公开(公告)号：US5382716A

公开(公告)日：1995-01-17

申请号：US36026

申请日：1993-03-23

Applicant: Helmut Bahrmann ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Jurgen Szameitat ,  Thomas Muller ,  Ernst Wiebus

Inventor： Helmut Bahrmann ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Jurgen Szameitat ,  Thomas Muller ,  Ernst Wiebus

IPC: B01J31/24 ,  C07B61/00 ,  C07C27/22 ,  C07C29/141 ,  C07C29/17 ,  C07C31/125 ,  C07C45/50 ,  C07C45/74 ,  C07C47/21 ,  C07C67/08 ,  C07C69/80 ,  C07C29/16

CPC classification number: C07C45/50 ,  C07C29/175 ,  C07C45/74

Abstract: Mixtures of isomeric decyl alcohols obtained by hydroformylation of butadiene to produce aldehyde mixtures, condensation of the aldehyde mixtures, isolated from the reaction product, to form an aldol mixture, and isolation and hydrogenation of the aldol mixture. The mixture of isomeric decyl alcohols, esterified using phthalic acid, gives a mixture of isomeric decyl phthalates which are plasticizers having excellent cold properties.

Abstract translation: 通过丁二烯加氢甲酰化生成醛混合物得到的异构癸醇的混合物，从反应产物中分离的醛混合物的缩合形成醛醇混合物，以及醛醇混合物的分离和氢化。 使用邻苯二甲酸酯化的异构癸醇的混合物得到异构癸基邻苯二甲酸酯的混合物，其是具有优异的冷特性的增塑剂。

公开(公告)号：US07074304B2

公开(公告)日：2006-07-11

申请号：US10318564

申请日：2002-12-13

Applicant: Wolfgang Dukat ,  Peter Lappe ,  Klaus Schmid ,  Horst Scholz ,  Edgar Storm

Inventor： Wolfgang Dukat ,  Peter Lappe ,  Klaus Schmid ,  Horst Scholz ,  Edgar Storm

IPC: B01D3/34 ,  C07C29/80

CPC classification number: C07C29/80 ,  C07C2602/40 ,  C07C2603/14 ,  C07C2603/18 ,  C07C2603/60 ,  C07C2603/68 ,  C07C35/37 ,  C07C35/38

Abstract: A process for purifying alicyclic alcohols by distillation, wherein the alicyclic alcohols are distilled in the presence of from 1 to 550 ppm of acidic compounds.

公开(公告)号：US5516948A

公开(公告)日：1996-05-14

申请号：US484589

申请日：1995-06-07

Applicant: Helmut Bahrmann ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Thomas Muller ,  Jurgen Szameitat ,  Ernst Wiebus

Inventor： Helmut Bahrmann ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Thomas Muller ,  Jurgen Szameitat ,  Ernst Wiebus

IPC: C07C31/125 ,  C07C29/141 ,  C07C29/16 ,  C07C45/50 ,  C07C67/08 ,  C07C69/80 ,  C08F8/00 ,  C08F10/00 ,  C08F10/06 ,  C08K5/12 ,  C07C27/20

CPC classification number: C08K5/12 ,  C07C29/16 ,  C07C45/50 ,  C07C67/08 ,  C07C69/80

Abstract: Mixtures of isomeric decyl alcohols obtained by oligomerization of propylene in the presence of deactivated zeolites as catalysts, followed by separation of the nine carbon olefins from the oligomer mixture, then hydroformylation of the 9 carbon olefins to 10 carbon aldehydes, and hydrogenation of the aldehydes to the corresponding alcohols. The mixtures, when esterified with phthalic acid, or anhydride, provide a mixture of isomeric di-decyl phthalates that can be used as plasticizers.

Abstract translation: 通过在失活的沸石作为催化剂的存在下将丙烯低聚获得的异构癸醇的混合物，然后从低聚物混合物中分离出9种碳烯烃，然后将9种碳烯烃加氢甲酰化成10种碳醛，并将醛氢化成 相应的醇类。 当用邻苯二甲酸或酸酐酯化时，混合物提供可用作增塑剂的异构二癸基邻苯二甲酸酯的混合物。

公开(公告)号：US5463147A

公开(公告)日：1995-10-31

申请号：US311561

申请日：1994-09-23

Applicant: Helmut Bahrmann ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Thomas Muller ,  Jurgen Szameitat ,  Ernst Wiebus

Inventor： Helmut Bahrmann ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Thomas Muller ,  Jurgen Szameitat ,  Ernst Wiebus

IPC: C07C27/20 ,  C07C29/17 ,  C07C29/38 ,  C07C31/125 ,  C07C45/50 ,  C07C45/74 ,  C07C67/08 ,  C07C69/80 ,  C08K5/00 ,  C08K5/10 ,  C08K5/105 ,  C08K5/12 ,  C08L27/06 ,  C07C27/22 ,  C07C29/141

CPC classification number: C08K5/12 ,  C07C29/175 ,  C07C31/125 ,  C07C45/50 ,  C07C45/74 ,  C08K5/0016

Abstract: Mixtures of isomeric decyl alcohols prepared by hydroformylation of mixtures of butene-1 and butene-2 in two stages to give aldehyde mixtures, and condensation of the aldehyde mixtures to form an aldol mixture, followed by separation and hydrogenation. The first stage of the hydroformylation proceeds in the presence of rhodium catalysts dissolved in water, the second stage in the presence of cobalt catalysts homogeneously dissolved in the reaction medium. The mixture of isomeric decyl alcohols, when esterified with phthalic acid, yields a mixture of isomeric decyl phthalates which are useful as plasticizers.

Abstract translation: 通过二阶段丁烯-1和丁烯-2的混合物的加氢甲酰化得到的异构癸醇的混合物得到醛混合物，醛混合物缩合形成醛醇混合物，然后分离和氢化。 在溶解在水中的铑催化剂存在下进行加氢甲酰基化的第一阶段，第二阶段在均匀溶解在反应介质中的钴催化剂存在下进行。 当用邻苯二甲酸酯化时，异构癸醇的混合物产生可用作增塑剂的异构癸基邻苯二甲酸酯的混合物。

公开(公告)号：US5294415A

公开(公告)日：1994-03-15

申请号：US903010

申请日：1992-06-23

Applicant: Peter Lappe ,  Ludger Bexten ,  Dieter Kupies

Inventor： Peter Lappe ,  Ludger Bexten ,  Dieter Kupies

IPC: C01G55/00 ,  C07C45/50 ,  C22B3/38 ,  B01J38/48 ,  B01J38/64 ,  C22B11/00

CPC classification number: C07C45/50 ,  C01G55/001 ,  C22B3/0051 ,  Y02P10/234

Abstract: To separate and recover rhodium, the distillation residues of oxo synthesis products are initially treated with an oxidant. Then the reaction mixture is reacted, in the presence of carbon monoxide (or a compound which splits off carbon monoxide), with an aqueous solution of a reagent forming a water-soluble complex compound with rhodium. The reaction mixture breaks into an organic phase and an aqueous phase, the complex goes to the aqueous phase as it is substantially insoluble in the organic phase.

Abstract translation: 为了分离和回收铑，首先用氧化剂处理氧合成产物的蒸馏残余物。 然后在一氧化碳（或分解一氧化碳的化合物）存在下，使反应混合物与形成水溶性络合物与铑的试剂的水溶液反应。 反应混合物分解成有机相和水相，当它基本上不溶于有机相时，络合物进入水相。

公开(公告)号：US07196128B2

公开(公告)日：2007-03-27

申请号：US10886967

申请日：2004-07-08

Applicant: Peter Lappe ,  Christoph Balzarek

Inventor： Peter Lappe ,  Christoph Balzarek

IPC: C07C69/66 ,  C08K5/09

CPC classification number: C07C69/40 ,  C07C69/38 ,  C07C69/42 ,  C07C69/44 ,  C07C69/50 ,  C07C2601/14 ,  C10M105/36 ,  C10M2207/282 ,  C10N2240/00

Abstract: A carboxylic ester of the formula in which A is —(CH2)x— where x=1–10, a process for its preparation which esters are useful lubricated and plasticizers for high molecular polymeric thermoplastics.

Abstract translation: 一种下式的羧酸酯

公开(公告)号：US06482972B1

公开(公告)日：2002-11-19

申请号：US08437221

申请日：1995-05-08

Applicant: Helmut Bahrmann ,  Wilfried Fenske ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Thomas Müller ,  Jürgen Szameitat ,  Ernst Wiebus

Inventor： Helmut Bahrmann ,  Wilfried Fenske ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Thomas Müller ,  Jürgen Szameitat ,  Ernst Wiebus

IPC: C07C6976

CPC classification number: C08K5/12 ,  C07C29/175 ,  C07C45/50 ,  C07C45/74 ,  C07C69/80 ,  C12C11/02 ,  C07C31/125 ,  C07C47/21 ,  C07C47/02

Abstract: Mixtures of isomeric nonanols and decanols are obtained by joint aldol condensation of n-butanal and pentanals, and up to 1% by weight of 3-methylbutanal, hydrogenation of the aldol condensation product to the corresponding saturated alcohols, and separation from the reaction mixture of the components boiling at temperatures lower than those of the nonanols and decanols. The pentanals are mixtures of 60 to 90% by weight of n-pentanal and 10 to 40% by weight of 2-methylbutanal. The alcohol mixture is especially suitable for preparing ester plasticizers.

Abstract translation: 异构壬醇和癸醇的混合物是通过正丁醛和戊醛的联合醛醇缩合得到的，高达1重量％的3-甲基丁醛，醛醇缩合产物氢化成相应的饱和醇，并从 组分在低于壬醇和癸醇的温度下沸腾。 戊醛是60至90重量％的正戊醛和10至40重量％的2-甲基丁醛的混合物。 醇混合物特别适用于制备酯增塑剂。

公开(公告)号：US5847200A

公开(公告)日：1998-12-08

申请号：US839329

申请日：1997-04-17

Applicant: Helmut Bahrmann ,  Peter Lappe ,  Thomas Muller

Inventor： Helmut Bahrmann ,  Peter Lappe ,  Thomas Muller

IPC: C07C45/50 ,  C07F9/50

CPC classification number: C07F9/509 ,  C07F9/5027

Abstract: New diphosphines in the form of ammonium carboxylates, sulfonates or phosphonates having a singly or multiply charged diphosphine anion and the corresponding number of ammonium cations as counter ions, and a process for their preparation useful as ligand in rhodium catalyst systems for hydroformylation of olefins.

Abstract translation: 具有单或多电荷二膦阴离子的铵羧酸盐，磺酸盐或膦酸盐形式的新二膦以及相应数量的铵阳离子作为抗衡离子，以及用作其用作配体的方法，用于烯烃加氢甲酰化的铑催化剂体系。

公开(公告)号：US5583250A

公开(公告)日：1996-12-10

申请号：US484588

申请日：1995-06-07

Applicant: Helmut Bahrmann ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Thomas M uller ,  J urgen Szameitat ,  Ernst Wiebus

Inventor： Helmut Bahrmann ,  Wolfgang Greb ,  Peter Heymanns ,  Peter Lappe ,  Thomas M uller ,  J urgen Szameitat ,  Ernst Wiebus

IPC: C07C31/125 ,  C07C29/141 ,  C07C29/16 ,  C07C45/50 ,  C07C67/08 ,  C07C69/80 ,  C08F8/00 ,  C08F10/00 ,  C08F10/06 ,  C08K5/12 ,  C07C69/76

CPC classification number: C08K5/12 ,  C07C29/16 ,  C07C45/50 ,  C07C67/08 ,  C07C69/80

Abstract: Mixtures of isomeric decyl alcohols obtained by oligomerization of propylene in the presence of deactivated zeolites as catalysts, followed by separation of the nine carbon olefins from the oligomer mixture, then hydroformylation of the 9 carbon olefins to 10 carbon aldehydes, and hydrogenation of the aldehydes to the corresponding alcohols. The mixtures, when esterified with phthalic acid, or anhydride, provide a mixture of isomeric di-decyl phthalates that can be used as plasticizers.

Abstract translation: 通过在失活的沸石作为催化剂的存在下将丙烯低聚获得的异构癸醇的混合物，然后从低聚物混合物中分离出9种碳烯烃，然后将9种碳烯烃加氢甲酰化成10种碳醛，并将醛氢化成 相应的醇类。 当用邻苯二甲酸或酸酐酯化时，混合物提供可用作增塑剂的异构二癸基邻苯二甲酸酯的混合物。

公开(公告)号：US5481045A

公开(公告)日：1996-01-02

申请号：US240902

申请日：1994-05-11

Applicant: Wolfgang A. Herrmann ,  Rainer Manetsberger ,  Helmut Bahrmann ,  Christian Kohlpaintner ,  Peter Lappe

Inventor： Wolfgang A. Herrmann ,  Rainer Manetsberger ,  Helmut Bahrmann ,  Christian Kohlpaintner ,  Peter Lappe

IPC: B01J31/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07F9/50 ,  C07C47/11

CPC classification number: C07F9/5027 ,  B01J31/2452 ,  C07C45/50 ,  B01J2231/321 ,  B01J2531/0266 ,  B01J2531/822 ,  B01J2531/96

Abstract: Sulfonated diphosphines of the formula ##STR1## in which Ar is m-C.sub.6 H.sub.4 -SO.sub.3 M, M is hydrogen, ammonium, a monovalent metal, or the chemical equivalent of a polyvalent metal; Ph is phenyl; the m's are individually 1 or 2, and the n's are individually 0, 1, or 2. A method of their preparation and the hydroformylation of olefins and olefinically unsaturated compounds using these compounds as a constituent of water-soluble catalyst systems are also disclosed.

Abstract translation: 其中Ar是m-C6H4-SO3M的式“IMAGE”的磺化二膦，M是氢，铵，一价金属或多价金属的化学当量; Ph为苯基; m是单独的1或2，n分别为0,1或2.它们的制备方法和使用这些化合物作为水溶性催化剂体系的组分的烯烃和烯属不饱和化合物的加氢甲酰化也被公开。