 mol % based on the total amount of repeating units and/or (ii) the amorphous fluoropolymer is capable of being dehydrofluorinated, wherein the amorphous fluoropolymer is derivable from a polymerization of (a) one or more gaseous fluorinated monomers and (b) not more than 0.5% by weight based on the total weight of monomers of one or more olefins having a bromine or iodine atom bonded to a carbon of the double bond of the olefin.

    摘要翻译： 根据本发明的一个方面，提供（i）具有一个或多个固化部位成分的无定形含氟聚合物，所述无定形含氟聚合物中的固化部位成分以基于总量的0.1至0.5mol％ 重复单元的量和/或（ii）无定形含氟聚合物能够脱氟化氢，其中无定形含氟聚合物可衍生自（a）一种或多种气态氟化单体的聚合，和（b）不超过0.5重量％ 关于具有与烯烃的双键结合的溴或碘原子的一种或多种烯烃的单体的总重量。

    Primer coating of PTFE for metal substrates
    38.
    发明申请
    Primer coating of PTFE for metal substrates 有权
    用于金属基材的PTFE底漆涂层

    公开(公告)号：US20060003168A1

    公开(公告)日：2006-01-05

    申请号：US11172345

    申请日：2005-06-30

    申请人： Michael Dadalas ,  Klaus Hintzer ,  Gernot Loehr ,  Tilman Zipplies

    发明人： Michael Dadalas ,  Klaus Hintzer ,  Gernot Loehr ,  Tilman Zipplies

    IPC分类号： B32B27/00

    CPC分类号： C09D179/08 ,  C08L27/08 ,  C09D5/002 ,  C09D177/00 ,  C09D179/04 ,  C09D181/06 ,  Y10T428/3154 ,  C08L2666/14 ,  C08L2666/04

    摘要： The present invention provides an aqueous coating composition comprising (i) particles of a non-melt processible polymer of tetrafluoroethylene and (ii) a non-fluorinated polymer selected from the group consisting of a polysulfone, a polyamide, a polyimide, a polyamide-imide, a polybismaleimide and mixtures thereof, wherein said particles are core-shell particles whereby the shell comprises a copolymer of tetrafluoroethylene and a partially fluorinated or non-fluorinated comonomer. The aqueous coating composition may be used for providing a primer coating on a substrate such as a metal or glass substrate. Such primer coating may provide good or excellent non-stick coatings combined with good or excellent scratch and wear resistance of the coating. Also, such primer coating may provide for good to excellent PTFE coatings that can resist hot salt water. The aqueous coating composition may also be used to provide other coating layers of a multi-layer coating.

    摘要翻译： 本发明提供一种水性涂料组合物，其包含（i）四氟乙烯的不可熔融加成聚合物的颗粒和（ii）选自聚砜，聚酰胺，聚酰亚胺，聚酰胺 - 酰亚胺的非氟化聚合物 ，多双马来酰亚胺及其混合物，其中所述颗粒是核 - 壳颗粒，其中壳包含四氟乙烯和部分氟化或非氟化共聚单体的共聚物。 水性涂​​料组合物可以用于在诸如金属或玻璃基材的基材上提供底漆涂层。 这种底漆涂层可以提供良好或优异的不粘涂层，同时具有涂层的良好或优异的耐擦伤性和耐磨性。 此外，这种底漆涂层可以提供可耐受热盐水的良好至优异的PTFE涂层。 水性涂​​料组合物也可用于提供多层涂层的其它涂层。

    Fluoropolymer compositions containing a nitrogen cure site monomer
    39.
    发明授权
    Fluoropolymer compositions containing a nitrogen cure site monomer 有权
    含有氮固化点单体的含氟聚合物组合物

    公开(公告)号：US06844388B2

    公开(公告)日：2005-01-18

    申请号：US10122489

    申请日：2002-04-11

    申请人： Werner M. A. Grootaert ,  Robert E. Kolb ,  Klaus Hintzer

    发明人： Werner M. A. Grootaert ,  Robert E. Kolb ,  Klaus Hintzer

    IPC分类号： C08L101/06 ,  C08F14/18 ,  C08K3/04 ,  C08K5/00 ,  C08K5/50 ,  C08F8/00

    CPC分类号： C08K5/0025 ,  C08K5/50 ,  C08L27/12 ,  C08L27/18

    摘要： A composition of (a) a fluoropolymer having interpolymerized units derived from a nitrogen-containing cure site monomer; and (b) a nonfluorinated catalyst composition that includes a compound having the general formula: {RA}(−){QR′k}(+) or in certain cases the precursors thereof, wherein R is hydrogen, an alkyl, alkenyl, cycloalkyl, cycloalkenyl, aryl or aralkyl, A is an acid- or acid-derivative anion, Q is phosphorous, sulfur, nitrogen, arsenic, or antimony, and each R′ is hydrogen or an alkyl, aryl, aralkyl, or alkenyl group, k is the valence of Q; and optionally (c) an alcohol of the formula R2—OH, wherein R2 is an alkyl group which can be partially fluorinated. Also provided are a method of making a fluoropolymer, a method of increasing induction time, and fluoropolymer articles containing curable or cured fluoropolymer compositions.

    摘要翻译： （a）具有衍生自含氮固化位点单体的共聚单元的含氟聚合物的组合物; （b）非氟化催化剂组合物，其包含具有以下通式的化合物：{RA}（（ - ）> {Q'k}（（+））或在某些情况下为其前体，其中R为氢，烷基 ，烯基，环烷基，环烯基，芳基或芳烷基，A是酸或酸衍生的阴离子，Q是磷，硫，氮，砷或锑，并且每个R'是氢或烷基，芳基，芳烷基或 烯基，k是Q的化合价; 和任选地（c）式R 2 -OH的醇，其中R 2是可部分氟化的烷基。 还提供了制备含氟聚合物的方法，增加诱导时间的方法和含有可固化或固化的含氟聚合物组合物的含氟聚合物制品。

    Process for producing fluoropolymers having a reduced amount of polar end groups
    40.
    发明授权
    Process for producing fluoropolymers having a reduced amount of polar end groups 有权
    制备极性端基量少的含氟聚合物的方法

    公开(公告)号：US06812310B2

    公开(公告)日：2004-11-02

    申请号：US10452523

    申请日：2003-06-02

    申请人： Werner M. A. Grootaert ,  Klaus Hintzer ,  Bernhard Hirsch ,  Harald Kaspar ,  Gernot Löhr ,  Franz März ,  Guy Van Gool

    发明人： Werner M. A. Grootaert ,  Klaus Hintzer ,  Bernhard Hirsch ,  Harald Kaspar ,  Gernot Löhr ,  Franz März ,  Guy Van Gool

    IPC分类号： C08F11418

    CPC分类号： C08F214/262 ,  C08F214/267

    摘要： A fluoropolymer having a reduced amount of polar end groups. The fluoropolymer is produced by free radical polymerization of fluorinated monomers and the initiation of the polymerization is carried out in the presence of a chloride salt. Polar end groups include hydroxy groups and ionized or ionizable end groups. Examples of ionized or ionizable end groups include acid groups and salts thereof such as sulfonic acid and salts thereof, —CH2—OSO3H groups, sulfates and carbonyl containing end groups such as carboxylic and carboxylate groups. Due to the presence of chloride salt at the initiation of the free radical polymerization, CF2Cl end groups are formed instead of the polar end groups. As a result, a fluoropolymer is obtained that has improved processibility and heat resistance.

    摘要翻译： 具有极性端基量减少的含氟聚合物。 含氟聚合物通过氟化单体的自由基聚合制备，并且聚合的引发在氯化物盐的存在下进行。 极性端基包括羟基和电离或可离子化端基。 电离或可离子化端基的实例包括酸基及其盐，例如磺酸及其盐，-CH 2 -OSO 3 H基，硫酸酯和含羰基的端基如羧酸和羧酸酯基。 由于在自由基聚合开始时存在氯化物盐，而是形成CF 2 Cl端基，而不是极性端基。 结果，得到具有改善的加工性和耐热性的含氟聚合物。