摘要:
The present disclosure describes fluoropolymers having long chain branches and methods of making these fluoropolymers. These fluoropolymers may have improved melt processing properties. Shaped articles containing these fluoropolymers are also provided.
摘要:
Described herein is a composition comprising an aqueous polymerization reaction product of fluorinated monomers and wherein the polymerization is initiated (i) in the absence of a fluorinated emulsifier and whereby no fluorinated emulsifier is added during polymerization or (ii) in the presence of an fluorinated emulsifier selected from: [Rf—O-L-COO-]i Xi+ (I) wherein L represents a linear or branched, non-fluorinated, partially fluorinated, or fully fluorinated alkylene group, Rf represents a linear or branched partially or fully fluorinated aliphatic group or a linear or branched partially or fully fluorinated aliphatic group interrupted with at least one oxygen atom, Xi+ represents a cation having the valence i and i is 1, 2 or 3; wherein the reaction product and/or the resulting aqueous phase are substantially free of di- and tri-alkylamines and substantially free of low molecular weight fluoroorganic compounds and methods thereof.
摘要翻译:本文描述的是包含氟化单体的水性聚合反应产物的组合物,其中聚合反应开始于(i)在不存在氟化乳化剂的情况下,并且由此在聚合过程中不加入氟化乳化剂,或(ii)在氟化乳化剂存在下 选自:[Rf-OL-COO-] i Xi +(I)其中L表示直链或支链,非氟化,部分氟化或完全氟化的亚烷基,Rf表示直链或支链部分或完全氟化的脂族基团或 间隔有至少一个氧原子的直链或支链部分或完全氟化的脂肪族基团,X i +表示i为i且i为1,2或3的阳离子; 其中所述反应产物和/或所得水相基本上不含二烷基胺和三烷基胺,并且基本上不含低分子量氟代有机化合物及其方法。
摘要:
Provided are curable fluoroelastomers. Further provided are methods of making the curable elastomers, curable fluoroelastomer compositions and methods of making them and shaped articles made from the curable fluoroelastomer compositions.
摘要:
Described herein is a polymerizable composition substantially free of an organic emulsifier, methods of making, and articles thereof. The polymerizable composition comprises: a continuous phase; a polymerizable monomer; an initiator; and inorganic nanoparticles, wherein the inorganic nanoparticles are substantially free of groups that will copolymerize with the polymerizable monomer.
摘要:
A method for removing a fluorinated carboxylic acid or salt thereof from an aqueous liquid by contacting the aqueous liquid with adsorbent particles. The fluorinated carboxylic acid or salt thereof is selected from the group consisting of partially fluorinated carboxylic acids or salts thereof and fully fluorinated carboxylic acids or salts thereof.
摘要:
The present disclosure describes fluoropolymers having long chain branches and methods of making these fluoropolymers. These fluoropolymers may have improved melt processing properties. Shaped articles containing these fluoropolymers are also provided.
摘要:
A method of making a fluoropolymer dispersion by first providing a fluoropolymer dispersion comprising fluoropolymer particles and one or more fluorinated surfactants selected from fluorinated carboxylic acids or salts thereof having the general formula: [Rf—O-L-COO−]iXi+ (I) wherein L represents a linear partially or fully fluorinated alkylene group or an aliphatic hydrocarbon group, Rf represents a linear partially or fully fluorinated aliphatic group or a linear partially or fully fluorinated aliphatic group interrupted with one or more oxygen atoms, Xi+ represents a cation having the valence i and i is 1, 2 or 3; Then adding one or more non-fluorinated surfactants selected from anionic and non-ionic surfactants followed by reducing the total amount of the one or more fluorinated surfactants to an amount of not more than 500 ppm, for example not more than 250 ppm based on the total weight of the dispersion while maintaining or increasing the amount of solids in the dispersion.
摘要:
In accordance with one aspect of the invention, there is provided (i) an amorphous fluoropolymer that has one or more cure site components, the cure site components being contained in the amorphous fluoropolymer in an amount between 0.1 and 0.5 mol % based on the total amount of repeating units and/or (ii) the amorphous fluoropolymer is capable of being dehydrofluorinated, wherein the amorphous fluoropolymer is derivable from a polymerization of (a) one or more gaseous fluorinated monomers and (b) not more than 0.5% by weight based on the total weight of monomers of one or more olefins having a bromine or iodine atom bonded to a carbon of the double bond of the olefin.
摘要:
A fluoropolymer having a reduced amount of polar end groups. The fluoropolymer is produced by free radical polymerization of fluorinated monomers and the initiation of the polymerization is carried out in the presence of a chloride salt. Polar end groups include hydroxy groups and ionized or ionizable end groups. Examples of ionized or ionizable end groups include acid groups and salts thereof such as sulfonic acid and salts thereof, —CH2—OSO3H groups, sulfates and carbonyl containing end groups such as carboxylic and carboxylate groups. Due to the presence of chloride salt at the initiation of the free radical polymerization, CF2Cl end groups are formed instead of the polar end groups. As a result, a fluoropolymer is obtained that has improved processibility and heat resistance.