OXIDATIVE DEHYDROGENATION OF ETHANE USING CARBON DIOXIDE

    公开(公告)号:US20200247733A1

    公开(公告)日:2020-08-06

    申请号:US16857676

    申请日:2020-04-24

    Abstract: The present disclosure relates to methods and systems suitable for chemical production by dehydrogenation of ethane utilizing carbon dioxide as a soft oxidant. Ethane and carbon dioxide are reacted in a catalytic reactor to produce a reaction product stream comprising at least ethylene and carbon dioxide. The carbon dioxide can be separated for recycling back into the catalytic reactor, and the ethylene can be upgraded using a variety of process units. Heat from the reaction product stream can be recycle for further uses, including reducing the amount of added heating needed in the catalytic reactor. Additional materials, such carbon monoxide, hydrogen, syngas, methanol, methane, ethane, and even heavier hydrocarbons can be provided.

    Apparatus for producing water-absorbing resin particles

    公开(公告)号:US10730028B2

    公开(公告)日:2020-08-04

    申请号:US16088653

    申请日:2017-02-16

    Abstract: An apparatus for producing water-absorbing resin particles for which surface cross-linking treatment is conducted by spraying a surface cross-linking agent to a water-absorbing resin particle precursor and heating the agent and the precursor, the apparatus includes a treatment container in which the surface cross-linking treatment is conducted, a stirring device including a stirring member disposed in the treatment container, a heating device that heats an inside of the treatment container; and a spray nozzle disposed in the treatment container, the spray nozzle spraying into the treatment container the surface cross-linking agent supplied from a surface cross-linking agent supply source in an exterior of the treatment container through a supply pipe. In a flow path in the spray nozzle spanning from an entrance of the spray nozzle to a spray exit, a point whose opening cross-section is smallest in a flow path through which a fluid passes is the spray exit.

    Oxidative dehydrogenation of ethane using carbon dioxide

    公开(公告)号:US10662127B2

    公开(公告)日:2020-05-26

    申请号:US16113772

    申请日:2018-08-27

    Abstract: The present disclosure relates to methods and systems suitable for chemical production by dehydrogenation of ethane utilizing carbon dioxide as a soft oxidant. Ethane and carbon dioxide are reacted in a catalytic reactor to produce a reaction product stream comprising at least ethylene and carbon dioxide. The carbon dioxide can be separated for recycling back into the catalytic reactor, and the ethylene can be upgraded using a variety of process units. Heat from the reaction product stream can be recycle for further uses, including reducing the amount of added heating needed in the catalytic reactor. Additional materials, such carbon monoxide, hydrogen, syngas, methanol, methane, ethane, and even heavier hydrocarbons can be provided.

    Recovering bromine from solid waste containing bromine compounds, and applications thereof

    公开(公告)号:US10654720B2

    公开(公告)日:2020-05-19

    申请号:US15551700

    申请日:2016-02-18

    Abstract: Recovering bromine from solid waste containing bromine compounds, and applications thereof, such as for recovering bromine in a form suitable for reuse, or for manufacturing bromine salt (for example, calcium bromide). Bromine recovery method and system include: providing and mixing (i) solid waste containing bromine compounds and (ii) solid calcium hydroxide; heating the mixture in a chemical reducing (non-oxidizing) environment, thereby forming heated product consisting essentially of only solid calcium bromide (salt); and processing the heated product, to form bromine. Calcium bromide manufacturing method and system include: providing and mixing (i) solid waste containing bromine compounds and (ii) solid calcium hydroxide; heating the mixture in a chemical reducing (non-oxidizing) environment, thereby forming solid calcium bromide (salt). Applicable to processes of, or involving, manufacturing bromine-based flame (fire) retardant materials.

    Shear retort for ablative pyrolysis

    公开(公告)号:US10604704B2

    公开(公告)日:2020-03-31

    申请号:US15972657

    申请日:2018-05-07

    Applicant: VORSANA INC

    Abstract: A shear retort mill for slow ablative pyrolysis features friction heating between shearing surfaces on a rotating disk and a static or rotating cylindrical drum enclosing the disk. A feed enters the workspace between the rotating disk and the bottom of the drum through a hollow feed shaft coupled to the rotating disk. Preferably, an auger compacts and moves the feed downward, and a shredder reduces the feed's particle size. The feed is increasingly ground and pyrolyzed as it is forced between the drum and disk shearing surface. As the dense processed material extrudes at the edge of the workspace, the gases and liquid products are forced inward by the barrier of dense solids. A static exhaust pipe at the center of the rotating feed shaft allows for the exit of these gases, which preferably go to a heat exchanger to recover any condensable fractions.

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