摘要:
MnOx-containing, base-metal oxide mixtures (e.g., MnOx—CeO2) are useful NOx oxidation catalyst materials and NOx storage materials in lean-burn engine exhaust gas treatments using Lean NOx Trap (LNT) systems. These oxidation catalyst materials are used in combination with a NOx storage material and a NOx reduction material. MnOx-containing oxide mixtures can replace platinum (Pt) in LNT systems where the exhaust of the engine is repeatedly varied between a relatively long fuel-lean mode of operation and a relatively short fuel-rich mode of operation. The combination of the MnOx oxidation catalyst, NOx storage material, and NOx reduction catalyst material serves to complete the oxidation of unburned hydrocarbons and carbon monoxide, and to convert NOx to nitrogen.
摘要:
A high-surface area fine particle dispersal of LaMnO3 or a promoted derivation of LaMnO3 may be prepared by the citrate method. The amount of citric acid used to complex the constituent metal cations into citrate complexed mixed metal compounds may range from about 40 mol % to about 100 mol % in excess of stoichiometry.
摘要:
The oxidation of nitrogen oxide (NO) in an oxygen-containing exhaust gas flow from a diesel or other lean-burn engine may be catalyzed using particles of co-precipitated and calcined manganese (Mn), cerium (Ce) and zirconium (Zr) mixed oxides. In preferred embodiments, the molar ratios of Mn, Ce and Zr to the total amount of base metals in the ternary mixed oxide catalyst are in the range of 0.25-0.35, 0.40-0.50 and 0.20-0.25, respectively. Further, this ternary mixed oxide catalyst is less susceptible to sulfur poisoning than previously-disclosed binary mixed oxide catalysts. The ternary mixed oxide catalyst may also be regenerated—and the inhibiting effect of SO2 reversed—by briefly exposing the catalyst to a reducing exhaust gas environment.
摘要:
A composition for hydrogen storage includes a source of hydrogen atoms, a receptor, and a chemical bridge formed between the source and the receptor. The chemical bridge is formed from a precursor material. The receptor is adapted to receive hydrogen spillover from the source.
摘要:
A system and method for reducing nitrous oxides in diesel exhaust with hydrogen and carbon monoxide over a palladium based catalyst. The catalyst comprises a compound represented by the formula: X % Pd—Y % V2O5/Z, where X is between about 0.1 to about 2.0, Y is between about 0.1 to about 7.0, and Z is an oxide support.
摘要:
A system and method for reducing nitrous oxides in diesel exhaust with hydrogen and carbon monoxide over a palladium based catalyst. The catalyst comprises a compound represented by the formula: X % Pd—Y % V2O5/Z, where X is between about 0.1 to about 2.0, Y is between about 0.1 to about 7.0, and Z is an oxide support.
摘要翻译:一种用于在钯基催化剂上用氢和一氧化碳还原柴油机废气中的一氧化二氮的系统和方法。 催化剂包含由下式表示的化合物:X%Pd-Y%V 2 O 5 / Z,其中X为约0.1至约2.0,Y为 约0.1至约7.0,Z是氧化物载体。
摘要:
A composition for hydrogen storage includes a source of hydrogen atoms, a receptor, and a chemical bridge formed between the source and the receptor. The chemical bridge is formed from a precursor material. The receptor is adapted to receive hydrogen spillover from the source.