公开(公告)号：US20090052043A1

公开(公告)日：2009-02-26

申请号：US11884378

申请日：2006-02-21

申请人： Yukimitsu Iwata ,  Koichi Mikami ,  Yoshihiro Nishimura ,  Takashi Kodama

发明人： Yukimitsu Iwata ,  Koichi Mikami ,  Yoshihiro Nishimura ,  Takashi Kodama

IPC分类号： G02B5/00

CPC分类号： G02B5/02 ,  G02F1/133502

摘要： An optical laminate having a light transparent base material and an anti-dazzling layer provided on the light transparent base material, wherein the outermost surface of the anti-dazzling layer has a concavoconvex surface. The concavoconvex shape simultaneously satisfies the following formulae (I) 1.2≦θa≦2.5 and (II) 0.004≦ψ≦0.18, wherein θa represents the average inclination angle of the concavoconvex part; Rz represents the average roughness of concavoconvexes; Sm represents the average spacing of the concavoconvexes; and ψ represents the ratio, between Rz and Sm, defined by ψ=Rz/Sm. The optical laminate has an internal haze value of not less than 0% and not more than 50%, and the optical laminate has a surface haze value of not less than 0.5% and not more than 4.5%.

摘要翻译： 一种具有透光基材和防透光层的光学层叠体，其设置在透光基材上，其中防炫目层的最外表面具有凹凸表面。 凹凸形状同时满足以下公式（I）1.2 <=θa<= 2.5和（II）0.004 <= psi <= 0.18，其中θa表示凹凸部分的平均倾斜角; Rz表示凹凸的平均粗糙度; Sm表示凹凸的平均间距; psi表示由psi = Rz / Sm定义的Rz和Sm之间的比率。 光学层叠体的内部雾度值为0％以上且50％以下，光学层叠体的表面雾度值为0.5％以上且4.5％以下。

公开(公告)号：US20090021834A1

公开(公告)日：2009-01-22

申请号：US11884404

申请日：2006-02-21

申请人： Yukimitsu Iwata ,  Koichi Mikami ,  Yoshihiro Nishimura ,  Takashi Kodama

发明人： Yukimitsu Iwata ,  Koichi Mikami ,  Yoshihiro Nishimura ,  Takashi Kodama

IPC分类号： G02B1/10

CPC分类号： G02B5/0278 ,  G02B5/0226 ,  G02B5/0294 ,  G02F1/133502 ,  Y10T428/24669 ,  Y10T428/249994

摘要： An anti-dazzling laminate formed from an optical laminate having a light transparent base material and an anti-dazzling layer provided on the light transparent base material. The optical laminate is produced by providing the light transparent base material and forming the anti-dazzling layer having a concavoconvex shape on the light transparent base material, wherein the concavoconvex shape of the anti-dazzling layer satisfies the following requirements: Sm is not less than 100 μm and not more than 600 μm, θa is not less than 0.1 degree and not more than 1.2 degrees, and Rz is more than 0.2 μm and not more than 1 μm, wherein Sm represents the average spacing of concavoconvexes (or profile irregularities) in the anti-dazzling layer; θa represents the average inclination angle of the concavoconvexes (or profile irregularities); and Rz represents the average roughness of the concavoconvexes (or profile irregularities).

摘要翻译： 由透光性基材和防透光层构成的光学层叠体形成的抗光泽层叠体，设置在透光性基材上。 通过提供透光性基材并在透光性基材上形成具有凹凸形状的防眩光层，制造光学层叠体，其中，防眩光层的凹凸形状满足以下要求：Sm不小于 100μm，600μm以下，θa为0.1度以上且1.2d以下，Rz大于0.2μm，1μm以下，其中，Sm为凹凸的平均间隔（或轮廓不规则） 在防炫光层; thetaa表示凹凸（或轮廓不规则）的平均倾斜角; 并且Rz表示凹凸的平均粗糙度（或轮廓不规则）。

公开(公告)号：US20090002831A1

公开(公告)日：2009-01-01

申请号：US11817818

申请日：2006-03-29

申请人： Koichi Mikami ,  Yukimitsu Iwata ,  Yoshihiro Nishimura ,  Takashi Kodama

发明人： Koichi Mikami ,  Yukimitsu Iwata ,  Yoshihiro Nishimura ,  Takashi Kodama

IPC分类号： G02B1/11

CPC分类号： G02B1/111 ,  G02B5/02 ,  G02B5/3033 ,  Y10T428/1036 ,  Y10T428/24372 ,  Y10T428/24537 ,  Y10T428/2457 ,  Y10T428/25 ,  Y10T428/26

摘要： An anti-dazzling laminate made of an optical laminate including a light transparent base material and an anti-dazzling layer having a concavoconvex shape provided on the material. The laminate simultaneously satisfies formulae: 0≦G100≦15 (I), 0.1≦Hs≦5.0 (II), 0.3≦Rz≦1.8 (III) wherein G100 represents a scintillation value which is a standard deviation of a variation in brightness distribution at a resolution of 100 ppi measured on the surface of the laminate; Hs represents the surface haze value of the laminate; and Rz represents the average roughness of the concavoconvex shape of the anti-dazzling layer.

摘要翻译： 由光学层压制品制成的防光泽层压材料，该层压材料包括透明基材和具有凹凸形状的抗眩光层。 层压板同时满足公式：0 <= G100 <= 15（I），0.1 <= Hs <= 5.0（II），0.3 <= Rz <= 1.8（III）其中G100表示​​闪烁值， 在层压体的表面上测量的分辨率为100ppi的亮度分布的变化; Hs表示层压板的表面雾度值; Rz表示防炫目层的凹凸形状的平均粗糙度。

公开(公告)号：US07439926B2

公开(公告)日：2008-10-21

申请号：US10530135

申请日：2004-06-22

申请人： Koichi Mikami ,  Noboru Matsuoka

发明人： Koichi Mikami ,  Noboru Matsuoka

IPC分类号： H01Q1/42 ,  H01Q21/00

CPC分类号： H01Q19/106 ,  H01Q7/00 ,  H01Q9/16 ,  H01Q9/285 ,  H01Q15/18 ,  H01Q19/10 ,  H01Q19/13

摘要： A planar antenna fitted with a reflector of small shape and small depth. A reflector 21 of planar shape is provided at the rear face of a radiator 20 of planar shape made of a triangular loop element. The side sections 21b on both sides of the reflector 21 are bent towards the radiator 20 and the separation .alpha.2 between the leading edges of the side sections 21b and the side edges of the radiator 20 is thereby reduced. In this way, an excellent electrical characteristic of the planar antenna 2 fitted with a reflector and can be achieved by reducing the separation D2 of the radiator 20 and reflector 21.

摘要翻译： 一种平面天线，其装配有小形状和小深度的反射器。 平面形状的反射器21设置在由三角形环形元件制成的平面形状的散热器20的后表面。 反射器21的两侧的侧部部分21b朝向散热器20弯曲并分离。 从而减小了侧部21b的前缘和散热器20的侧边缘之间的距离。 这样，搭载有反射体的平面天线2的电气特性良好，能够减小散热器20和反射体21的分离距离D 2。

公开(公告)号：US20060142603A1

公开(公告)日：2006-06-29

申请号：US11353533

申请日：2006-02-13

申请人： Koichi Mikami ,  Noboru Sayo

发明人： Koichi Mikami ,  Noboru Sayo

IPC分类号： C07F15/00 ,  C07C29/14

CPC分类号： C07F9/65527 ,  B01J31/1805 ,  B01J31/2409 ,  B01J2231/643 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  C07B2200/07 ,  C07C29/145 ,  C07C211/65 ,  C07F9/5022 ,  C07F9/5027 ,  C07F9/65517 ,  C07F9/65522 ,  C07F15/0046 ,  C07F15/0053 ,  C07C33/22 ,  C07C33/18 ,  C07C33/46

摘要： A novel transition metal complex, preferably a ruthenium-phosphine complex or rhodium-phosphine complex, which is effectively usable in various asymmetric syntheses and, in particular, is more effectively usable in the asymmetric hydrogenation of various ketones; and a novel process for producing an optically active alcohol with the complex. The novel transition metal complex includes a ligand obtained by introducing a diarylphosphino group into each of the 2- and 2′-positions of diphenyl ether, benzophenone, benzhydrol, or the like. It preferably further includes an optically active 1,2-diphenylethylenediamine coordinated thereto. The complex preferably is a novel diphosphine-ruthenium-optically active diamine complex or diphosphine-rhodium-optically active diamine complex. The process comprises using the complex as an asymmetric hydrogenation catalyst to conduct the asymmetric hydrogenation of a ketone compound to thereby obtain an optically active alcohol in a high optical purity and a high yield.

摘要翻译： 一种新颖的过渡金属络合物，优选钌膦络合物或铑 - 膦配合物，其可有效地用于各种不对称合成，特别是更有效地用于各种酮的不对称氢化; 以及用该复合物生产光学活性醇的新方法。 新型过渡金属络合物包括通过将二芳基膦基引入二苯基醚，二苯甲酮，二苯甲醇等的2位和2位中的每一个得到的配位体。 其优选还包括与其配位的光学活性1,2-二苯基乙二胺。 络合物优选为新型二膦 - 钌 - 光学活性二胺络合物或二膦 - 铑光学活性二胺络合物。 该方法包括使用络合物作为不对称氢化催化剂进行酮化合物的不对称氢化，从而获得高光学纯度和高收率的光学活性醇。

公开(公告)号：US06596887B2

公开(公告)日：2003-07-22

申请号：US09805364

申请日：2001-03-14

申请人： Koichi Mikami ,  Toshinobu Korenaga ,  Noboru Sayo

发明人： Koichi Mikami ,  Toshinobu Korenaga ,  Noboru Sayo

IPC分类号： C07F1500

CPC分类号： C07F15/0053 ,  B01J31/1805 ,  B01J31/2409 ,  B01J31/2452 ,  B01J31/28 ,  B01J2231/643 ,  B01J2531/0266 ,  B01J2531/821 ,  C07C29/145 ,  C07C211/58 ,  C07C33/22 ,  C07C33/18

摘要： Provided is a process for preparing an optically active ruthenium-phosphine complex represented by the following formula (1): wherein L represents a bidentate ligand compound of a tertiary phosphine; X represents a halogen atom; and * means chiral center (L* is an optically active substance), which comprises reacting a ruthenium-phosphine complex represented by: RumXnLpAq or [RuX(D)(L)]X wherein, X and L have the same meanings as described above (L is a racemic modification); A represents triethylamine (Et3N), etc.; and m, n, p and q each stands for an integer and D represents benzene, etc. with ½ equivalent of a specific optically active chiral diamine, thereby inactivating one of the enantiomers; and then with a specific optically active diamine derivative, thereby activating the other enantiomer.

摘要翻译： 本发明提供一种由下式（1）表示的光学活性钌膦络合物的制备方法：其中L表示叔膦的二齿配体化合物; X表示卤原子; 和*表示手性中心（L *是光学活性物质），其包括使由下式表示的钌 - 膦配合物反应：其中X和L具有与上述相同的含义（L为外消旋修饰）。 A表示三乙胺（Et 3 N）等。 m，n，p和q各自表示整数，D表示苯等，与1/2当量的特定光学活性手性二胺，从而使一种对映体失活; 然后用特定的光学活性二胺衍生物，从而活化另一种对映异构体。

公开(公告)号：US06326520B1

公开(公告)日：2001-12-04

申请号：US09377688

申请日：1999-08-20

申请人： Akihiro Ishii ,  Koichi Mikami

发明人： Akihiro Ishii ,  Koichi Mikami

IPC分类号： C07C49213

CPC分类号： C07F7/1892 ,  B01J31/223 ,  B01J2231/341 ,  B01J2531/0266 ,  B01J2531/46 ,  C07C43/1787 ,  C07C45/30 ,  C07C49/82

摘要： The invention relates to a method for producing a novel optically active compound represented by the general formula [IV]. This method includes the step of reacting a vinyl ether with a halogenated acetaldehyde in the presence of an optically active binaphthol-titanium complex. With this, the novel optically active compound can be produced very easily. Furthermore, the novel optically active compound can easily be oxidized to a novel optically active &agr;,&bgr;-dihydrexyketone represented by the general formula [V]. These novel optically active compounds can each be used as useful intermediates. where R is a lower alkyl group or —Si(R3)3, where R3 is a lower alkyl group and three of R3 may be the same or different groups, R1 is a lower alkyl group or a substituted or unsubstituted phenyl group, R2 is hydrogen atom or a lower alkyl group or a substituted or unsubstituted phenyl group, or R1 and R2 are combined to form an alkylene group, and X is hydrogen, fluorine, chlorine or bromine with a proviso that three of said X may be the same or different atoms, but are not hydrogen at the same time.

摘要翻译： 本发明涉及一种由通式[Ⅳ]表示的新的光学活性化合物的制备方法。 该方法包括在光学活性联萘酚钛络合物存在下使乙烯基醚与卤代乙醛反应的步骤。 由此，可以非常容易地制造新颖的光学活性化合物。 此外，新的光学活性化合物可以容易地被氧化成由通式[V]表示的新的光学活性α，β-二羟基酮。 这些新的光学活性化合物各自可用作有用的中间体。其中R是低级烷基或-Si（R3）3，其中R3是低级烷基，R3中的三个可以是相同或不同的基团，R1是 低级烷基或取代或未取代的苯基，R 2为氢原子或低级烷基或取代或未取代的苯基，或R 1和R 2结合形成亚烷基，X为氢，氟，氯或溴 条件是所述X中的三个可以是相同或不同的原子，但不是同时是氢。

公开(公告)号：US5972543A

公开(公告)日：1999-10-26

申请号：US100083

申请日：1998-06-19

申请人： Toshifumi Yokoyama ,  Koichi Mikami ,  Chiaki Hatsuda ,  Hiroshi Mohri

发明人： Toshifumi Yokoyama ,  Koichi Mikami ,  Chiaki Hatsuda ,  Hiroshi Mohri

IPC分类号： H01L21/027 ,  G03F1/32 ,  G03F9/00

CPC分类号： G03F1/32

摘要： A phase shift mask, e.g. a halftone phase shift mask, which need not to form an ultra-fine pattern and is capable of suppressing during exposure the occurrence of a sub-peak of light intensity, which has an adverse effect on the image formation, and which has a light-blocking pattern with a reduced transmittance at a region outside a device pattern area which corresponds to a region subjected to multiple exposure during transfer effected by using the mask. The halftone phase shift mask has on a transparent substrate (101) a halftone phase shift film (102) comprising a single layer or a plurality of layers. The composition of the halftone phase shift film (102) is changed in a region (107) outside a device pattern area on the transparent substrate (101) which corresponds to a multiple-exposure region by a method wherein the region (107) is irradiated with an electromagnetic wave, a particle beam, heat rays, etc., or a method wherein after a region in which the composition is not desired to change has been masked, the whole blank is exposed to an active atmosphere, thereby reducing the transmittance for exposure light at the region (107).

摘要翻译： 相移掩模，例如 半色调相移掩模，其不需要形成超细图案，并且能够在曝光期间抑制对图像形成产生不利影响的光强度的次峰值的出现， 在对应于通过使用掩模进行的转印期间经受多次曝光的区域的器件图案区域外的区域处的透射率降低的阻挡图案。 半色调相移掩模在透明基板（101）上具有包括单层或多层的半色调相移膜（102）。 通过照射区域（107）的方法，半透明相移膜（102）的组成在与多曝光区域对应的透明基板（101）的装置图案区域外的区域（107）中变化 具有电磁波，粒子束，热射线等，或者其中在组合物不希望改变的区域已被掩蔽之后，整个坯料暴露于活性气氛，从而降低透射率 在区域（107）处的曝光光。

公开(公告)号：US5811208A

公开(公告)日：1998-09-22

申请号：US691369

申请日：1996-08-02

申请人： Toshifumi Yokoyama ,  Koichi Mikami ,  Chiaki Hatsuda ,  Hiroshi Mohri

发明人： Toshifumi Yokoyama ,  Koichi Mikami ,  Chiaki Hatsuda ,  Hiroshi Mohri

IPC分类号： H01L21/027 ,  G03F1/32 ,  G03F9/00

CPC分类号： G03F1/32

摘要： A phase shift mask, e.g. a halftone phase shift mask, which need not to form an ultra-fine pattern and is capable of suppressing during exposure the occurrence of a sub-peak of light intensity, which has an adverse effect on the image formation, and which has a light-blocking pattern with a reduced transmittance at a region outside a device pattern area which corresponds to a region subjected to multiple exposure during transfer effected by using the mask. The halftone phase shift mask has on a transparent substrate (101) a halftone phase shift film (102) comprising a single layer or a plurality of layers. The composition of the halftone phase shift film (102) is changed in a region (107) outside a device pattern area on the transparent substrate (101) which corresponds to a multiple-exposure region by a method wherein the region (107) is irradiated with an electromagnetic wave, a particle beam, heat rays, etc., or a method wherein after a region in which the composition is not desired to change has been masked, the whole blank is exposed to an active atmosphere, thereby reducing the transmittance for exposure light at the region (107).

公开(公告)号：US08859789B2

公开(公告)日：2014-10-14

申请号：US13989662

申请日：2011-11-16

申请人： Koichi Mikami ,  Kohsuke Aikawa ,  Yuta Hioki

发明人： Koichi Mikami ,  Kohsuke Aikawa ,  Yuta Hioki

IPC分类号： C07D407/00 ,  C07D305/10 ,  C07D407/04 ,  C07D409/04

CPC分类号： C07D305/10 ,  C07D407/04 ,  C07D409/04

摘要： A method for producing an optically active fluorine-containing oxeten, the method being provided to include the steps of causing a fluorine-containing α-ketoester and an internal alkyne to react with each other in the presence of a transition metal complex that has an optically active ligand.

摘要翻译： 一种制备光学活性的含氟氧杂环丁酮的方法，该方法包括以下步骤：在具有光学上的过渡金属配合物的存在下，使含氟α-酮酯和内部炔烃彼此反应 活性配体。