公开(公告)号：US20110137067A1

公开(公告)日：2011-06-09

申请号：US13058026

申请日：2009-08-18

申请人： Axel Franzke ,  Robert Baumann ,  Michael Bock ,  Roderich Roettger ,  Andreas Leitner ,  Matthias Kloetzer

发明人： Axel Franzke ,  Robert Baumann ,  Michael Bock ,  Roderich Roettger ,  Andreas Leitner ,  Matthias Kloetzer

IPC分类号： C07C269/04

CPC分类号： C07C269/04 ,  C07C271/28

摘要： A process for preparing urethanes by reacting aromatic diamines with a dialkyl carbonate, wherein the alkyl radical of the organic dialkyl carbonate comprises 2-18 carbon atoms and one or more heteroatoms and the reaction is performed in the presence of a catalyst.

摘要翻译： 通过使芳族二胺与碳酸二烷基酯反应来制备聚氨酯的方法，其中有机碳酸二烷基酯的烷基包含2-18个碳原子和一个或多个杂原子，反应在催化剂存在下进行。

公开(公告)号：US20110021836A1

公开(公告)日：2011-01-27

申请号：US12936080

申请日：2009-04-09

申请人： Michael Bock ,  Martin Sesing ,  Eckhard Stroefer

发明人： Michael Bock ,  Martin Sesing ,  Eckhard Stroefer

IPC分类号： C07C211/49

CPC分类号： C07C263/10 ,  C07C209/62 ,  C07C209/86 ,  C07C265/14 ,  C07C211/51

摘要： The invention relates to a process for the work-up of residues from the production of isocyanates, which comprises the steps: a) hydrolysis of the residues by means of water, b) introduction of the reaction product from step a) into a mixer having a heat transfer surface, c) separation of amine and water from the output from step b), d) separation of water and amine.

摘要翻译： 本发明涉及一种用于处理异氰酸酯生产残留物的方法，其包括以下步骤：a）通过水水解残留物，b）将来自步骤a）的反应产物引入具有 传热表面，c）从步骤b）的输出分离胺和水，d）水和胺的分离。

公开(公告)号：US07709679B2

公开(公告)日：2010-05-04

申请号：US12160163

申请日：2007-01-12

申请人： Michael Bock ,  Hans-Juergen Pallasch ,  Filip Deberdt ,  Johnny Moors

发明人： Michael Bock ,  Hans-Juergen Pallasch ,  Filip Deberdt ,  Johnny Moors

IPC分类号： C07C263/10 ,  C07C209/60

CPC分类号： C07C209/78 ,  C07C209/84 ,  C07C263/10 ,  C07C211/50 ,  C07C265/12

摘要： The invention provides a process for the simultaneous preparation of 4,4′-diphenylmethanediamine and also diphenylmethane diisocyanate and polyphenylenepolymethylene polyisocyanates, which comprises the steps a) preparation of a mixture of diphenylmethanediamine and polyphenylenepolymethylenepolyamines by acid condensation of aniline and formaldehyde and subsequent work-up of the mixture, b) splitting-off of part of the mixture prepared in step a), c) distillation of the mixture separated off in step b) in a column, d) recirculation of the bottom product from step c) to the end product from step a) and condensation of the overhead product from step c), e) distillation of the overhead product from step c) in a column, f) recirculation of the overhead product from step e) to the end product from step a), g) isolation of the 4,4′-diphenylmethanediamine obtained as bottom product in step e), h) reaction of the mixture from step a) with phosgene and subsequent work-up of the reaction product.

摘要翻译： 本发明提供了同时制备4,4'-二苯基甲二胺和二苯基甲烷二异氰酸酯和聚亚苯基多亚甲基多异氰酸酯的方法，其包括以下步骤：a）通过苯胺和甲醛的酸缩合制备二苯基甲二胺和聚亚苯基多亚甲基多胺的混合物，随后的后处理 的混合物，b）分离步骤a）中制备的一部分混合物，c）在柱中蒸馏步骤b）中分离出的混合物，d）将底部产物从步骤c）再循环到末端 来自步骤a）的产物和来自步骤c）的塔顶馏出物的冷凝，e）在柱中蒸馏步骤c）的塔顶馏出物，f）将塔顶产物从步骤e）再循环到来自步骤a）的最终产物， g）分离步骤e）中作为底部产物获得的4,4'-二苯基甲二胺二糖，h）步骤a）的混合物与光气反应，随后后处理反应物 产品

公开(公告)号：US20090188906A1

公开(公告)日：2009-07-30

申请号：US12360968

申请日：2009-01-28

申请人： Michael Bock ,  Erich Dunker

发明人： Michael Bock ,  Erich Dunker

IPC分类号： F27B5/14

CPC分类号： F27B17/02 ,  G01N31/12 ,  Y02P10/143

摘要： A high-temperature tube furnace for pyrolysis includes a twin-hole ceramic tube including a pyrolysis capillary concentrically arranged within a sintering heat tube which is concentrically arranged within a thermally insulated tube housing. At least one heating tube holding element that is electrically insulative and high-temperature resistant is provided and includes at least three pins disposed radially about the sintering heating tube. Each pin is mounted to the tube housing via a clamp in such a way that the pins are adjustable in the radial direction so that the sintering heating tube is removably disposed between the tips of the pins. The sintering heating tube is connected to a voltage source for applying a heating current to thereto.

摘要翻译： 用于热解的高温管式炉是包括同心地布置在烧结热管内的热解毛细管的双孔陶瓷管，其同心地布置在绝热管壳体内。 提供至少一个电绝缘和耐高温的加热管保持元件，并且包括设置在烧结加热管径向周围的至少三个销。 每个销通过夹具安装到管壳体上，使得销在径向方向上可调节，使得烧结加热管可拆卸地设置在销的顶端之间。 烧结加热管连接到用于向其施加加热电流的电压源。

公开(公告)号：US07472870B2

公开(公告)日：2009-01-06

申请号：US10844090

申请日：2004-05-12

申请人： Kenneth L. Zagorski ,  Joseph Donoghue ,  Michael Bock

发明人： Kenneth L. Zagorski ,  Joseph Donoghue ,  Michael Bock

IPC分类号： F16L3/08

CPC分类号： F16L1/06 ,  F16L1/20 ,  F16L59/123 ,  F16L59/135 ,  Y10T403/5781

摘要： A pipe anchor having: a base cradle with a lug; a top cradle with a lug and secured to the base cradle so as to encircle a pipe within the base cradle and the top cradle; a locking mechanism with opposite mating components attached to the base cradle and the top cradle; at least one lug attached to the pipe; and insulation material filling a space between the pipe and the cradles, wherein the insulation material engages the at least one lug of the pipe and the lugs of the cradles.

摘要翻译： 一种管锚，具有：具有凸耳的底座; 具有凸耳并固定到基座的顶架，以便围绕底架和顶托中的管; 具有连接到所述底座和所述顶部支架的相对配合部件的锁定机构; 至少一个连接到管道的凸耳; 以及绝缘材料，其填充所述管道和所述托架之间的空间，其中所述绝缘材料接合所述管道的至少一个凸耳和所述托架的凸耳。

公开(公告)号：US20090005596A1

公开(公告)日：2009-01-01

申请号：US12160163

申请日：2007-01-12

申请人： Michael Bock ,  Hans-Jurgen Pallasch ,  Filip Deberdt ,  Johnny Moors

发明人： Michael Bock ,  Hans-Jurgen Pallasch ,  Filip Deberdt ,  Johnny Moors

IPC分类号： C07C211/09

CPC分类号： C07C209/78 ,  C07C209/84 ,  C07C263/10 ,  C07C211/50 ,  C07C265/12

摘要： The invention provides aprocess for the simultaneous preparation of 4,4′-diphenylmethanediamine and also diphenylmethane diisocyanate and polyphenylenepolymethylene polyisocyanates, which comprises the steps a) preparation of a mixture of diphenylmethanediamine and polyphenylenepolymethylenepolyamines by acid condensation of aniline and formaldehyde and sub-sequent work-up of the mixture, b) splitting-off of part of the mixture prepared in step a), c) distillation of the mixture separated off in step b) in a column, d) recirculation of the bottom product from step c) to the end product from step a) and condensation of the overhead product from step c), e) distillation of the overhead product from step c) in a column, f) recirculation of the overhead product from step e) to the end product from step a), g) isolation of the 4,4′-diphenylmethanediamine obtained as bottom product in step e), h) reaction of the mixture from step a) with phosgene and subsequent work-up of the reaction product.

摘要翻译： 本发明提供了同时制备4,4'-二苯基甲烷二胺以及二苯基甲烷二异氰酸酯和聚亚苯基多亚甲基多异氰酸酯的方法，其包括以下步骤：a）通过苯胺和甲醛的酸缩合制备二苯基甲二胺和聚亚苯基多亚甲基多胺的混合物， - b）分离步骤a）中制备的部分混合物，c）在柱中蒸馏步骤b）中分离出的混合物，d）将底部产物从步骤c）再循环至 来自步骤a）的最终产物和来自步骤c）的塔顶馏出物的缩合，e）将柱子产物从步骤c）中蒸馏出来，f）将塔顶产物从步骤e）再循环到来自步骤 a），g）分离步骤e）中作为底部产物获得的4,4'-二苯基甲烷二胺，h）步骤a）的混合物与光气的反应和随后的反应产物的后处理 ct。

公开(公告)号：US06883513B2

公开(公告)日：2005-04-26

申请号：US10656842

申请日：2003-09-05

申请人： Michael Bock

发明人： Michael Bock

IPC分类号： A21B1/44 ,  A21B3/04 ,  F24B1/00

CPC分类号： A21B1/44 ,  A21B3/04

摘要： A rack oven includes a rack carrier with a main body ant at least one side support connected to the main body for movement between a rack holding position and a rack transfer position. The main body and side support form a rack receiving channel. The side support may be biased into one of the rack holding and the rack transfer positions.

摘要翻译： 架式烤箱包括具有主体的机架托架，至少一个侧支撑件连接到主体，用于在机架保持位置和机架传送位置之间移动。 主体和侧支撑形成机架接收通道。 侧支撑件可以被偏压到搁架保持和支架传送位置之一。

公开(公告)号：US06550561B2

公开(公告)日：2003-04-22

申请号：US09989280

申请日：2001-11-20

申请人： Wolfram Dau ,  Dag-Arnulf Schlaf ,  Michael Bock ,  Wolfgang Lange ,  Andreas Bauer

发明人： Wolfram Dau ,  Dag-Arnulf Schlaf ,  Michael Bock ,  Wolfgang Lange ,  Andreas Bauer

IPC分类号： B60K100

CPC分类号： B60G7/001 ,  B60G2200/142 ,  B60G2200/44 ,  B60G2204/143 ,  B60G2204/15 ,  B60G2204/41 ,  B60G2204/4302 ,  B60G2206/122 ,  B60G2206/604 ,  B62D21/11

摘要： An auxiliary chassis for a motor vehicle is formed as a generally rectangular structure for holding an engine, transmission and other equipment. The auxiliary chassis is mounted to front end structural members at a position spaced from and below the structural member forming a further impact absorbing structure.

公开(公告)号：US5997701A

公开(公告)日：1999-12-07

申请号：US973108

申请日：1998-02-09

申请人： Michael Bock

发明人： Michael Bock

IPC分类号： C25D1/00 ,  C25D1/10 ,  G11B7/26 ,  C25D17/00

CPC分类号： C25D1/10

摘要： The invention relates to an apparatus for the galvanic deposition of a metal layer on a substrate and comprises a substrate holder connected to a drive shaft that extends in a direction perpendicular to a surface of the substrate. The cathode current is supplied to the substrate by the drive shaft. The drive shaft has an outer insulating layer. The substrate is held in contact with a contact plate by a supporting ring on the outer periphery of a supporting plate. The contact plate rests on a base of the supporting plate and has a central sleeve connectable with the drive shaft. A mounting portion is provided in the base around the sleeve and a tube portion is inserted into the mounting portion in a sealing and detachable manner. An internally threaded ring is arranged on the drive shaft and is shiftable along the longitudinal axis of the drive shaft. The internally threaded ring is detachably connectable to the tube portion and seals the tube portion and the drive shaft from intrusion of the electrolyte material.

摘要翻译： PCT No.PCT / EP97 / 01633 Sec。 371日期：1998年2月9日 102（e）日期1998年2月9日PCT 1997年10月9日PCT公布。 公开号WO97 / 37060 日期1997年10月9日本发明涉及一种用于在衬底上电镀沉积金属层的装置，包括连接到沿与衬底表面垂直的方向延伸的驱动轴的衬底保持器。 通过驱动轴将阴极电流供给到基板。 驱动轴具有外绝缘层。 基板通过在支撑板的外周上的支撑环与接触板保持接触。 接触板搁置在支撑板的基部上，并具有可与驱动轴连接的中心套筒。 安装部分设置在基座周围的套筒上，管部分以密封和可拆卸的方式插入安装部分。 内螺纹环设置在驱动轴上，并可沿驱动轴的纵向轴线移动。 内螺纹环可拆卸地连接到管部分并且密封管部分和驱动轴以防止电解质材料侵入。

公开(公告)号：US09000213B2

公开(公告)日：2015-04-07

申请号：US13502763

申请日：2010-10-27

申请人： Michael Bock ,  Robert Baumann ,  Axel Franzke ,  Eckhard Stroefer ,  Gerhard Theis

发明人： Michael Bock ,  Robert Baumann ,  Axel Franzke ,  Eckhard Stroefer ,  Gerhard Theis

IPC分类号： C07C263/04 ,  C07C29/12 ,  C07C29/128 ,  C07C68/06

CPC分类号： C07C263/04 ,  C07C29/12 ,  C07C29/128 ,  C07C68/065 ,  C07C2601/14 ,  C07C69/96 ,  C07C265/12 ,  C07C265/14 ,  C07C31/202

摘要： A process for coproducing di- and/or polyisocyanates and glycols, comprising process stages A, B, C and E for preparing glycols and process stages A, C, D, E, F and G for preparing di- and/or polyisocyanates,which comprises accomplishing the material coupling via the separation of the reaction mixture obtained in process stage A into process stages B and C, by in process stage A, reacting an aqueous alkylene oxide with carbon dioxide to give a reaction mixture comprising alkylene carbonate, hydrolyzing a portion of the alkylene carbonate-comprising reaction mixture obtained in process stage A to glycol in process stage B, dewatering the remaining alkylene carbonate-comprising stream of the reaction mixture from process stage A in process stage C, in process stage D, synthesizing amine by hydrogenating an aromatic nitro compound or a nitrile, in process stage E, transesterifying the dewatered alkylene carbonate-comprising mixture from process stage C with a monohydroxy alcohol to give the corresponding dialkyl carbonate, obtaining glycol as a coproduct, in process stage F, reacting the dialkyl carbonate-comprising reaction mixture obtained in process stage E with the amine obtained in process stage D to a mixture comprising the corresponding mono-, di- and/or polycarbamate, which in process stage G is cleaved to obtain the corresponding di- and/or polyisocyanate.

摘要翻译： 用于共混生产二 - 和/或多异氰酸酯和二醇的方法，包括制备二元醇和工艺阶段A，C，D，E，F和G的制备二 - 和/或多异氰酸酯的工艺阶段A，B，C和E， 包括通过在工艺阶段A中将经处理阶段A获得的反应混合物分离成工艺阶段B和C来实现材料偶联，使环氧烷水溶液与二氧化碳反应，得到包含碳酸亚烷基酯的反应混合物，水解部分 在工艺阶段B中获得的含碳酸亚烷基酯的反应混合物在工艺阶段B中与二醇的混合物，在工艺阶段D中将来自反应混合物的剩余的含有碳酸亚烃的物流从工艺阶段C脱水，通过氢化合成胺 芳香族硝基化合物或腈，在工艺阶段E中，将来自工艺阶段C的脱水的含碳酸亚烷基酯混合物与单羟基醇酯交换，得到 相应的碳酸二烷基酯，在工艺阶段F中获得二醇作为副产物，将在工艺阶段E中获得的含碳酸二烷基酯的反应混合物与在工艺阶段D中获得的胺反应到包含相应的单 - ，二 - 和/ 或聚氨酯，其在工艺阶段G被切割以获得相应的二 - 和/或多异氰酸酯。