Foams made from water-absorbing, basic polymers, method for the production and utilization thereof
    35.
    发明授权
    Foams made from water-absorbing, basic polymers, method for the production and utilization thereof 有权
    由吸水性碱性聚合物制成的泡沫体,其生产和利用方法

    公开(公告)号:US07838567B2

    公开(公告)日:2010-11-23

    申请号:US10502212

    申请日:2003-01-30

    Abstract: Foams composed of water-absorbing basic polymers, obtainable by (I) foaming a crosslinkable aqueous mixture including (a) at least one basic polymer whose basic groups have optionally been neutralized, (b) at least one crosslinker, (c) at least one surfactant, (d) optionally at least one solubilizer, (e) optionally thickeners, foam stabilizers, fillers, fibers and/or cell nucleators, and (f) optionally particulate water-absorbing acidic polymers, by dissolving a gas which is inert toward free radicals in the crosslinkable aqueous mixture under a pressure from 2 to 400 bar and subsequently decompressing the crosslinkable aqueous mixture to atmospheric or by dispersing fine bubbles of a gas which is inert toward free radicals, and (II) crosslinking the foamed mixture to form a hydrogel foam and if applicable adjusting the water content of the polymer foam to 1-60% by weight. Preparation of the foams by application of the abovementioned measures (I) and (II) and use of the thus obtainable foams in hygiene articles to absorb body fluids, in dressing material to cover wounds, as a sealing material, as a packaging material, as a soil improver, as a soil substitute, to dewater sludges, to absorb aqueous acidic wastes, to thicken waterborne paints or coatings in the course of disposing of residual quantities thereof, to dewater water-containing oils or hydrocarbons or as a material for filters in ventilation systems.

    Abstract translation: 由吸水性碱性聚合物组成的泡沫体可通过(I)发泡可交联水性混合物得到,所述可交联水性混合物包括(a)至少一种碱性基团任选被中和的碱性聚合物,(b)至少一种交联剂,(c)至少一种 表面活性剂,(d)任选的至少一种增溶剂,(e)任选的增稠剂,泡沫稳定剂,填料,纤维和/或细胞成核剂,和(f)任选的颗粒状吸水性酸性聚合物, 在2至400巴的压力下在可交联水性混合物中的基团,随后将可交联的含水混合物减压至大气或通过分散对自由基呈惰性的气体的细小气泡,和(II)将发泡混合物交联以形成水凝胶 泡沫,如果适用,将聚合物泡沫的含水量调节至1-60重量%。 通过应用上述措施(I)和(II)制备泡沫体,并将如此获得的泡沫在卫生制品中的使用以吸收体液,在敷料中覆盖伤口作为密封材料作为包装材料,如 土壤改良剂,作为土壤替代物,去除污泥,吸收含水酸性废物,在处理剩余量的过程中加厚水性涂料或涂料,将含水油或碳氢化合物或用作过滤器的材料脱水 通风系统。

    Process for crosslinking hydrogels with bis- and poly-2- oxazolidinones
    40.
    发明授权
    Process for crosslinking hydrogels with bis- and poly-2- oxazolidinones 有权
    用双 - 和多 - 2-恶唑烷酮交联水凝胶的方法

    公开(公告)号:US06472478B1

    公开(公告)日:2002-10-29

    申请号:US09601349

    申请日:2000-08-18

    CPC classification number: A61L15/60 C08F8/30 Y10S524/916 Y10T442/699

    Abstract: The invention relates to a process for the gel or surface postcrosslinking of water-absorbing polymers in which the polymers are treated with a surface postcrosslinking solution and during or after the treatment are postcrosslinked and dried by means of an increase in temperature, the crosslinker being a compound of the formula in which R1 and R2 independently of one another are H, hydroxyl, phenyl or C1-C6-alkyl, R3 is hydrogen, C1-C12-alkyl, C1-C12-alkenyl or C6-C12-aryl and R4 and R5 independently of one another are C1-C12-alkyl, C1-C12-alkenyl, C6-C12-aryl, hydroxyl, C1-C12-alkoxy or hydrogen, dissolved in an inert solvent, to water-absorbing polymers which can be obtained by said process, and to their use in hygiene articles, packaging materials and nonwovens.

    Abstract translation: 本发明涉及一种吸水聚合物的凝胶或表面后交联方法,其中聚合物用表面后交联溶液处理,并且在处理之间或之后,通过温度升高进行后交联和干燥,交联剂为 R 1和R 2彼此独立地是H,羟基,苯基或C 1 -C 6烷基的化合物,R 3是氢,C 1 -C 12 - 烷基,C 1 -C 12 - 烯基或C 6 -C 12 - 芳基,R 4和R 5 彼此独立地是溶解在惰性溶剂中的C 1 -C 12烷基,C 1 -C 12 - 烯基,C 6 -C 12 - 芳基,羟基,C 1 -C 12 - 烷氧基或氢,可以通过所述 过程,以及它们在卫生用品,包装材料和无纺布中的应用。

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