Removal of acidic halides from gas streams
    31.
    发明授权
    Removal of acidic halides from gas streams 失效
    从气流中去除酸性卤化物

    公开(公告)号:US5601702A

    公开(公告)日:1997-02-11

    申请号:US367498

    申请日:1994-12-30

    Applicant: Tsoung Y. Yan

    Inventor: Tsoung Y. Yan

    CPC classification number: C10G19/073 B01D53/68 B01D53/685 Y10S210/902

    Abstract: Acidic halides, especially chlorides, are removed from gas by contact with particles of solid caustic covered by aqueous and hydrocarbon phases, respectively. Effective neutralization is achieved without swelling or plugging the bed of solid caustic. Halides are removed as brine. Efficient caustic utilization is achieved by controlling water vapor levels in the gas based on pH of brine product.

    Abstract translation: 酸性卤化物,特别是氯化物,分别通过与水相和烃相覆盖的固体苛性碱颗粒接触而从气体中除去。 实现有效的中和,而不会膨胀或堵塞固体苛性碱床。 卤化物作为盐水除去。 通过根据盐水产品的pH控制气体中的水汽含量来实现苛性碱的利用。

    Two phase removal of halides from liquid hydrocarbons cross-reference to
related applications
    39.
    发明授权
    Two phase removal of halides from liquid hydrocarbons cross-reference to related applications 失效
    液相碳氢化合物的两相脱除相互参照相关应用

    公开(公告)号:US5595648A

    公开(公告)日:1997-01-21

    申请号:US367501

    申请日:1994-12-30

    Applicant: Tsoung Y. Yan

    Inventor: Tsoung Y. Yan

    CPC classification number: C10G19/073

    Abstract: Acidic halides, especially chlorides, are removed from dry liquid hydrocarbon streams such as catalytic reformate by contact with large particles of low surface area solid caustic such as a bed of NaOH pellets. Effective neutralization is achieved in a bed which is essentially free of any aqueous phase. Salt formed by the neutralization reaction deposit as solids on the surface of the solid caustic. A process for producing a low chloride, dry reformate product is also disclosed.

    Abstract translation: 通过与大颗粒的低表面积固体苛性碱如NaOH颗粒床接触,将酸性卤化物,特别是氯化物从干燥液体烃流中除去,例如催化重整产物。 在基本上不含任何水相的床中实现有效的中和。 通过中和反应形成的盐作为固体沉积在固体苛性碱的表面上。 还公开了一种生产低氯化物,干重整产品的方法。

    Converting calcium sulphide to calcium oxide
    40.
    发明授权
    Converting calcium sulphide to calcium oxide 失效
    将硫化钙转化为氧化钙

    公开(公告)号:US4216197A

    公开(公告)日:1980-08-05

    申请号:US953147

    申请日:1978-10-17

    Applicant: Gerald Moss

    Inventor: Gerald Moss

    CPC classification number: C01F11/10 C10G11/18 C10G19/073

    Abstract: CaS is converted to CaO with increased production of SO.sub.2 and decreased production of CaSO.sub.4 by passing CaS-containing particles into one region of a conversion bed wherein they are fluidized at an elevated temperature by an upwardly-passing oxygen-containing fluidizing gas, removing particles of increased CaO content from a second region of the bed, and providing a reducing agent (e.g. a hydrocarbon gas, liquid or carbonaceous solid) in the bed between the first and second regions, preferably nearer the latter, to produce a mildly reducing atmosphere which reduces any CaSO.sub.4 and increases the yield of SO.sub.2. The removed particles may be circulated to a fluidized gasification bed wherein a sulphur-containing fuel is converted to substantially sulphur-free fuel gas and wherein the sulphur is fixed as CaS in the particles, which particles are thereafter recirculated to the conversion bed.

    Abstract translation: 通过使含CaS的颗粒通过转化床的一个区域,其中它们通过向上流过的含氧流化气体在高温下流化,CaS转化为具有增加的SO 2产生量并减少CaSO 4的产生的CaO,并除去 从床的第二区域增加CaO含量,并且在第一和第二区域之间的床中提供还原剂(例如烃气体,液体或碳质固体),优选更靠近后者,以产生温和还原气氛,其减少 任何CaSO 4并提高SO2的产率。 除去的颗粒可以循环到流化气化床,其中含硫燃料转化为基本上不含硫的燃料气体,其中硫作为CaS固定在颗粒中,然后将颗粒再循环到转化床中。

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