公开(公告)号：US20090170006A1

公开(公告)日：2009-07-02

申请号：US12064181

申请日：2006-08-10

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Chisen Hashimoto ,  Masahide Kondo

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Chisen Hashimoto ,  Masahide Kondo

IPC: H01M6/16

CPC classification number: H01M10/0525 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0025 ,  H01M2300/0037 ,  H01M2300/004 ,  H01M2300/0042

Abstract: The present invention provides a nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, containing 0.01% to 30% by weight of a 1,2-cyclohexanediol derivative having a specific structure; and a lithium secondary battery using the nonaqueous electrolytic solution. The lithium secondary battery exhibits excellent battery characteristics such as electrical capacity, cycle property, and storage property and can maintain excellent long-term battery performance.

Abstract translation: 本发明提供一种非水电解液，其中电解质盐溶解在非水溶剂中，其含有0.01重量％至30重量％的具有特定结构的1,2-环己二醇衍生物; 以及使用非水电解液的锂二次电池。 锂二次电池具有优异的电池特性，例如电容，循环特性和存储性能，并且可以保持优异的长期电池性能。

公开(公告)号：US20070178380A1

公开(公告)日：2007-08-02

申请号：US10584266

申请日：2004-12-24

Applicant: Masato Iwanaga ,  Hideyuki Inomata ,  Keisuke Ooga ,  Koji Abe ,  Kazuhiro Miyoshi

Inventor： Masato Iwanaga ,  Hideyuki Inomata ,  Keisuke Ooga ,  Koji Abe ,  Kazuhiro Miyoshi

IPC: H01M4/58 ,  H01M10/40

CPC classification number: H01M10/0567 ,  H01M4/131 ,  H01M4/133 ,  H01M10/0525 ,  H01M10/0569

Abstract: A nonaqueous electrolyte secondary battery comprising a negative electrode constituted of a carbonaceous material permitting reversible insertion and desorption of lithium, a positive electrode permitting reversible insertion and desorption of lithium, a separator separating these positive electrode and negative electrode from each other and a nonaqueous electrolyte composed of an organic solvent and, dissolved therein, a solute of lithium salt, wherein the nonaqueous electrolyte contains vinylene carbonate and di(2-propynyl) oxalate, these vinylene carbonate and di(2-propynyl) oxalate added in an amount of 0.1 to 3.0% by mass and 0.1 to 2.0% by mass, respectively, based on the mass of the nonaqueous electrolyte. Thus, there can be provided a nonaqueous electrolyte secondary battery wherein a stable SEI surface coating is formed to thereby exhibit a large initial capacity and excel in cycle characteristics at high temperature and wherein any cell swelling is slight.

Abstract translation: 一种非水电解质二次电池，包括由允许锂的可逆插入和解吸的碳质材料构成的负极，允许锂的可逆插入和解吸的正极，将这些正极和负极彼此分离的隔板和构成的非水电解质 的有机溶剂中溶解有锂盐溶质，其中非水电解质含有碳酸亚乙烯酯和草酸二（2-丙炔基）酯，这些碳酸亚乙烯酯和草酸二（2-丙炔基）的添加量为0.1〜3.0 质量％，以质量计0.1〜2.0质量％。 因此，可以提供一种非水电解质二次电池，其中形成稳定的SEI表面涂层，从而表现出大的初始容量，并且在高温下具有优异的循环特性，并且其中任何电池膨胀都很小。

公开(公告)号：US09647294B2

公开(公告)日：2017-05-09

申请号：US13576182

申请日：2011-02-02

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo

IPC: H01M10/056 ,  C07C309/70 ,  C07C309/68 ,  C07C309/67 ,  H01M10/0567 ,  H01M10/052 ,  C07F9/113 ,  C07F9/32

CPC classification number: H01M10/0567 ,  C07C309/67 ,  C07F9/113 ,  C07F9/327 ,  H01M10/052 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

Abstract: The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it.The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. R1(O)n—X1—R2  (I) (In the formula, X1 represents a group —C(═O)—, a group —C(═O)—C(═O)—, a group —S(═O)2—, a group —P(═O) (—R3)—, or a group —X3—S(═O)2O—. R1 represents an alkenyl group, a formyl group, an alkyl group, an acyl group, an arylcarbonyl, an alkanesulfonyl group, an alkynyloxysulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkyl(alkoxy)phosphoryl group, or a dialkoxyphosphoryl group; R2 represents an alkynyl group or an alkynyloxy group; R3 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, or an aryloxy group; n indicates 0 or 1.

公开(公告)号：US09029024B2

公开(公告)日：2015-05-12

申请号：US13386841

申请日：2010-08-12

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Kazuyuki Kawabe

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Kazuyuki Kawabe

IPC: H01M10/052 ,  H01M6/16 ,  H01M10/0569 ,  H01M10/0568 ,  H01M4/505 ,  H01M4/52 ,  H01M10/0567 ,  H01M4/02 ,  H01M10/0525

CPC classification number: H01M10/052 ,  H01M4/505 ,  H01M4/52 ,  H01M6/164 ,  H01M6/166 ,  H01M6/168 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02T10/7011

Abstract: Disclosed are a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which contains a sulfonate compound having a specific structure in an amount of from 0.01 to 10% by mass of the nonaqueous electrolytic solution, and an electrochemical device containing the nonaqueous electrolytic solution. The nonaqueous electrolytic solution is excellent in the effect of improving the storage property of primary batteries and improving the cycle property of secondary batteries in use thereof at high temperatures and the low-temperature property thereof after high-temperature cycles.

Abstract translation: 公开了溶解在非水溶剂中的电解质盐的非水电解液，其含有非水电解液的0.01〜10质量％的特定结构的磺酸盐化合物，含有非水电解质的电化学装置 解。 非水电解液在高温下的一次电池的储存性提高，二次电池的循环性提高，高温循环后的低温性优异。

公开(公告)号：US08597834B2

公开(公告)日：2013-12-03

申请号：US12801631

申请日：2010-06-17

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

IPC: H01M4/13 ,  H01M6/16

CPC classification number: H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2010/4292 ,  H01M2300/0025

Abstract: A nonaqueous electrolyte secondary battery including a negative electrode containing a graphite material as the negative active material, a positive electrode containing lithium cobalt oxide as a main component of the positive active material and a nonaqueous electrolyte solution, the battery being characterized in that the lithium cobalt oxide contains a group IVA element selected from the group consisting of Ti, Zr and Hf and a group IIA element of the periodic table, the nonaqueous electrolyte solution contains 0.2-1.5% by weight of a sulfonyl-containing compound and preferably further contains 0.5-4% by weight of vinylene carbonate.

Abstract translation: 包含含有作为负极活性物质的石墨材料的负极，含有钴酸锂作为正极活性物质的主要成分的正极和非水电解液的非水电解质二次电池，其特征在于，所述锂钴 氧化物含有选自Ti，Zr和Hf的IVA族元素和周期表的IIA族元素，非水电解质溶液含有0.2-1.5重量％的含磺酰基化合物，优选还含有0.5- 4重量％的碳酸亚乙烯酯。

公开(公告)号：US20130071733A1

公开(公告)日：2013-03-21

申请号：US13701193

申请日：2011-06-03

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

IPC: H01M10/0566

CPC classification number: H01M10/0567 ,  H01G11/58 ,  H01M10/052 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

Abstract: The present invention provides a nonaqueous electrolytic solution which can improve the electrochemical characteristics in a broad temperature range, an electrochemical element produced by using the same and a sulfonic ester compound having a branched structure which is used for the same.The present invention relates to a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, which comprises a sulfonic ester compound represented by the following Formula (I) in an amount of 0.001 to 5% by mass of the nonaqueous electrolytic solution: (wherein R represents an alkyl group or an aryl group; A represents a >CH group or a >SiZ group (Z represents an alkyl group or an aryl group); X represents an alkyl group, a cycloalkyl group or an aryl group; Y represents a cycloalkyl group, a -L1CHRaOSO2Rb group or a —Si(Rc)(Rd)OSO2Rb group; W represents 1 or 2; Ra represents an alkyl group; Rb, Rc and Rd represent an alkyl group or an aryl group; L1 represents an alkylene group in which at least one hydrogen atom may be substituted with —OSO2Re (Re has the same meaning as that of R), a divalent linkage group containing at least one ether bond or a single bond).

Abstract translation: 本发明提供一种可以提高宽温度范围内的电化学特性的非水电解液，使用该电解质的电化学元件和具有分支结构的磺酸酯化合物。 本发明涉及通过将电解质盐溶解在非水溶剂中而制备的非水电解液，该非水溶剂包含以下式（I）表示的磺酸酯化合物：非水电解液的0.001〜5质量％ （其中R表示烷基或芳基; A表示> CH基或> SiZ基（Z表示烷基或芳基）; X表示烷基，环烷基或芳基; Y 表示环烷基，-L1CHRaOSO2Rb基或-Si（Rc）（Rd）OSO2Rb基; W表示1或2; Ra表示烷基; Rb，Rc和Rd表示烷基或芳基; L1表示 其中至少一个氢原子可以被-OSO 2 Re取代的亚烷基（Re具有与R相同的含义），含有至少一个醚键或单键的二价连接基团）。

公开(公告)号：US07781106B2

公开(公告)日：2010-08-24

申请号：US10567902

申请日：2004-08-09

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata ,  Yasuo Matsumori

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata ,  Yasuo Matsumori

IPC: H01M6/16

CPC classification number: H01M6/16 ,  H01M4/131 ,  H01M4/133 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

Abstract: The invention provides a lithium secondary battery which is excellent in long-term cycle property and in battery characteristics, such as electric capacity and storage property, and a nonaqueous electrolytic solution usable for such a lithium secondary battery. The present invention relates to a lithium secondary battery including a positive electrode, a negative electrode, and a nonaqueous electrolytic solution containing an electrolyte salt dissolved in a nonaqueous solvent, characterized in that the positive electrode is made of a material including a lithium compound oxide, in that the negative electrode is made of a material including graphite, and in that the nonaqueous electrolytic solution contains dialkyl oxalate and further contains vinylene carbonate and/or 1,3-propanesultone, and a nonaqueous electrolytic solution for use in such a battery.

Abstract translation: 本发明提供一种锂电池，该锂二次电池具有优异的长期循环性能和电容特性以及蓄电性等电池特性，以及可用于这种锂二次电池的非水电解液。 本发明涉及一种锂二次电池，其包括正极，负极和含有溶解在非水溶剂中的电解质盐的非水电解液，其特征在于，所述正极由包含锂复合氧化物的材料制成， 由于负极由包括石墨的材料制成，并且非水电解液含有草酸二烷基酯，还含有碳酸亚乙烯酯和/或1,3-丙磺酸内酯，以及用于这种电池的非水电解液。

公开(公告)号：US20090280404A1

公开(公告)日：2009-11-12

申请号：US12064337

申请日：2006-08-11

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo ,  Manabu Takase

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Masahide Kondo ,  Manabu Takase

IPC: H01M6/14 ,  H01M6/16

CPC classification number: H01M10/0525 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2300/004

Abstract: The present invention provides a nonaqueous electrolytic solution exhibiting excellent electrical capacity, long-term cycle property, and storage property in a charged state; and a lithium secondary battery using the nonaqueous electrolytic solution.The nonaqueous electrolytic solution in which an electrolyte salt is dissolved in a nonaqueous solvent, comprises 0.001% to 5% by weight of a tin compound represented by the following general formula (I) and/or (II), on the basis of the weight of the nonaqueous electrolytic solution: R1R2R3Sn-MR4R5R6  (I) where R1 to R3 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, an aryl group, or an aryloxy group; R4 to R6 each represent a hydrogen atom, a halogen atom, an alkyl group, an alkenyl group, an alkynyl group, or an aryl group; M represents Si or Ge; and SnX2  (II) where X represents β-diketonate.

Abstract translation: 本发明提供一种在充电状态下显示出优异的电容，长期循环性能和储存性能的非水电解液。 以及使用非水电解液的锂二次电池。 其中电解质盐溶解在非水溶剂中的非水电解液包含0.001重量％至5重量％的由以下通式（I）和/或（II）表示的锡化合物，基于重量 的非水电解液：R1R2R3Sn-MR4R5R6（I）其中R1至R3各自表示氢原子，卤素原子，烷基，烯基，炔基，芳基或芳氧基; R4至R6各自表示氢原子，卤素原子，烷基，烯基，炔基或芳基; M表示Si或Ge; 和SnX 2（II），其中X代表β-二酮。

公开(公告)号：US07550233B2

公开(公告)日：2009-06-23

申请号：US10472202

申请日：2002-03-22

Applicant: Koji Abe ,  Motoki Yuguchi ,  Yasuo Matsumori ,  Kazuhiro Miyoshi

Inventor： Koji Abe ,  Motoki Yuguchi ,  Yasuo Matsumori ,  Kazuhiro Miyoshi

IPC: H01M6/16

CPC classification number: H01M10/0567 ,  H01M2/0222 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/4235 ,  H01M2300/0037 ,  H01M2300/004

Abstract: A non-aqueous electrolytic solution containing a ketone compound having the formula (I): in which each of R1 and R2 is linear or branched alkyl; and each of R3, R4, R5 and R6 is hydrogen or linear or branched alkyl; however, R1 and R4 can be combined to form a cycloalkanone ring in conjunction with a propanone skeleton to which R1 and R4 are connected, and two or more of alkyl of R2, alkyl of R5, a branched chain of alkyl of R1, and a branched chain of alkyl of R4 can be combined to form a cycloalkane ring, or alkyl of R1 and alkyl of R2 and/or alkyl of R4 and alkyl of R5 can be combined to each other to form a cycloalkane ring, is favorably employed for manufacturing a lithium secondary battery that is excellent in the battery performances and cycle performance.

Abstract translation: 含有具有式（I）的酮化合物的非水电解液：其中R1和R2各自为直链或支链烷基; R3，R4，R5和R6各自为氢或直链或支链烷基; 然而，R1和R4可以与R1和R4连接的丙酮骨架结合形成环烷酮环，R2和R2的烷基，R5的烷基，R1的烷基支链和 可以将R4的烷基的支链结合形成环烷烃环，或者R 1的烷基和R 2的烷基和/或R 4的烷基和/或R 5的烷基可以相互结合形成环烷烃环，有利地用于制造 具有优异的电池性能和循环性能的锂二次电池。

公开(公告)号：US20070231707A1

公开(公告)日：2007-10-04

申请号：US11597652

申请日：2005-05-30

Applicant: Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

Inventor： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC: H01M10/40

CPC classification number: H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0567 ,  H01M2300/004

Abstract: A nonaqueous electrolytic solution for a lithium secondary battery, in which 0.01 to 10 wt. % of a sulfur-containing acid ester and 0.01 to 10 wt. % of a triple bond-containing compound are dissolved in a nonaqueous solvent, and a lithium secondary battery employing the nonaqueous electrolytic solution.

Abstract translation: 一种锂二次电池用非水电解液，其中，0.01〜10重量％ ％的含硫酸酯和0.01〜10wt。 将含三价键的化合物的％溶解在非水溶剂中，使用该非水电解液的锂二次电池。