Abstract:
A process for continuously producing water-absorbing polymer particles, wherein the acrylic acid used to produce the polymer particles has a low purity.
Abstract:
A process for producing water-absorbing polymer particles, wherein an aqueous polymer gel is applied by means of a swivel belt to the conveyor belt of a forced-air belt drier, and the swivel belt, proceeding from one end position, is accelerated through a first pivot angle to an angular speed v1, decelerated through a second pivot angle to an angular speed v2 and decelerated through a third pivot angle to the other end position.
Abstract:
A process for producing water-absorbing polymer particles by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets and postcrosslinking the polymer particles, wherein the postcrosslinked polymer particles are at least partly coated.
Abstract:
A process for producing water-absorbing polymer particles with a low centrifuge retention capacity by polymerizing in a continuous kneading reactor under an inert gas volume flow of at most 10 m3/h per m3 of reactor volume.
Abstract:
Foams composed of water-absorbing basic polymers, obtainable by (I) foaming a crosslinkable aqueous mixture including (a) at least one basic polymer whose basic groups have optionally been neutralized, (b) at least one crosslinker, (c) at least one surfactant, (d) optionally at least one solubilizer, (e) optionally thickeners, foam stabilizers, fillers, fibers and/or cell nucleators, and (f) optionally particulate water-absorbing acidic polymers, by dissolving a gas which is inert toward free radicals in the crosslinkable aqueous mixture under a pressure from 2 to 400 bar and subsequently decompressing the crosslinkable aqueous mixture to atmospheric or by dispersing fine bubbles of a gas which is inert toward free radicals, and (II) crosslinking the foamed mixture to form a hydrogel foam and if applicable adjusting the water content of the polymer foam to 1-60% by weight. Preparation of the foams by application of the abovementioned measures (I) and (II) and use of the thus obtainable foams in hygiene articles to absorb body fluids, in dressing material to cover wounds, as a sealing material, as a packaging material, as a soil improver, as a soil substitute, to dewater sludges, to absorb aqueous acidic wastes, to thicken waterborne paints or coatings in the course of disposing of residual quantities thereof, to dewater water-containing oils or hydrocarbons or as a material for filters in ventilation systems.
Abstract:
The invention relates to the production of superabsorbent polymers on a continuous belt reactor, comprising at least one rotating knife that cuts the formed polymer gel at the end of the continuous belt reactor, wherein the length of the cutting edge is at least 1 cm and the cutting edge is non-parallel to the rotation axis.
Abstract:
A process for preparing water-absorbing polymer beads with high permeability by polymerizing droplets of a monomer solution in a gas phase surrounding the droplets, wherein a water-insoluble inorganic salt is suspended in the monomer solution and the polymer beads have a mean diameter of at least 150 μm.
Abstract:
A process for producing water-absorbing polymeric particles comprises conducting the polymerization in at least two parallel continuous polymerization reactors under substantially identical conditions and further processing the reaction products conjointly in at least one process step.
Abstract:
The present invention relates to novel (meth)acrylic esters of polyalkoxylated trimethylolpropane of the formula where EO is O—CH2-CH2- PO is independently at each instance O—CH2-CH(CH3)- or O—CH(CH3)-CH2- n1, n2 and n3 are independently 4, 5 or 6, n1+n2+n3 is 14, 15 or 16, m1, m2 and m3 are independently 1, 2 or 3, m1+m2+m3 is 4, 5 or 6, R1, R2 and R3 are independently H or CH3, a simplified process for preparing these esters and the use of reaction mixtures thus obtainable.
Abstract:
The invention relates to a process for the gel or surface postcrosslinking of water-absorbing polymers in which the polymers are treated with a surface postcrosslinking solution and during or after the treatment are postcrosslinked and dried by means of an increase in temperature, the crosslinker being a compound of the formula in which R1 and R2 independently of one another are H, hydroxyl, phenyl or C1-C6-alkyl, R3 is hydrogen, C1-C12-alkyl, C1-C12-alkenyl or C6-C12-aryl and R4 and R5 independently of one another are C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl, hydroxyl, C1-C12-alkoxy or hydrogen, dissolved in an inert solvent, to water-absorbing polymers which can be obtained by said process, and to their use in hygiene articles, packaging materials and nonwovens.