Enzymatic synthesis of sugar acrylates
    31.
    发明授权
    Enzymatic synthesis of sugar acrylates 有权
    糖丙糖酸酯的酶合成

    公开(公告)号:US07767425B2

    公开(公告)日:2010-08-03

    申请号:US10495580

    申请日:2002-11-15

    IPC分类号: C12P19/02

    CPC分类号: C07H13/04

    摘要: A process is described for the enzymatic synthesis of sugar acrylates, and a process is described for preparing polymeric sugar acrylates, the polymers obtainable by this process and their use for preparing, for example, cosmetics, drugs, laundry detergents, thickeners, protecting colloids, superabsorbents and textile sizes.

    摘要翻译: 描述了用于糖类丙烯酸酯的酶促合成的方法,并且描述了制备聚合糖丙烯酸酯的方法,可通过该方法获得的聚合物及其用于制备例如化妆品,药​​物,衣物洗涤剂,增稠剂,保护胶体, 超吸收剂和纺织品尺寸。

    Modified polyaminoamides
    32.
    发明申请
    Modified polyaminoamides 有权
    改性聚氨基酰胺

    公开(公告)号:US20070179270A1

    公开(公告)日:2007-08-02

    申请号:US10592370

    申请日:2005-03-18

    IPC分类号: C08G69/08

    摘要: The present invention relates to novel modified polyaminoamides which are useful as dispersing agents for particulate inorganic solids, especially for inorganic pigments such as clay minerals. The new polyamides are also useful as graying inhibiting additives and detergency boosting additives in washing composition for laundry. In the modified polyaminoamide according to the invention at least a part of the amino nitrogens of the polymer carry both a hydrocarbon radical R which is selected from C1-C6-alkyl, C6-C16-aryl-C1-C4-alkyl and a group AIk-O-A, wherein A is hydrogen or an acidic group selected from B1—PO(OH)2, B1—S(O)2OH and B2—COOH which may be present in the acidic or anionic form, wherein B1 is a single bond or C1-C6-alkanediyl, and B2 is C1-C6-alkanediyl and Alk is C2-C6-alkane-1,2-diyl, and a moiety of the formula (I) —(CH2—CR1R2—O—)pA ,wherein A is as defined above R1 is independently selected from hydrogen, C1-C12-alkyl, C2-C8-alkenyl, C6-C16-aryl or C6-C16-aryl-C1-C4-alkyl, R2 is independently selected from hydrogen or methyl and p is an integer provided that p has a number average of at least 10.

    摘要翻译: 本发明涉及可用作颗粒状无机固体分散剂的新型改性聚氨基酰胺,特别是无机颜料如粘土矿物。 新型聚酰胺也可用作用于洗涤用洗涤剂组合物中的抑灰添加剂和助洗剂。 在根据本发明的改性聚氨基酰胺中,聚合物的至少一部分氨基氮携带选自C 1 -C 6 - 烷基的烃基R ,C 6 -C 16 - 芳基-C 1 -C 4 - 烷基和基团Alk-OA ,其中A是氢或选自B 1 -PO(OH)2,B 0 -S(O)2的酸性基团 > 2 OH和B 2 -COOH,其可以以酸性或阴离子形式存在,其中B 1是单键或C1-C 6个亚烷基,B 2是C 1 -C 6 - 烷二基,Alk是C 2 - (I) - (CH 2 CH 2) - (CH 2)2 - , - 其中A如上所定义R 1独立地选自氢,C 1 -C 4烷基, C 1 -C 12烷基,C 2 -C 8 - 烯基,C 6 - C 16 - 芳基或C 6 -C 16 - 芳基 1 C 1 -C 4 - 烷基,R 2独立地选自氢或甲基,p是整数,条件是p具有数均分子 至少10。

    Polyelectrolyte complexes and a method for production thereof
    33.
    发明授权
    Polyelectrolyte complexes and a method for production thereof 失效
    聚电解质络合物及其制备方法

    公开(公告)号:US06740633B2

    公开(公告)日:2004-05-25

    申请号:US10258615

    申请日:2002-11-06

    IPC分类号: C11D185

    摘要: Polyelectrolyte complexes of cationic and anionic polymers which consist of (a) cationic condensates of (i) at least one amine and (ii) a crosslinking agent from the group consisting of epihalohydrins, bishalohydrins of diols, bishalohydrins of polyalkylene glycols, bishalohydrins of polytetrahydrofurans, alkylene dihalides, alkylene trihalides, bisepoxides, trisepoxides, tetraepoxides and/or mixtures of said compounds, and/or quaternized cationic condensates of (i) and (ii), and (b) anionic compounds containing at least three anionic groups and have a charge ratio between anionic and cationic polymers of from 0.01 to 20, and a process for the preparation of the polylectrolyte complexes by mixing the cationic condensates (a) with anionic compounds (b).

    摘要翻译: 阳离子和阴离子聚合物的聚电解质络合物由(a)至少一种胺的阳离子缩合物和(ii)来自二卤代醇的二卤代醇,聚亚烷基二醇的双水甙元,聚四氢呋喃的双卤水, 亚烷基二卤化物,三卤化亚烷基,双环氧化物,三环氧化物,四环氧化物和/或所述化合物的混合物和/或(i)和(ii)的季铵化阳离子缩合物,和(b)含有至少三个阴离子基团并具有电荷比 在0.01至20的阴离子和阳离子聚合物之间,以及通过将阳离子缩合物(a)与阴离子化合物(b)混合来制备聚电解质络合物的方法。

    Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith
    35.
    发明授权
    Laundry detergent compositions with amino acid based polymers to provide appearance and integrity benefits to fabrics laundered therewith 失效
    具有氨基酸基聚合物的洗衣洗涤剂组合物,为了洗涤的织物提供外观和完整性

    公开(公告)号:US06407053B1

    公开(公告)日:2002-06-18

    申请号:US09485247

    申请日:2000-02-07

    IPC分类号: C11D337

    摘要: Modified polyaspartic acids are obtained by polycondensing (a) 1 to 99.9 mol % aspartic acid with (b) 99 to 0.1 mol % fatty acids, polybasic carboxylic acids, anhydrides of polybasic carboxylic acids, polybasic hydroxycarboxylic acids, monobasic poly-hydroxycarboxylic acids, alcohols, amines, alkoxylated alcohols and amines, amino sugars, carbohydrates, sugar carboxylic acids and/or non-proteinogenic aminocarboxylic acids, or by polymerizing monoethylenically unsaturated monomers in the presence of polyaspartic acids, in the manner of radically initiated graft copolymerization. Also disclosed is a process for preparing these modified polyaspartic acids, as well as the use of these modified polyaspartic acids as additives to washing and cleaning agents, as water conditioning agents and as deposit inhibitors during the condensation of sugar juice.

    摘要翻译: 通过将(a)1至99.9mol%天冬氨酸与(b)99至0.1mol%脂肪酸,多元羧酸,多元羧酸的酸酐,多元羟基羧酸,一元多羟基羧酸,醇 ,胺,烷氧基化醇和胺,氨基糖,碳水化合物,糖羧酸和/或非蛋白质氨基羧酸,或通过在自由基引发的接枝共聚的方式在聚天冬氨酸的存在下聚合单烯属不饱和单体。 还公开了制备这些改性聚天冬氨酸的方法,以及这些改性聚天冬氨酸作为洗涤剂和清洁剂的添加剂的用途,作为水调节剂和在糖汁冷凝期间作为沉积抑制剂的用途。

    Modified polyaminoamides
    37.
    发明授权
    Modified polyaminoamides 有权
    改性聚氨基酰胺

    公开(公告)号:US08022134B2

    公开(公告)日:2011-09-20

    申请号:US10592370

    申请日:2005-03-18

    IPC分类号: C08G73/02 C11D3/37

    摘要: The present invention relates to novel modified polyaminoamides which are useful as dispersing agents for particulate inorganic solids, especially for inorganic pigments such as clay minerals. The new polyamides are also useful as graying inhibiting additives and detergency boosting additives in washing composition for laundry. In the modified polyaminoamide according to the invention at least a part of the amino nitrogens of the polymer carry both a hydrocarbon radical R which is selected from C1-C6-alkyl, C6-C16-aryl-C1-C4-alkyl and a group AIk-O-A, wherein A is hydrogen or an acidic group selected from B1—PO(OH)2, B1—S(O)2OH and B2—COOH which may be present in the acidic or anionic form, wherein B1 is a single bond or C1-C6-alkanediyl, and B2 is C1-C6-alkanediyl and Alk is C2-C6-alkane-1,2-diyl, and a moiety of the formula (I) —(CH2—CR1R2—O—)pA ,wherein A is as defined above R1 is independently selected from hydrogen, C1-C12-alkyl, C2-C8-alkenyl, C6-C16-aryl or C6-C16-aryl-C1-C4-alkyl, R2 is independently selected from hydrogen or methyl and p is an integer provided that p has a number average of at least 10.

    摘要翻译: 本发明涉及可用作颗粒状无机固体分散剂的新型改性聚氨基酰胺,特别是无机颜料如粘土矿物。 新型聚酰胺也可用作用于洗涤用洗涤剂组合物中的抑灰添加剂和助洗剂。 在根据本发明的改性聚氨基酰胺中,聚合物的至少一部分氨基氮携带选自C 1 -C 6烷基,C 6 -C 16 - 芳基-C 1 -C 4 - 烷基和基团AI k的烃基R -OA,其中A是氢或选自B1-PO(OH)2,B1-S(O)2OH和B2-COOH的酸性基团,其可以以酸性或阴离子形式存在,其中B1是单键或 C1-C6链烷二基,B2是C1-C6烷二基,Alk是C2-C6-烷烃-1,2-二基,和式(I) - (CH2-CR1R2-O-)pA的部分,其中 A如上所定义,R 1独立地选自氢,C 1 -C 12 - 烷基,C 2 -C 8 - 烯基,C 6 -C 16 - 芳基或C 6 -C 16 - 芳基-C 1 -C 4烷基,R 2独立地选自氢或甲基 并且p是整数,条件是p的数均数至少为10。

    Treatment method, which promotes the removal of dirt, for the surfaces of textiles and non-textiles
    39.
    发明授权
    Treatment method, which promotes the removal of dirt, for the surfaces of textiles and non-textiles 失效
    处理方法,促进织物和非纺织品表面的污垢去除

    公开(公告)号:US07074750B2

    公开(公告)日:2006-07-11

    申请号:US10479983

    申请日:2002-06-14

    IPC分类号: C11D3/37

    摘要: A process for the soil release treatment of surfaces of textile and nontextile materials, in which cationically modified hydrophilic nanoparticles based on crosslinked polymers of (a) 60 to 99.99% by weight of one or more carboxyl-containing ethylenically unsaturated monomers or salts thereof, (b) 0 to 40% by weight of one or more water-insoluble monoethylenically unsaturated monomers, (c) 0.01 to 30% by weight of one or more polyethylenically unsaturated monomers, (d) 0 to 25% by weight of one or more sulfonic acid- and/or phosphonic acid-containing monomers or salts thereof, (e) 0 to 30% by weight of one or more water-soluble nonionic monomers are applied to the surface of the materials from an aqueous dispersion, where the dispersion of the hydrophilic nanoparticles can be stabilized with anionic, nonionic and/or betainic emulsifiers and/or protective colloids, and where the hydrophilic nanoparticles have a particle size of from 10 nm to 2 μm and have been cationically modified by coating their surface with one or more cationic polymers, one or more polyvalent metal ions and/or one or more cationic surfactants.

    摘要翻译: 一种纺织和非纺织材料表面的污垢释放处理方法,其中基于(a)60-99.99重量%的一种或多种含羧基的烯属不饱和单体或其盐的交联聚合物的阳离子改性亲水性纳米颗粒( b)0至40重量%的一种或多种水不溶性单烯属不饱和单体,(c)0.01至30重量%的一种或多种多烯属不饱和单体,(d)0至25重量%的一种或多种磺酸 含酸和/或膦酸的单体或其盐,(e)0至30重量%的一种或多种水溶性非离子单体,由水分散体施加到材料的表面上,其中, 亲水性纳米颗粒可以用阴离子,非离子和/或甜菜碱乳化剂和/或保护胶体稳定,并且其中亲水性纳米颗粒具有10nm至2μm的粒度并且已被阳离子改性 用一种或多种阳离子聚合物,一种或多种多价金属离子和/或一种或多种阳离子表面活性剂涂覆它们的表面。