Process for the solvent extraction of palladium from aqueous solutions
    5.
    发明授权
    Process for the solvent extraction of palladium from aqueous solutions 失效
    从水溶液中溶剂萃取钯的方法

    公开(公告)号:US5292491A

    公开(公告)日:1994-03-08

    申请号:US938215

    申请日:1992-10-16

    申请人: Oliver Schumacher

    发明人: Oliver Schumacher

    IPC分类号: C01G55/00 C22B3/36

    摘要: The invention relates to a process for the solvent extraction of palladium from aqueous solutions of palladium salts which contain nitrate ions and are essentially free of halide and pseudohalide ions, pyridinecarboxylic esters being used as the extraction medium.

    摘要翻译: PCT No.PCT / EP91 / 01193 Sec。 371日期:1992年10月16日 102(e)日期1992年10月16日PCT提交1991年6月26日PCT公布。 出版物WO92 / 01819 日本1992年2月6日。本发明涉及从含有硝酸根离子的钯盐的水溶液中溶剂萃取钯的方法,并且基本上不含卤化物和拟卤化物离子,吡啶羧酸酯用作提取介质。

    Regenerating perosmate catalyst
    10.
    发明授权
    Regenerating perosmate catalyst 失效
    再生渗硅催化剂

    公开(公告)号:US4280924A

    公开(公告)日:1981-07-28

    申请号:US107867

    申请日:1979-12-28

    摘要: A catalyst residue containing osmium catalyst having a substantial component with a valency state less than +5 is regenerated to a valency state greater than +5 by contacting the residue with an organic hydroperoxide at a pH greater than 7 and the regenerated catalyst residue is recycled to a hydroxylation reactor containing ethylene or propylene, a polar organic solvent, an aqueous solution of cesium, rubidium, potassium or tetraalkylammonium hydroxide and an organic hydroperoxide.

    摘要翻译: 通过使残余物与pH大于7的有机氢过氧化物接触,将含有价态小于+5的实质组分的含锇催化剂的催化剂残余物再生成大于+5的化合态,并将再生催化剂残余物再循环至 含有乙烯或丙烯的羟基化反应器,极性有机溶剂,铯,铷,钾或四烷基氢氧化铵的水溶液和有机氢过氧化物。