摘要:
An object of the invention is to provide a jig electrolytic stripper that can sufficiently remove palladium adhered to the current-conducting portion of a plating jig, that can remove palladium adhered to the insulating-material-coated portion of the jig, and that exhibits reduced erosion of the metal of the current-conducting portion of the jig. The jig electrolytic stripper comprises the following components (A) to (C): (A) at least one member selected from the group consisting of nitric acid and salts thereof, (B) at least one member selected from the group consisting of ammonia, ammonium salts, ethylene amine compounds, alkyl diamine compounds, and amino acids, and (C) a bromide.
摘要:
The present invention relates to a process for the preparation of ruthenium(III) chloride (RuCl3) as well to a process for the purification of ruthenium(III) chloride (RuCl3) and a use of the process for the preparation or the purification of ruthenium(III) chloride (RuCl3).
摘要:
Hydrometallurgical methods are described for the isolation and recovery of platinum from rhenium-containing materials, and more particularly, from superalloys containing rhenium, platinum, and other metals. In addition, apparatuses capable of carrying out the hydrometallurgical methods and the product streams generated from the methods and apparatuses are described.
摘要:
A non-lead composition for use as a thick-film resistor paste in electronic applications. The composition comprises particles of Li2RuO3 of diameter between 0.5 and 5 microns and a lead-free frit. The particles have had the lithium at or near primarily the surface of the particle at least partially exchanged for atoms of other metals.
摘要:
The invention relates to a process for the solvent extraction of palladium from aqueous solutions of palladium salts which contain nitrate ions and are essentially free of halide and pseudohalide ions, pyridinecarboxylic esters being used as the extraction medium.
摘要:
There is described a process for the separation and purification of the platinum group metals from base metal out of acidic aqueous solutions. For this purpose there is used a substituted thiourea of the formulaR.sub.1 R.sub.2 N--CS--NH--CO--R.sub.3orR.sub.1 R.sub.2 N--CS--NH--COOR.sub.3as the extraction agent. Preferably there are employed N,N-dialkyl-N'-benzoylthiourea wherein R.sub.1 and R.sub.2 are methyl, n-butyl, or n-hexyl.
摘要:
Organic sulfur compounds containing a carbon-sulfur double bond are used to remove homogeneous catalyst group VIII metals from chemical process streams.
摘要:
Residues are formed in the carbonylation of esters or ethers, particularly in the production of acetic anhydride or ethylidene diacetate. When such residues contain noble metal, typically rhodium, used as a catalyst, the noble metals must be recovered before the residues can be disposed of. The metal values are freed from the residues by treatment with amines, thereby enabling the rhodium to be extracted by subsequent contact with an aqueous halogen acid. The residues are pretreated with alkanols and concentrated by evaporation to improve the effect of such amine treatments.
摘要:
Salts of Group VIII noble metals are recovered from neutral or acidic solutions by admixing with the solution up to 10% by weight of hydrogen peroxide, adsorbing the salt of the Group VIII noble metal from the peroxide-containing solution on activated carbon and separating activated carbon containing the adsorbed Group VIII noble metal salts from solution diminished in concentration thereof.
摘要:
A catalyst residue containing osmium catalyst having a substantial component with a valency state less than +5 is regenerated to a valency state greater than +5 by contacting the residue with an organic hydroperoxide at a pH greater than 7 and the regenerated catalyst residue is recycled to a hydroxylation reactor containing ethylene or propylene, a polar organic solvent, an aqueous solution of cesium, rubidium, potassium or tetraalkylammonium hydroxide and an organic hydroperoxide.