公开(公告)号：US5942465A

公开(公告)日：1999-08-24

申请号：US035709

申请日：1998-03-05

申请人： Elizabeth G. Burns ,  John DiCillo ,  Kristine B. Lawrence

发明人： Elizabeth G. Burns ,  John DiCillo ,  Kristine B. Lawrence

IPC分类号： B41M5/382 ,  B41M5/00 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/42 ,  B41M5/50 ,  B41M5/52 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/38235 ,  B41M5/385 ,  B41M5/52 ,  B41M5/3854 ,  B41M5/388 ,  B41M5/39 ,  B41M5/5218 ,  B41M5/5254 ,  B41M5/5272 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/31786

摘要： A thermal dye transfer assemblage comprising:(a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, said dye being:I) an electrically neutral, deprotonated, delocalized cationic dye precursor;II) a pendant basic dye of the formula D-(L-E).sub.m wherein D represents the residue of a dye, L represents a linking group, E represents a moiety with basic properties and m is an integer of 1-3; orIII) a cationic dye precursor having the following structure: ##STR1## and (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a mixture ofi) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity; andii) a polyester which has been polymerized in the presence of an aluminum salt and which contains an aluminum ion.

摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料为：I）电中性，去质子化的离域阳离子染料前体; II）式D-（L-E）m的侧基碱性染料，其中D表示染料的残基，L表示连接基团，E表示具有碱性的部分，m为1-3的整数; 或III）具有以下结构的阳离子染料前体：和（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，所述染料接收元件与染料供体元件重叠关系 使得染料层与染料影像接收层接触，染料影像接收层包含i）Tg小于约19℃且不具有或仅具有轻微酸度的聚合物的混合物; 和ii）在铝盐存在下聚合并含有铝离子的聚酯。

公开(公告)号：US5939355A

公开(公告)日：1999-08-17

申请号：US47158

申请日：1998-03-24

申请人： Elizabeth G. Burns ,  John DiCillo ,  Matthew Wayne Johns ,  Kristine B. Lawrence

发明人： Elizabeth G. Burns ,  John DiCillo ,  Matthew Wayne Johns ,  Kristine B. Lawrence

IPC分类号： B32B27/36 ,  B41M5/00 ,  B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/50 ,  B41M5/52 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/38235 ,  B41M5/385 ,  B41M5/52 ,  B41M5/3854 ,  B41M5/388 ,  B41M5/39 ,  B41M5/5218 ,  B41M5/5254 ,  B41M5/5272 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/31786

摘要： A thermal dye transfer assemblage comprising:(a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, said dye being:I) an electrically neutral, deprotonated, delocalized cationic dye precursor;II) a pendant basic dye of the formula D-(L-E).sub.m wherein D represents the residue of a dye, L represents a linking group, E represents a moiety with basic properties and m is an integer of 1-3; orIII) a cationic dye precursor having the following structure: ##STR1## and (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a mixture ofi) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity;ii) a sulfonated polyester; andiii) a hydrated transition metal or metalloid salt of a strong acid.

摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料为：I）电中性，去质子化的离域阳离子染料前体; II）式D-（L-E）m的侧基碱性染料，其中D表示染料的残基，L表示连接基团，E表示具有碱性的部分，m为1-3的整数; 或III）具有以下结构的阳离子染料前体：和（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，所述染料接收元件与染料供体元件重叠关系 使得染料层与染料影像接收层接触，染料影像接收层包含i）Tg小于约19℃且不具有或仅具有轻微酸度的聚合物的混合物; ii）磺化聚酯; 和iii）强酸的水合过渡金属或准金属盐。

公开(公告)号：US5804531A

公开(公告)日：1998-09-08

申请号：US995728

申请日：1997-12-22

申请人： Steven Evans ,  Teh-Ming Kung ,  Kristine B. Lawrence ,  Richard C. VanHanehem

发明人： Steven Evans ,  Teh-Ming Kung ,  Kristine B. Lawrence ,  Richard C. VanHanehem

IPC分类号： B41M5/035 ,  B41M5/00 ,  B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/50 ,  B41M5/52 ,  B41M5/38

CPC分类号： B41M5/385 ,  B41M5/3854 ,  B41M5/3856 ,  B41M5/388 ,  B41M5/39 ,  B41M5/52 ,  B41M5/5227 ,  B41M5/5272 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/31786

摘要： A thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being: I) an electrically neutral, deprotonated, delocalized cationic dye precursor; II) a pendant basic dye of the formula D-(L-E).sub.m wherein D represents the residue of a dye, L represents a covalent linking group, E represents a moiety with basic properties and m is an integer of 1-3; or III) a cationic dye precursor having the following structure: ##STR1## (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the dye image-receiving layer, the dye image-receiving layer comprising a polyester ionomer comprising a polyester backbone containing units of a salt of a sulfonic acid or sulfonimide and a basic nitrogen-containing compound which has a pKa of its conjugate acid in the range from about 6 to about 10.

摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料为：I）电中性，去质子化的离域阳离子染料前体; II）式D-（L-E）m的侧基碱性染料，其中D表示染料的残基，L表示共价连接基团，E表示具有碱性的部分，m表示1-3的整数; 或III）具有以下结构的阳离子染料前体：（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，所述染料接收元件与染料接收元件处于重叠关系， 供体元件，使得染料层与染料影像接收层接触，染料影像接收层包含聚酯离聚物，其包含含有磺酸或磺酰亚胺盐和含碱性含氮化合物的单元的聚酯骨架 其共轭酸的pKa在约6至约10的范围内。

公开(公告)号：US5786300A

公开(公告)日：1998-07-28

申请号：US878924

申请日：1997-06-19

申请人： Wayne A. Bowman ,  Robert A. Guistina ,  Kristine B. Lawrence

发明人： Wayne A. Bowman ,  Robert A. Guistina ,  Kristine B. Lawrence

IPC分类号： B41M5/30 ,  B41M5/00 ,  B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/50 ,  B41M5/52 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/385 ,  B41M5/52 ,  B41M5/5218 ,  B41M5/5254 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24802 ,  Y10T428/31855

摘要： A thermal dye transfer assemblage comprising: (I) a dye-donor element comprising a support having thereon sequentially repeating dye layer patches of a dye dispersed in a polymeric binder, at least one of the dye patches containing a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N-H group which is part of a conjugated system; and (II) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer comprising a polymer having a Tg of less than about 9.degree. C. and being of no or only slight acidity and a hydrated transition metal or metalloid salt of a strong acid, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer.

摘要翻译： 一种热染料转移组合物，其包含：（I）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料顺序重复染料层贴片的载体，至少一种含有去质子化阳离子染料的染色剂，其能够 被染色成具有作为共轭体系的一部分的NH基团的阳离子染料; 和（II）染料接收元件，其包含其上具有聚合物染料影像接收层的载体，所述聚合物染料影像接收层包含Tg小于约9℃并且不具有或仅具有轻微酸性的聚合物和水合过渡金属或准金属 强酸的盐，染料接收元件与染料供体元件重叠关系，使得染料层与聚合染料影像接收层接触。

公开(公告)号：US5744422A

公开(公告)日：1998-04-28

申请号：US878704

申请日：1997-06-19

申请人： Steven Evans ,  Helmut Weber ,  Kristine B. Lawrence ,  Robert A. Guistina

发明人： Steven Evans ,  Helmut Weber ,  Kristine B. Lawrence ,  Robert A. Guistina

IPC分类号： B41M5/30 ,  B41M5/00 ,  B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/50 ,  B41M5/52 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/5218 ,  B41M5/385 ,  B41M5/3852 ,  B41M5/3854 ,  B41M5/388 ,  B41M5/39 ,  B41M5/52 ,  B41M5/5254 ,  B41M5/5272 ,  B41M5/5281 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/259

摘要： A thermal dye transfer assemblage comprising: (I) a dye-donor element comprising a support having thereon sequentially repeating dye layer patches of a dye dispersed in a polymeric binder, at least one of the dye patches containing a pendant basic-substituted dye having the formula: A-(L-B).sub.m wherein: A represents a thermally transferable dye residue, L represents a divalent linking group, B represents a basic substituent, and m represents an integer of from 1 to 3; and (II) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer containing a hydrated transition metal or metalloid salt of a strong acid.

摘要翻译： 一种热染料转移组合物，其包含：（I）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料上的顺序重复的染料层片的载体，至少一种含有碱性取代染料的染料， 式中：A表示可热转移的染料残基，L表示二价连接基团，B表示碱性取代基，m表示1〜3的整数。 和（II）染料接收元件，其包含其上具有聚合染料影像接收层的载体，染料接收元件与染料供体元件重叠关系，使得染料层与聚合染料接触 图像接收层，聚合染料影像接收层含有强酸的水合过渡金属或准金属盐。

公开(公告)号：US5733846A

公开(公告)日：1998-03-31

申请号：US761055

申请日：1996-12-05

申请人： Elizabeth G. Burns ,  John DiCillo ,  Kristine B. Lawrence ,  Richard C. VanHanehem

发明人： Elizabeth G. Burns ,  John DiCillo ,  Kristine B. Lawrence ,  Richard C. VanHanehem

IPC分类号： B41M5/382 ,  B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  B41M5/50 ,  B41M5/52 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/385 ,  B41M5/52 ,  B41M5/3854 ,  B41M5/388 ,  B41M5/39 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/24802 ,  Y10T428/31855

摘要： A thermal dye transfer assemblage comprising: (a) a dye-donor element comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, the dye being a deprotonated cationic dye which is capable of being reprotonated to a cationic dye having a N-H group which is part of a conjugated system, and (b) a dye-receiving element comprising a support having thereon a polymeric dye image-receiving layer, the dye-receiving element being in a superposed relationship with the dye-donor element so that the dye layer is in contact with the polymeric dye image-receiving layer, the polymeric dye image-receiving layer comprising a mixture of i) a polymer having a Tg of less than about 19.degree. C. and having no or only slight acidity; and ii) a polymeric acid with a saturated hydrocarbon backbone capable of reprotonating the deprotonated cationic dye.

摘要翻译： 一种热染料转移组合物，包括：（a）染料供体元件，其包含其上具有分散在聚合物粘合剂中的染料层的载体，所述染料是去质子化的阳离子染料，其能够被再赋色为阳离子染料， 作为共轭体系的一部分的NH基团，和（b）染料接收元件，其包含其上具有聚合染料影像接收层的载体，染料接收元件与染料供体元件重叠关系，因此 染料层与聚合物染料影像接收层接触，聚合染料影像接收层包含i）Tg小于约19℃且不具有或仅具有轻微酸度的聚合物的混合物; 和ii）具有能够使去质子化的阳离子染料重现的饱和烃主链的聚合酸。

公开(公告)号：US5369080A

公开(公告)日：1994-11-29

申请号：US169779

申请日：1993-12-16

申请人： Kristine B. Lawrence ,  Steven Evans

发明人： Kristine B. Lawrence ,  Steven Evans

IPC分类号： B41M5/385 ,  B41M5/388 ,  B41M5/39 ,  C09B53/02 ,  C09B55/00 ,  B41M5/035 ,  B41M5/38

CPC分类号： B41M5/39 ,  B41M5/3858 ,  C09B53/02 ,  B41M2205/30 ,  Y10S428/913 ,  Y10S428/914 ,  Y10T428/31786

摘要： A cyan dye-donor element for thermal dye transfer imaging comprising a support having thereon a dye layer comprising a dye dispersed in a polymeric binder, wherein the dye comprises a mixture of at least two different cyan dyes, each of the dyes comprising a 2-carbamoyl-4-[N-(p-substituted aminoaryl)imino]-1,4-naphthoquinone, with the proviso that at least one dye is present at a concentration of at least 10 wt.% and that same dye also contains an alkyl group substituted with a group capable of intermolecular hydrogen bonding.

摘要翻译： 一种用于热染料转移成像的青色染料供体元件，包括其上具有分散在聚合物粘合剂中的染料层的载体，其中所述染料包含至少两种不同的青色染料的混合物，每种染料包含2- 氨基甲酰基-4- [N-（对取代氨基芳基）亚氨基] -1,4-萘醌，条件是至少一种染料以至少10重量％的浓度存在，并且相同的染料还含有烷基 该基团被能够分子间氢键的基团取代。

公开(公告)号：US06699538B2

公开(公告)日：2004-03-02

申请号：US09999469

申请日：2001-10-31

申请人： Kristine B. Lawrence ,  Paul B. Merkel ,  Hwei-Ling Yau

发明人： Kristine B. Lawrence ,  Paul B. Merkel ,  Hwei-Ling Yau

IPC分类号： B41M500

CPC分类号： B41M5/52 ,  B41M5/506 ,  B41M5/5254 ,  Y10T428/24802

摘要： An ink jet recording element having a support having thereon the following layers in order: a) a base layer having a polymeric binder and a polymeric mordant; and b) an overcoat layer having a polymeric UV-absorbing material.

摘要翻译： 一种具有支撑体的喷墨记录元件，其上具有以下层：a）具有聚合物粘合剂和聚合物媒染剂的基底层; 和b）具有聚合物UV吸收材料的外涂层。

公开(公告)号：US06527387B2

公开(公告)日：2003-03-04

申请号：US09770781

申请日：2001-01-26

申请人： Kristine B. Lawrence ,  Tien-Teh Chen ,  Yongcai Wang

发明人： Kristine B. Lawrence ,  Tien-Teh Chen ,  Yongcai Wang

IPC分类号： B41J201

CPC分类号： B41M5/52 ,  B41M5/5236 ,  B41M5/5245 ,  B41M5/5254

摘要： An ink jet printing method, comprising the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink-receptive elements comprising a support having thereon an image-receiving layer comprising a cationic polymer containing at least one ethylenically unsaturated monomer containing a trialkylammonium salt, each trialkylammonium salt containing at least one alkyl group having greater than 8 carbon atoms; C) loading the printer with an ink jet ink composition comprising water, a humectant, and a water-soluble anionic dye; and D) printing on the image-receiving layer using the ink jet ink in response to the digital data signals.

摘要翻译： 一种喷墨打印方法，包括以下步骤：A）提供对数字数据信号作出响应的喷墨打印机; B）将所述打印机装载到具有包含载体的油墨接收元件，所述支撑体上具有包含阳离子聚合物的图像接收层 含有至少一种含有三烷基铵盐的烯属不饱和单体，每个三烷基铵盐含有至少一个具有大于8个碳原子的烷基; C）用包含水，湿润剂和水溶性的喷墨油墨组合物装载打印机 阴离子染料; 和D）响应于数字数据信号使用喷墨油墨在图像接收层上进行打印。

公开(公告)号：US06454404B1

公开(公告)日：2002-09-24

申请号：US09770128

申请日：2001-01-26

申请人： Kristine B. Lawrence ,  David M. Teegarden

发明人： Kristine B. Lawrence ,  David M. Teegarden

IPC分类号： G01D1100

CPC分类号： B41M5/5245 ,  C09D11/30

摘要： An inkjet printing method, including comprising the steps of: A) providing an ink jet printer that is responsive to digital data signals; B) loading the printer with ink-receptive elements including comprising a support having thereon an image-receiving layer including comprising a cationic, water-dispersible, partially quaternized pyridine-containing polymer; C) loading the printer with an ink jet ink composition including comprising water, a humectant, and a water soluble anionic dye; and D) printing on said image-receiving layer using said ink jet ink in response to said digital data signals.

摘要翻译： 一种喷墨打印方法，包括以下步骤：A）提供响应于数字数据信号的喷墨打印机; B）将所述打印机装载到具有墨接受元件的装置中，所述墨盒包括包括其上具有图像接收层的支撑件，包括： 阳离子，水分散性，部分季铵化的含吡啶聚合物; C）用包含水，湿润剂和水溶性阴离子染料的喷墨油墨组合物装载打印机; 和D）响应于所述数字数据信号在所述图像接收层上使用所述喷墨油墨进行打印。