公开(公告)号：US20050271987A1

公开(公告)日：2005-12-08

申请号：US11187870

申请日：2005-07-25

申请人： Katsuhiro Yamashita ,  Katsumi Kobayashi ,  Takanori Hioki

发明人： Katsuhiro Yamashita ,  Katsumi Kobayashi ,  Takanori Hioki

IPC分类号： G03C1/005 ,  G03C1/035 ,  G03C1/09 ,  G03C1/12 ,  G03C1/16 ,  G03C1/18 ,  G03C1/20 ,  G03C1/22 ,  G03C1/29 ,  G03C1/34 ,  G03C7/30

CPC分类号： G03C7/3041 ,  G03C1/0051 ,  G03C1/09 ,  G03C1/12 ,  G03C1/127 ,  G03C1/16 ,  G03C1/18 ,  G03C1/20 ,  G03C1/22 ,  G03C1/29 ,  G03C2001/097

摘要： An object of the present invention is to provide a silver halide photographic light-sensitive material which is reduced in the various problems ascribable to the multilayer adsorption of a sensitizing dye. A silver halide photographic emulsion comprising a silver halide grain having adsorbed on the surface thereof a sensitizing dye in multiple layers is described, wherein the variation coefficient of the light absorption strength distribution among the grains is 100% or less.

摘要翻译： 本发明的目的是提供一种卤化银摄影感光材料，其减少了由致敏染料的多层吸附引起的各种问题。 描述了包含在其表面上吸附有多层感光染料的卤化银颗粒的卤化银照相乳剂，其中颗粒之间的光吸收强度分布的变化系数为100％以下。

公开(公告)号：US06762015B2

公开(公告)日：2004-07-13

申请号：US09845355

申请日：2001-05-01

申请人： Tetsuo Nakamura ,  Takanori Hioki

发明人： Tetsuo Nakamura ,  Takanori Hioki

IPC分类号： G03C112

CPC分类号： G03C1/29 ,  G03C1/0051 ,  G03C1/09 ,  G03C1/14 ,  G03C1/16 ,  G03C1/18 ,  G03C2001/097

摘要： A silver halide photographic emulsion which contains at least two sensitizing dyes represented by the following formula (I): Dye-((A)rQ)q(M)m  (I) wherein Dye represents a dye moiety; A represents a linking group; Q represents a dissociable group; r represents 0 or 1; q represents an integer of 2 or more; provided that at least one Q represents —SO3H and at least one Q represents a dissociable group other than —SO3H; M represents a counter ion; and m represents a number of 0 or more necessary to neutralize the electric charge in the molecule, and when 2 represents 2 or more, M's need not be the same.

摘要翻译： 含有至少两种由下式（I）表示的增感染料的卤化银照相乳剂：其中染料代表染料部分; A表示连接基团; Q表示可离解的基团; r表示0或1; q表示2以上的整数， 条件是至少一个Q表示-SO 3 H，并且至少一个Q表示除-SO 3 H以外的可离解基团; M表示抗衡离子; m表示中和分子中的电荷所需的0以上的数，当2表示2以上时，M不必相同。

公开(公告)号：US06759186B2

公开(公告)日：2004-07-06

申请号：US10058285

申请日：2002-01-30

申请人： Tetsuo Nakamura ,  Kimiyasu Morimura ,  Takanori Hioki

发明人： Tetsuo Nakamura ,  Kimiyasu Morimura ,  Takanori Hioki

IPC分类号： G03C1005

CPC分类号： G03C1/29 ,  C09B23/0008 ,  C09B23/04 ,  C09B23/06 ,  G03C1/0051 ,  G03C1/09 ,  G03C2001/097

摘要： A silver halide photographic material is disclosed, comprising at least one silver halide emulsion layer provided on a support, the emulsion layer comprising a silver halide emulsion containing at least two sensitizing dyes represented by the following general formula (I): wherein X represents an oxygen atom, sulfur atom, selenium atom or NR′; R and R′ each represent a substituted or unsubstituted alkyl, aryl or heterocyclic group; D represents a group required to form a methine dye; M represents a counter ion; and m represents a number of not smaller than 0 required to neutralize the electric charge in the molecule.

摘要翻译： 公开了一种卤化银照相材料，其包含至少一个设置在载体上的卤化银乳剂层，所述乳剂层包含含有至少两种由以下通式（I）表示的增感染料的卤化银乳剂：其中X表示氧 原子，硫原子，硒原子或NR'; R和R'各自表示取代或未取代的烷基，芳基或杂环基; D表示形成次甲基染料所需的基团; M表示抗衡离子; m表示中和分子中的电荷所需的不小于0的数。

公开(公告)号：US06649337B2

公开(公告)日：2003-11-18

申请号：US09987620

申请日：2001-11-15

申请人： Takanori Hioki ,  Katsumi Kobayashi

发明人： Takanori Hioki ,  Katsumi Kobayashi

IPC分类号： G03C112

CPC分类号： G03C1/49854 ,  G03C1/12 ,  G03C1/49818 ,  G03C2001/03594

摘要： A heat-developable photosensitive material comprises: a support; a photosensitive silver halide; a non-photosensitive organic silver salt; a reducing agent for a silver ion; a binder; and a compound having specified structure.

公开(公告)号：US06566044B2

公开(公告)日：2003-05-20

申请号：US09816062

申请日：2001-03-26

申请人： Katsuhisa Ohzeki ,  Tetsuo Nakamura ,  Takanori Hioki

发明人： Katsuhisa Ohzeki ,  Tetsuo Nakamura ,  Takanori Hioki

IPC分类号： G03C108

CPC分类号： G03C1/29 ,  C09B23/0008 ,  C09B23/0066 ,  C09B23/0075 ,  C09B23/0083 ,  C09B23/04 ,  C09B23/06 ,  C09B23/08 ,  C09B23/102 ,  C09B23/107 ,  G03C1/0051 ,  G03C5/26 ,  Y10S430/146 ,  Y10S430/164

摘要： The present invention provides a silver halide photographic material that is excellent in photographic speed as well as image graininess and exhibits low residual color even after rapid processing. The silver halide photographic material contains a compound represented by formula (I) and a compound represented by formula (II), as defined.

公开(公告)号：US06461803B1

公开(公告)日：2002-10-08

申请号：US09655837

申请日：2000-09-06

申请人： Yoichi Suga ,  Takanori Hioki ,  Jun Okamoto

发明人： Yoichi Suga ,  Takanori Hioki ,  Jun Okamoto

IPC分类号： G03C146

CPC分类号： G03C1/46 ,  G03C1/16 ,  G03C7/3041

摘要： A silver halide color photographic lightsensitive material comprising at least one red-sensitive silver halide emulsion layer, at least one green-sensitive silver halide emulsion layer and at least one blue-sensitive silver halide emulsion layer on a support, wherein the lightsensitive material has an ISO speed of 640 or more, and has a variation, in terms of a SNGR ratio, of magenta and cyan colors of 0 dB or more when the lightsensitive material is subjected to each of white light exposure, white fluorescent lamp exposure and three band fluorescent lamp exposure.

摘要翻译： 一种卤化银彩色照相感光材料，其包含至少一种感红卤化银乳剂层，至少一种感绿卤化银乳剂层和至少一种蓝色感光卤化银乳剂层，其中所述光敏材料具有 ISO感光度为640以上，并且当感光材料经受白光曝光，白色荧光灯曝光和三色荧光灯时，具有0dB以上的品红色和青色的SNGR比的变化 灯曝光

公开(公告)号：US06365335B1

公开(公告)日：2002-04-02

申请号：US09373584

申请日：1999-08-13

申请人： Takanori Hioki ,  Kiyoshi Morimoto

发明人： Takanori Hioki ,  Kiyoshi Morimoto

IPC分类号： G03C112

CPC分类号： G03C1/14 ,  G03C1/0051 ,  G03C1/127 ,  G03C1/16 ,  G03C1/18 ,  G03C1/22 ,  G03C1/26 ,  G03C2001/0055

摘要： A Silver halide photographic material high in sensitivity and decreased in residual color is disclosed, which comprises at least one compound represented by the following formula (I): wherein Z1 represents an oxygen atom, a sulfur atom, a selenium atom, a tellurium atom, a carbon atom or a nitrogen atom; Q represents a group necessary for forming a methine dye; M1 represents a charge equilibrium counter ion; m1 represents the number necessary for neutralizing a charge of the molecule; Vp represents a group having a log P value lower than that of Cl; q1 represents 1, 2, 3 or 4; and R1 is represented by following: R1=(La)k1CONHSO2R11, R1=(Lb)k2SO2NHCOR12, R1=(Lc)k3CONHCOR13, R1=(Ld)k4SO2NHSO2R14 wherein R11, R12, R13 and R14 each represents an alkyl group, an aryl group, a heterocyclic group, an alkoxyl group, an aryloxy group, a heterocyclyloxy group or an amino group; La, Lb, Lc and Ld each represents a methylene group; and k1, k2, k3 a nd k4 each represents an integer of 1 to 18.

摘要翻译： 披露了高灵敏度和残留颜色降低的卤化银照相材料，其包含至少一种由下式（I）表示的化合物：其中Z1表示氧原子，硫原子，硒原子，碲原子， 碳原子或氮原子; Q表示形成次甲基染料所需的基团; M1表示电荷平衡反离子; m1表示中和分子的电荷所需的数目; Vp表示log P值低于Cl的基团; q1表示1,2,3或4; 并且R1表示如下：R1 =（La）k1CONHSO2R11，R1 =（Lb）k2SO2NHCOR12，R1 =（Lc）k3CONHCOR13，R1 =（Ld）k4SO2NHSO2R14其中R11，R12，R13和R14各自表示烷基， 杂环基，烷氧基，芳氧基，杂环氧基或氨基; La，Lb，Lc和Ld各自表示亚甲基; k1，k2，k3，...，k4分别表示1〜18的整数。

公开(公告)号：US5981162A

公开(公告)日：1999-11-09

申请号：US73763

申请日：1998-05-07

申请人： Takanori Hioki ,  Katsuhisa Ohzeki ,  Takashi Katoh

发明人： Takanori Hioki ,  Katsuhisa Ohzeki ,  Takashi Katoh

IPC分类号： G03C1/005 ,  G03C1/07 ,  G03C1/12 ,  G03C1/22 ,  G03C1/08 ,  G03C1/10

CPC分类号： G03C1/22 ,  G03C1/07 ,  G03C1/122 ,  G03C1/127 ,  G03C1/0051

摘要： A highly sensitive silver halide photographic material is described, which comprises at least one light-sensitive silver halide emulsion layer comprising at least one hemicyanine, hemioxonol, bishemicyanine or bishemioxonol dye having a particular structure and silver halide grains having an aspect ratio of from 3 to 50 or which comprises at least one light-sensitive silver halide emulsion layer comprising at least one bishemicyanine dye having a particular structure and silver halide grains at least 50%, based on projected area, of which are grains having a silver chloride content of at least 50 mole % and an outer surface at least 50% of which is constituted of (111) faces.

摘要翻译： 描述了一种高灵敏度的卤化银照相材料，其包括至少一种感光卤化银乳剂层，其包含至少一种具有特定结构的半花青，半氧杂醇，二草氰胺或二氯二氧杂环己烯染料，并且具有3至 50或其包含至少一种感光卤化银乳剂层，其包含至少一种具有特定结构的双氰胺染料和基于投影面积的至少50％的卤化银颗粒，其中至少具有氯化银含量至少为 50摩尔％，外表面的至少50％由（111）面构成。

公开(公告)号：US5763152A

公开(公告)日：1998-06-09

申请号：US622879

申请日：1996-03-29

申请人： Takanori Hioki ,  Mikio Ihama

发明人： Takanori Hioki ,  Mikio Ihama

IPC分类号： G03C1/10 ,  G03C1/12 ,  G03C1/14 ,  G03C1/20 ,  G03C1/22 ,  G03C1/26 ,  G03C1/34

CPC分类号： G03C1/12 ,  G03C1/10 ,  G03C1/127 ,  G03C1/14 ,  G03C1/20 ,  G03C1/22 ,  G03C1/26

摘要： A silver halide photographic light-sensitive material is disclosed. The material comprises a substrate provided thereon with at least one silver halide emulsion layer comprising at least one compound represented by the following Formula (I): ##STR1## wherein Ra and Rb each represents a hydrogen atom, an alkyl group having at least two carbon atoms or an aryl or heterocyclic group, provided that Ra and Rb do not simultaneously represent hydrogen atoms; La and Lb each represents a methylene group; L.sub.1 and L.sub.2 each represents a methine group; p.sub.1 represents 0 or 1; Z.sub.1 represents an atomic group required for forming a 5- or 6-membered nitrogen atom-containing heterocyclic ring; M.sub.1 represents a counterion required for balancing the electrical charge; m.sub.1 represents a numerical value of not less than 0 required for neutralizing the molecule; and Q represents a methine or polymethine group required for forming a methine dye. The light-sensitive material provides substantially low fogging, has high sensitivity and excellent storage stability and can provide images of high quality.

摘要翻译： 公开了一种卤化银照相感光材料。 该材料包括在其上设置有至少一个卤化银乳剂层的基底，所述卤化银乳剂层包含至少一种由下式（I）表示的化合物：其中Ra和Rb各自表示氢原子，具有至少两个碳原子的烷基 原子或芳基或杂环基团，条件是Ra和Rb不同时表示氢原子; La和Lb各自表示亚甲基; L1和L2各自表示次甲基; p1表示0或1; Z1表示形成5或6元含氮原子的杂环所需的原子团; M1代表平衡电荷所需的抗衡离子; m1表示中和分子所需的不小于0的数值; Q表示形成次甲基染料所需的次甲基或聚甲炔基。 感光材料提供基本上低雾度，具有高灵敏度和优异的储存稳定性，并且可以提供高质量的图像。

公开(公告)号：US5672469A

公开(公告)日：1997-09-30

申请号：US555095

申请日：1995-11-08

申请人： Takanori Hioki ,  Mikio Ihama

发明人： Takanori Hioki ,  Mikio Ihama

IPC分类号： G03C7/00 ,  G03C1/09 ,  G03C1/10 ,  G03C1/18 ,  G03C1/34

CPC分类号： G03C1/34 ,  G03C1/10 ,  G03C1/346

摘要： A silver halide photographic material comprising a support having thereon at least one light-sensitive layer, the photographic material comprising a reduction-sensitized silver halide emulsion containing a compound in which a group adsorptive to silver halide and a specific hydrazine structure are covalently bonded. The silver halide photographic material exhibits high sensitivity and improved fog characteristics and improved preservation stability.

摘要翻译： 一种卤化银照相材料，其包含其上具有至少一个感光层的载体，所述照相材料包含还原增感的卤化银乳剂，其含有其中吸附卤化银和特定肼结构的基团共价键合的化合物。 卤化银照相材料表现出高灵敏度和改善的雾特性和改善的保存稳定性。