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公开(公告)号：US4457874A
公开(公告)日：1984-07-03
申请号：US396698
申请日：1982-07-09
申请人： John G. Papalos , Arpad Savoly
发明人： John G. Papalos , Arpad Savoly
IPC分类号： B01F17/00 , B01F17/52 , C04B24/22 , C04B28/02 , C08G8/12 , C08G8/18 , C08G8/28 , C08G16/02 , C08L61/04 , C08L61/06 , C07C143/42
CPC分类号： C08G16/0237 , B01F17/0057 , C04B24/22 , C08G8/18
摘要： A dispersing agent which is(a) a condensation product of a substituted phenol sulfonic acid which is an arylphenol sulfonic acid or an aralkylphenol sulfonic acid with from about 0.5 to about 4 moles of formaldehyde per mole of substituted phenol sulfonic acid, or(b) a condensation product of (i) a substituted phenol sulfonic acid which is an arylphenol sulfonic acid or an aralkylphenol sulfonic acid and (ii) an aryl sulfonic acid with from about 0.5 to about 4 moles of formaldehyde per mole of substituted phenol sulfonic acid and aryl sulfonic acid wherein the weight ratio of substituted phenol sulfonic acid to aryl sulfonic acid is from about 0.95:0.05 to about 0.05:0.95.The dispersing agent may be used directly or reacted with a salt forming cation to obtain a salt. The condensation product is useful as a dispersing agent in hydraulic cement, mortar, concrete or the like.
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公开(公告)号：US4450262A
公开(公告)日：1984-05-22
申请号：US407270
申请日：1982-08-11
IPC分类号： C08F220/28 , G02B1/04 , C08F220/20 , C08F220/34
CPC分类号： C08F220/28 , G02B1/043
摘要： Novel hydrophilic copolymers are prepared containing a major portion of polymerized units of an hydroxyalkyl acrylate or methacrylate monomer and a minor portion of a nitro-substituted aryl acrylate or methacrylate monomer, and optionally with a minor amount of an alkylene glycol diacrylate or methacrylate as a cross-linking agent. These copolymers are made by a free radical polymerization mechanism or by gamma radiation of the reaction mixture. These copolymers are particularly useful as soft contact lens polymers, being extremely resistant to clouding and/or discoloration in use.
摘要翻译： 制备新的亲水共聚物，其包含主要部分的丙烯酸羟烷基酯或甲基丙烯酸羟烷基酯单体和少部分硝基取代的芳基丙烯酸酯或甲基丙烯酸酯单体的聚合单元，以及任选地与少量的二丙烯酸酯或甲基丙烯酸亚烷基二醇作为交叉 链接代理。 这些共聚物通过自由基聚合机理或通过反应混合物的γ辐射制备。 这些共聚物作为软性隐形眼镜聚合物是特别有用的，在使用中极易抵抗混浊和/或变色。
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公开(公告)号：US4441929A
公开(公告)日：1984-04-10
申请号：US411034
申请日：1982-08-24
CPC分类号： C04B28/04
摘要： Superplasticizers for cementitious compositions are produced from a raw material mixture of (1) naphthalenesulfonic acid formaldehyde condensate and (2) free sulfuric acid using a 1-step process or a 2-step process. In the 1-step process, the mixture is neutralized with a zinc compound such as zinc oxide to a pH of about 2 to obtain a superplasticizer mixture of the free acid of the naphthalenesulfonic acid formaldehyde condensate and zinc sulfate. In the 2-step process, the mixture is first neutralized with a zinc compound such as zinc oxide to a pH of about 2 and then with a base such as sodium hydroxide to a pH of about 6 to obtain a superplasticizer mixture of the sodium salt of the naphthalenesulfonic acid formaldehyde condensate and zinc sulfate. These superplasticizer mixtures are superior to a low salt content commercial sodium salt of a naphthalenesulfonic acid formaldehyde condensate where sodium sulfate content has been reduced by lime treatment.
摘要翻译： 用于水泥组合物的超增塑剂由（1）萘磺酸甲醛缩合物和（2）游离硫酸的原料混合物使用1步法或2步法制备。 在一步法中，将混合物用锌化合物如氧化锌中和至约2的pH，以获得萘磺酸甲醛缩合物的游离酸和硫酸锌的超增塑剂混合物。 在两步法中，首先用锌化合物如氧化锌将混合物中和至约2的pH，然后用碱如氢氧化钠中和至pH约6，得到钠盐的超增塑剂混合物 的萘磺酸甲醛缩合物和硫酸锌。 这些超增塑剂混合物优于通过石灰处理使硫酸钠含量降低的萘磺酸甲醛缩合物的低盐含量的商业钠盐。
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公开(公告)号：US5292965A
公开(公告)日：1994-03-08
申请号：US76563
申请日：1993-06-14
摘要： Radiation curable compositions containing outstanding reactive diluents have been developed. The diluents are lower alkyl ether acrylates and methacrylates of particular alkoxylated and non-alkoxylated polyols.Examples are mono-methoxy trimethylolpropane diacrylate, mono-methoxy neopentyl glycol monoacrylate and mono-methoxy, ethoxylated neopentyl glycol monoacrylate having an average of about two moles of ethylene oxide.
摘要翻译： 已经开发了含有突出的反应性稀释剂的可辐射固化组合物。 稀释剂是特定烷氧基化和非烷氧基化多元醇的低级烷基醚丙烯酸酯和甲基丙烯酸酯。 实例是单甲氧基三羟甲基丙烷二丙烯酸酯，单甲氧基新戊二醇单丙烯酸酯和具有平均约2摩尔环氧乙烷的单甲氧基乙氧基化新戊二醇单丙烯酸酯。
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公开(公告)号：US5159119A
公开(公告)日：1992-10-27
申请号：US696471
申请日：1991-05-06
摘要： Radiation curable compositions containing outstanding reactive diluents have been developed. The diluents are lower alkyl ether acrylates and methacrylates of particular alkoxylated and non-alkoxylated polyols.Examples are mono-methoxy trimethylolpropane diacrylate, mono-methoxy neopentyl glycol monoacrylate and mono-methoxy, ethoxylated neopentyl glycol monoacrylate having an average of about two moles of ethylene oxide.
摘要翻译： 已经开发了含有突出的反应性稀释剂的可辐射固化组合物。 稀释剂是特定烷氧基化和非烷氧基化多元醇的低级烷基醚丙烯酸酯和甲基丙烯酸酯。 实例是单甲氧基三羟甲基丙烷二丙烯酸酯，单甲氧基新戊二醇单丙烯酸酯和具有平均约2摩尔环氧乙烷的单甲氧基乙氧基化新戊二醇单丙烯酸酯。
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公开(公告)号：US4742105A
公开(公告)日：1988-05-03
申请号：US868149
申请日：1986-05-29
申请人： Edwin L. Kelley
发明人： Edwin L. Kelley
摘要： Binary mixtures of polyacrylates and sodium silicates are used as deflocculating agents for kaolin slurries to ensure pumpability and pourability of the slurry. An example of a binary mixture is a mixture of 67% by weight sodium polyacrylate having a weight average molecular weight of 4,200 and 33% by weight of sodium silicate on a dry solids basis.
摘要翻译： 聚丙烯酸酯和硅酸钠的二元混合物用作高岭土浆料的抗絮凝剂，以确保浆料的可泵送性和可倾倒性。 二元混合物的实例是以干固体为基础的67重量％的重均分子量为4200的聚丙烯酸钠和33重量％的硅酸钠的混合物。
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公开(公告)号：US4696981A
公开(公告)日：1987-09-29
申请号：US839353
申请日：1986-03-13
申请人： Kaoru Harada , Akira Shimoyama , Hiroji Mizumoto
发明人： Kaoru Harada , Akira Shimoyama , Hiroji Mizumoto
CPC分类号： C08G69/10 , Y10S526/922 , Y10S526/923
摘要： Homopolyamino acids and copolyamino acids are prepared by polycondensation of one kind or a mixture of two or more kinds of monoammonium, diammonium, monoamide, diamide or monoamideammonium salts of malic acid and/or maleic acid and/or fumaric acid, one kind or two or more kinds of amino acid being added to said raw materials, respectively, with application of microwaves, the resulting polyamino acids (imide type) being converted to peptide type, homopolyamino acids and copolyamino acids, respectively upon partial hydrolysis. The operation involved in the reaction is simple and the method permits the use of low cost reaction materials. As a result, imide type and also peptide type, homopolyamino and copolyamino acids are produced with uniform quality at a high rate of yield within an extremely short period of time. Accordingly, the method is incomparably superior to those which have been announced in the past.
摘要翻译： 共聚氨基酸和共聚氨基酸通过一种或两种以上的一种或两种以上的苹果酸和/或马来酸和/或富马酸的一种或两种或更多种单铵，二铵，一酰胺，二酰胺或单酰胺铵盐的混合来缩聚制备， 分别用微波加入到所述原料中的更多种类的氨基酸，所得到的聚氨基酸（酰亚胺型）分别转变为肽型，均聚氨基酸和共聚氨基酸。 反应中所涉及的操作简单，该方法允许使用低成本的反应材料。 结果，在非常短的时间内以高产率产生酰亚胺型和肽类型，均聚氨基和共聚氨基酸，质量均匀。 因此，该方法与以往已公布的方法无比优越。
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公开(公告)号：US4647384A
公开(公告)日：1987-03-03
申请号：US797212
申请日：1985-11-12
IPC分类号： C08F8/44 , C08F220/06 , C09K8/12 , C09K8/24 , C09K7/02
CPC分类号： C09K8/24 , C08F220/06 , C08F8/44 , C09K8/12
摘要： Copolymers of (1) from about 80% to about 98% by weight of acrylic acid and (2) from about 2% to about 20% by weight of itaconic acid and having a weight average molecular weight of between about 50,000 to about 1,000,000, preferably between about 100,000 to about 500,000, and which are at least water dispersible, are used as fluid loss control additives for aqueous drilling fluids and are particularly advantageous when used with muds containing soluble calcium and muds containing chloride ions such as seawater muds. An example is a copolymer of 95% by weight acrylic acid and 5% by weight itaconic acid in its sodium salt form.
摘要翻译： （1）约80％至约98％重量的丙烯酸和（2）约2％至约20％重量的衣康酸的共聚物，其重均分子量为约50,000至约1,000,000， 优选约100,000至约500,000，并且至少是水可分散的，用作水性钻井液的流体损失控制添加剂，并且当与含有可溶性钙和含有氯离子的泥浆（例如海水泥浆）一起使用时是特别有利的。 一个例子是95％（重量）的丙烯酸和5％（重量）的其钠盐形式的衣康酸的共聚物。
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公开(公告)号：US4634451A
公开(公告)日：1987-01-06
申请号：US732745
申请日：1985-05-10
IPC分类号： C10L1/32
CPC分类号： C10L1/326 , Y10S516/03
摘要： Aqueous carbonaceous mixtures such as water slurries of solid particulate carbonaceous materials having reduced viscosity, a stabilized network of carbonaceous materials in water and improved pumpability are obtained by using a condensation product of an aldehyde in aldehyde liberating composition, ketone and sulfur dioxide in a sulfur dioxide liberating composition as dispersant, the dispersant being present in an amount sufficient to reduce viscosity of the slurry, stabilize the network of carbonaceous materials in water and improve pumpability. An improved process for the condensation product is disclosed.
摘要翻译： 通过使用醛释放组合物中的醛与二氧化硫中的酮和二氧化硫的缩合产物，可以获得水性碳质混合物，例如具有降低粘度的固体颗粒状碳质材料的水浆料，水中含碳材料的稳定网络和改进的可泵送性 释放组合物作为分散剂，分散剂以足以降低浆料粘度的量存在，稳定碳质材料在水中的网络并提高泵送性。 公开了缩合产物的改进方法。
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公开(公告)号：US4622373A
公开(公告)日：1986-11-11
申请号：US608864
申请日：1984-05-10
IPC分类号： C08F220/06 , C09K8/12 , C09K8/24 , C08F228/02
CPC分类号： C08F220/06 , C09K8/12 , C09K8/24
摘要： Polymers of (1) from about 5% to about 50% by weight of 2-acrylamido-2-methylpropane sulfonic acid and (2) from about 95% to about 50% by weight of a second component, there being from 100% to about 80% by weight acrylic acid and from 0% to about 20% by weight of itaconic acid in the second component and having a weight average molecular weight of between about 50,000 to about 1,000,000 and which are at least water dispersible are used as fluid loss control additives for aqueous drilling fluids and are particularly advantageous when used with muds containing soluble calcium ions and muds containing chloride ions such as seawater muds. An example is a copolymer of 10% by weight 2-acrylamido-2-methylpropane sulfonic acid and 90% by weight acrylic acid in its sodium salt form.
摘要翻译： （1）约5重量％至约50重量％的2-丙烯酰胺基-2-甲基丙磺酸的聚合物和（2）约95重量％至约50重量％的第二组分，其中100重量％至 在第二组分中约80重量％的丙烯酸和0重量％至约20重量％的衣康酸，其重均分子量在约50,000至约1,000,000之间并且至少是水可分散的，用作流体损失 用于含水钻井液的控制添加剂，并且当与含有可溶性钙离子的泥浆和含有氯离子的泥浆（例如海水泥浆）一起使用时是特别有利的。 一个例子是其钠盐形式的10重量％的2-丙烯酰胺基-2-甲基丙磺酸和90重量％的丙烯酸的共聚物。
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