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    Fuel cell membrane
    35.
    发明授权
    Fuel cell membrane 有权
    燃料电池膜

    公开(公告)号：US09099711B2

    公开(公告)日：2015-08-04

    申请号：US14023466

    申请日：2013-09-11

    Applicant: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS

    Inventor： Nedal Y. Abu-Thabit ,  Sayed Mohammed Javaid Zaidi ,  Shaikh Asrof Ali ,  Khaled Mezghani

    IPC: H01M8/10 ,  H01M8/02

    CPC classification number: H01M8/1044 ,  H01M8/0221 ,  H01M8/0289 ,  H01M8/1018 ,  H01M8/1025 ,  H01M8/1034 ,  H01M8/1069 ,  H01M8/1081 ,  H01M8/1086 ,  H01M8/109 ,  H01M2008/1095 ,  H01M2300/0082 ,  H01M2300/0091 ,  Y02P70/56

    Abstract: The fuel cell membrane is a polymer electrolyte (or polyelectrolyte) membrane formed from a blend of sulfonated poly(ether ether ketone) (SPEEK) and phosphonated polysulfone in the ester form (PPSU-E), where the sulfonated poly(ether ether ketone) and the phosphonated polysulfone each form about 50 wt % of the polyelectrolyte membrane. The polyelectrolyte membrane is made by dissolving a mixture of SPEEK and PPSU in the ester form (PPSU-E) in dimethylacetamide (DMAc) at room temperature to form a solution. The SPEEK/PPSU-E mixture has a concentration of between about 10 wt % and about 15 wt % in the solution. The solution is then stirred and left to release air bubbles therefrom. The DMAc is then evaporated from the solution, leaving the resultant polyelectrolyte membrane, which is then washed and dried.

    Abstract translation: 燃料电池膜是由磺化聚（醚醚酮）（SPEEK）和酯形式（PPSU-E）的膦酸化聚砜的共混物形成的聚合物电解质（或聚电解质）膜，其中磺化的聚（醚醚酮） 并且膦酸化聚砜各自形成约50重量％的聚电解质膜。 聚电解质膜是通过在室温下将SPEEK和PPSU的混合物在二甲基乙酰胺（DMAc）中溶解在酯形式（PPSU-E）中形成的。 SPEEK / PPSU-E混合物在溶液中的浓度为约10重量％至约15重量％。 然后将溶液搅拌并留下以从其中释放气泡。 然后从溶液中蒸发DMAc，留下所得的聚电解质膜，然后将其洗涤并干燥。

    Reinforced composite electrolyte membrane for fuel cell
    36.
    发明授权
    Reinforced composite electrolyte membrane for fuel cell 有权
    燃料电池用强化复合电解质膜

    公开(公告)号：US09054357B2

    公开(公告)日：2015-06-09

    申请号：US11729931

    申请日：2007-03-30

    Applicant: Eun Ju Kim ,  Chong Kyu Shin ,  Bong Keun Lee ,  Seong Ho Choi

    Inventor： Eun Ju Kim ,  Chong Kyu Shin ,  Bong Keun Lee ,  Seong Ho Choi

    IPC: H01M6/18 ,  H01M8/10 ,  H01M8/04

    CPC classification number: H01M8/1053 ,  H01M8/04197 ,  H01M8/1007 ,  H01M8/1023 ,  H01M8/1025 ,  H01M8/1027 ,  H01M8/103 ,  H01M8/1032 ,  H01M8/1034 ,  H01M8/1039 ,  H01M8/1058 ,  H01M8/106 ,  H01M8/1062 ,  H01M8/1067 ,  H01M8/1081 ,  H01M2300/0082 ,  H01M2300/0088 ,  H01M2300/0094 ,  Y02E60/521 ,  Y02P70/56

    Abstract: Disclosed is a composite electrolyte membrane comprising a microporous polymer substrate and a sulfonated polymer electrolyte. The composite electrolyte membrane comprises: a first polymer electrolyte layer formed of a first non-fluorinated or partially-fluorinated sulfonated polymer electrolyte; a non-fluorinated or partially-fluorinated microporous polymer substrate stacked on the first polymer electrolyte layer, wherein pores of the microporous polymer substrate are impregnated with a second non-fluorinated or partially-fluorinated sulfonated polymer electrolyte, and the first polymer electrolyte and the second polymer electrolyte are entangled with each other on an interface thereof; and a third polymer electrolyte layer formed on the microporous polymer substrate impregnated with the second polymer electrolyte by a third non-fluorinated or partially-fluorinated sulfonated polymer electrolyte, wherein the second polymer electrolyte and the third polymer electrolyte are entangled with each other on an interface thereof. A method for manufacturing the composite electrolyte membrane, and a membrane-electrode assembly (MEA) and a fuel cell comprising the composite electrolyte membrane are also disclosed.

    Abstract translation: 公开了包含微孔聚合物基材和磺化聚合物电解质的复合电解质膜。 复合电解质膜包括：由第一非氟化或部分氟化的磺化聚合物电解质形成的第一聚合物电解质层; 堆叠在第一聚合物电解质层上的非氟化或部分氟化的微孔聚合物基材，其中微孔聚合物基材的孔用第二非氟化或部分氟化的磺化聚合物电解质浸渍，并且第一聚合物电解质和第二聚合物电解质 聚合物电解质在其界面上彼此缠结; 以及第三聚合物电解质层，其通过第三非氟化或部分氟化的磺化聚合物电解质在所述第二聚合物电解质浸渍的所述微孔聚合物基材上形成，其中所述第二聚合物电解质和所述第三聚合物电解质在界面上彼此缠结 其中。 还公开了复合电解质膜的制造方法以及膜电极组件（MEA）和包含该复合电解质膜的燃料电池。

    Proton exchange membrane for fuel cell
    37.
    发明授权
    Proton exchange membrane for fuel cell 失效
    用于燃料电池的质子交换膜

    公开(公告)号：US08741454B2

    公开(公告)日：2014-06-03

    申请号：US11770249

    申请日：2007-06-28

    Applicant: John Muldoon ,  Ryszard J. Wycisk ,  Peter N. Pintauro

    Inventor： John Muldoon ,  Ryszard J. Wycisk ,  Peter N. Pintauro

    IPC: H01M4/86

    CPC classification number: H01M8/1034 ,  B01D71/72 ,  B01D71/82 ,  C08J5/2256 ,  C08J2379/06 ,  H01M8/1067 ,  H01M2300/0082

    Abstract: A proton exchange membrane (PEM) with an ion exchange capacity of not less than 1 molar equivalent per kilogram and less than 20% water swelling is provided. The PEM includes a polymer having a polyphosphazene backbone with a polyaromatic functional group linked to the polyphosphazene as a polyaromatic side chain, a non-polyaromatic functional group linked to the polyphosphazene as a non-polyaromatic side chain, and an acidic functional group linked to the non-polyaromatic side chain. The polyaromatic functional group linked to the polyphosphazene provides for increased thermal and chemical stability, excellent ionic conductivities and low water swelling. The mole fraction of polyaromatic functional groups linked to the polyphosphazene backbone is between 0.05 and 0.60.

    Abstract translation: 提供离子交换容量不小于1摩尔当量/千克且小于20％的水溶胀的质子交换膜（PEM）。 PEM包括具有聚磷腈主链的聚合物，其具有与作为聚芳基侧链的聚磷腈连接的多芳族官能团，与作为非多芳族侧链的聚磷腈连接的非多芳族官能团和与 非多芳族侧链。 与聚磷腈连接的多芳基官能团提供了增加的热和化学稳定性，优异的离子电导率和低的水溶胀。 与聚磷腈骨架连接的多芳族官能团的摩尔分数为0.05-0.60。

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