摘要:
An object is to provide an electrolytic manganese dioxide with optimized properties, and a high capacity alkaline primary battery with excellent high-rate discharge characteristics. Disclosed is a spherical electrolytic manganese dioxide having an average circularity of 0.89 or more. The loss on heating from 200 to 400° C. of the spherical electrolytic manganese dioxide is preferably 2.5% by weight or more. Also disclosed is an alkaline primary battery including the above-described spherical electrolytic manganese dioxide as a positive electrode active material.
摘要:
A rectangular air battery includes: a first case having a bottom with air holes; a second case; and an insulating gasket with a substantially U-shaped cross-section. The first case and the second case are joined such that the opening of the second case faces the bottom of the first case, and are sealed by crimping the opening edge of the sidewalls of the first case onto the outer face of the second case, with the outer sidewalls of the insulating gasket interposed therebetween. A rib is provided on the bottom of the first case so as to protrude inward inside the first case. The rib extends along the four sidewalls of the first case and supports the inner lower end of the inner sidewalls of the insulating gasket, with at least a separator interposed therebetween.
摘要:
When the composite particle containing Si or Sn is used for the negative electrode, the ratio of the median diameter “Dc” of the conductive material to the median diameter “Da” of the negative electrode material (Dc/Da) is made from 0.02 to 0.5 in order to improve reduction in electron conductivity, which is attributed to fine division of the particles due to repeated charge/discharge.
摘要:
A negative electrode material for a nonaqueous electrolyte secondary battery having a high discharge capacity and a good cycle life is made from alloy particles having an average particle diameter of 0.1-50 μm and including Si phase grains 40 and a phase of a solid solution or an intermetallic compound of Si and other element selected from Group 2A elements, transition elements, Group 3B elements, and Group 4B elements from the long form periodic table (for example, an NiSi2 phase 42 and an [NiSi2+NiSi] phase 41) at least partially enveloping the Si phase grains. 5-99 wt % of this material is Si phase grains. The alloy particles can be manufactured by rapid solidification (such as atomization or roller quenching) of a melt including Si and the other element, or by adhering the other element to Si powder by electroless plating or mechanical alloying and then performing heat treatment. Even if rapid solidification is carried out, a negative electrode material having a good discharge capacity and cycle life is obtained without heat treatment.
摘要:
In cycles of charging and discharging, an excellent capacity maintenance rate is obtained. The charging and discharging cycle characteristic of battery is enhanced. Further, an excellent initial discharging capacity is obtained. A negative electrode, a positive electrode, and a non-aqueous electrolyte are contained. The negative electrode includes an alloy of Si, a first element and a second element. The first element includes at least one element selected from the group consisting of the second group element except Mg in the periodic table, transition elements, twelfth group element, thirteenth group element except B, and fourteenth group element except Si. The second element includes at least one element of B and Mg.
摘要:
This separator is provided at least at one surface thereof with a heat-resistant layer containing inorganic oxide particles and a binder, and the inorganic oxide particles have a component containing gallium in the range of 5 to 200 weight ppm in an aluminum oxide. This lithium ion secondary battery has: an electrode body including a positive electrode plate and a negative electrode plate laminated by interposing the separator therebetween; and a non-aqueous electrolytic solution impregnated in the electrode body. A lithium ion secondary battery using the separator having the heat-resistant layer is therefore less likely to cause a rise in resistance even in use under high-rate conditions.
摘要:
A non-aqueous electrolyte secondary battery includes a positive electrode, a negative electrode, and a heat-resistant layer disposed between the positive electrode and the negative electrode. The positive electrode of this secondary battery contains a positive electrode active substance having a hollow structure, which has a shell portion and a hollow portion formed inside the shell portion. In addition, the heat-resistant layer contains plate-shaped inorganic filler particles as the main component.
摘要:
An alkaline battery which is superior in high-rate discharge characteristics and in moderate- and low-rate discharge characteristics is provided.An alkaline battery according to the present invention includes a closed-end cylindrical battery case 8 housing a hollow cylindrical positive electrode 2, a negative electrode 3 disposed in a hollow portion of the positive electrode 2, a separator 4 sandwiched between the positive electrode 2 and the negative electrode 3, and an alkaline electrolyte. The negative electrode 3 is made of a zinc porous body made of a collection of zinc fibers. The alkaline electrolyte includes 0.05% to 0.5% by mass, both inclusive, of at least one of polyacrylate and polyacrylic acid with respect to a mass of zinc in the negative electrode 3.
摘要:
An alkaline battery which is superior in high-rate discharge characteristics and in moderate- and low-rate discharge characteristics is provided.An alkaline battery according to the present invention includes a closed-end cylindrical battery case 8 housing a hollow cylindrical positive electrode 2, a negative electrode 3 disposed in a hollow portion of the positive electrode 2, a separator 4 sandwiched between the positive electrode 2 and the negative electrode 3, and an alkaline electrolyte. The negative electrode 3 includes a zinc porous body. The alkaline electrolyte includes 0.1% to 2% by mass, both inclusive, of a surfactant having an average molecular weight of 120 to 350, both inclusive, with respect to a mass of zinc in the negative electrode 3. A capacity balance of the negative electrode/the positive electrode calculated under a condition in which MnO2 included in the positive electrode 2 has a theoretical capacity of 308 mAh/g and Zn included in the negative electrode 3 has a theoretical capacity of 820 mAh/g, is in the range from 0.9 to 1.1, both inclusive.
摘要:
The storage characteristics of an alkaline battery are improved by suppressing the production of hydrogen gas during storage. The alkaline battery includes a positive electrode, a negative electrode, and a conductive member in contact with the negative electrode. The negative electrode includes a zinc-containing negative electrode active material and an alkaline electrolyte, and the alkaline electrolyte includes a potassium hydroxide aqueous solution. The negative electrode active material, the alkaline electrolyte, and a contact surface of the conductive member with the negative electrode include the same metal element M, and the metal element M is a metal element other than zinc.