公开(公告)号：US20110160473A1

公开(公告)日：2011-06-30

申请号：US12917892

申请日：2010-11-02

申请人： Jifu Bi ,  Xuequan Zhang ,  Liansheng Jiang ,  Hongguang Cai ,  Bei Wang ,  Chunyu Zhang ,  Lihua Na ,  Quanquan Dai ,  Changliang Fan

发明人： Jifu Bi ,  Xuequan Zhang ,  Liansheng Jiang ,  Hongguang Cai ,  Bei Wang ,  Chunyu Zhang ,  Lihua Na ,  Quanquan Dai ,  Changliang Fan

IPC分类号： C07F19/00

CPC分类号： C07F9/6571 ,  C07F9/11 ,  C08F36/04 ,  C08F4/545

摘要： The invention provides a method for producing soluble neodymium chloride complex using neodymium chloride aqueous solution as raw material, thereby avoiding the use of anhydrous neodymium chloride, simplifying the synthesis process and reducing the cost for synthesizing neodymium chloride complex. The neodymium chloride complex produced by this method is soluble not only in polar solvent, but also in nonpolar solvent. Such neodymium chloride complex also has good dissolvability in aliphatic hydrocarbon solvent which has relatively weaker solution power, and even in aliphatic hydrocarbon solvent with 6 or less carbon atoms which has even lower solution power. Since neodymium chloride complex is soluble in aliphatic hydrocarbon solvent, its transportation may be conducted, which is convenient for industrial application and contributes to improve the utilization efficiency of rare earth.

摘要翻译： 本发明提供了一种使用氯化钕水溶液作为原料生产可溶性氯化钕络合物的方法，从而避免使用无水氯化钕，简化合成过程并降低合成氯化钕络合物的成本。 通过该方法制备的氯化钕络合物不仅可溶于极性溶剂，而且可溶于非极性溶剂中。 这种氯化钕络合物在溶解力相对较弱的脂族烃溶剂中也具有良好的溶解性，甚至在具有6个或更少碳原子的脂族烃溶剂中具有更低的溶液功率。 由于氯化钕络合物可溶于脂族烃溶剂，因此可以进行运输，这对于工业应用是方便的，有助于提高稀土的利用效率。

公开(公告)号：US20090263271A1

公开(公告)日：2009-10-22

申请号：US12105165

申请日：2008-04-17

申请人： Jian Meng ,  Daqing Fang ,  Deping Zhang ,  Dingxiang Tang ,  Huayi Lu ,  Lianshan Zhao ,  Wei Sun ,  Xin Qiu ,  Hongjie Zhang

发明人： Jian Meng ,  Daqing Fang ,  Deping Zhang ,  Dingxiang Tang ,  Huayi Lu ,  Lianshan Zhao ,  Wei Sun ,  Xin Qiu ,  Hongjie Zhang

IPC分类号： C22C23/00

CPC分类号： C22C23/04 ,  C22F1/06

摘要： A high-strength, high-toughness, weldable and deformable rare earth magnesium alloy comprised of 0.7˜1.7% of Ym, 5.5˜6.4% of Zn, 0.45˜0.8% of Zr, 0.02% or less of the total amount of impurity elements of Si, Fe, Cu and Ni, and the remainder of Mg, based on the total weight of the alloy. During smelting, Y, Ho, Er, Gd and Zr are added in a manner of Mg—Y-rich, Mg—Zr intermediate alloys into a magnesium melt; Zn is added in a manner of pure Zn, and at 690˜720° C., a round bar was cast by a semi-continuous casting or a water cooled mould, then an extrusion molding was performed at 380˜410° C. after cutting. Before the extrusion, the alloy is treated by the solid-solution treatment at 480˜510° C. for 2˜3 hours, however, the alloy can also be extrusion molded directly without the solid-solution treatment. After the extrusion molding, this alloy has a strength of 340 MPa or more and a percentage elongation of 14% or more at room temperature and is a high-strength, high-toughness, weldable and deformable rare earth magnesium alloy.

摘要翻译： 高强度，高韧性，可焊接和可变形的稀土镁合金由Ym的0.7〜1.7％，Zn的5.5〜6.4％，Zr的0.45〜0.8％，杂质元素的总量的0.02％以下 的Si，Fe，Cu和Ni，剩余的Mg基于合金的总重量。 在熔炼过程中，以Mg-Y，Mg-Zr中间合金的方式将Y，Ho，Er，Gd和Zr加入到镁熔体中; 以纯Zn的方式添加Zn，在690〜720℃下，通过半连续浇铸或水冷模具浇铸圆棒，然后在380〜410℃下进行挤出成型 切割。 在挤出前，合金经480〜510℃的固溶处理2〜3小时，然而，该合金也可直接挤出成型，无需固溶处理。 挤出成型后，该合金的室温下的强度为340MPa以上，伸长率为14％以上，为高强度，高韧性，可焊接且可变形的稀土类镁合金。

公开(公告)号：US20050282795A1

公开(公告)日：2005-12-22

申请号：US11148738

申请日：2005-06-09

申请人： Xiaogang Qu ,  Guoqiang Shangguan

发明人： Xiaogang Qu ,  Guoqiang Shangguan

IPC分类号： A61K31/555 ,  C07F7/30

CPC分类号： C07F7/30

摘要： The present invention relates to compounds of quinolyl organic germanium ester having the following Formula 1 and the synthesis methods thereof. R1 and R2 are defined in the specification. Organic germanium acyl chloride and 8-hydroxylquinoline were used as the starting raw materials. Displacement reaction was carried out at 0-40° C., followed by hydrolysis reaction and then by changing the solvent, water soluble quinolyl organic germanium ester was finally obtained. The quinolyl organic germanium ester possesses better water solubility and fat solubility. Due to the existence of both drug active group (organic germanium part) and drug recognizing group (quinoline part) in the structure of the quinolyl organic germanium ester, the compound is expected to develop a novel kind of anti-tumor drug.

摘要翻译： 本发明涉及具有下式1的喹啉基有机锗酯及其合成方法。 在本说明书中定义了R 1和R 2。 使用有机锗酰氯和8-羟基喹啉作为起始原料。 在0-40℃进行位移反应，然后水解反应，然后通过改变溶剂，最终得到水溶性喹啉基有机锗酯。 喹啉有机锗酯具有更好的水溶性和脂溶性。 由于药物活性基团（有机锗部分）和药物识别组（喹啉部分）在喹啉有机锗酯结构中的存在，预计该化合物将开发出一种新型的抗肿瘤药物。

公开(公告)号：US6158681A

公开(公告)日：2000-12-12

申请号：US112598

申请日：1998-07-09

申请人： Guanzhi Chen ,  Hongjian Ji ,  Xin Zhang

发明人： Guanzhi Chen ,  Hongjian Ji ,  Xin Zhang

IPC分类号： B29B9/06 ,  B02C19/12

CPC分类号： B29B9/06 ,  B29K2033/26

摘要： A low shearing curved surface granulator for bulk feed consists of a feeding mechanism and a granulating mechanism; wherein the mainbody of the feeding mechanism is a cylindrical body, the main part of the granulating mechanism is a groove pipe with flanges on both its ends, the groove pipe is longitudinally mounted on the cylindrical body, and the granulator is provided with a ball comber board and a ball scraper. A sector plate is mounted parallel to the cylindrical body on the inner cavity baseplane of the cylindrical body in the feeding mechanism; a driving wheel is set up under the sector plate; a sliding pin is fastened in the driving wheel; the sliding pin fits in with a slide way opened on the sector plate, which slides up and down in the slide way following rotating of the driving wheel, and the sector plate is made to swing repeatedly around the pin in the cylindrical body. The granulator performs massive feeding in one time, can greatly reduce labor. The granulator of the present invention provides for granulation of large quantities of material in a single feeding. This greatly reduces labor and increases granulation efficiency.

摘要翻译： 用于大量进料的低剪切曲面制粒机由进料机构和造粒机构组成; 其特征在于，所述供给机构的主体为圆柱体，所述造粒机构的主要部分为两端具有凸缘的槽管，所述槽管纵向安装在所述圆筒体上，所述造粒机设有球形精梳机 板和球刮刀。 扇形板平行于圆筒体安装在进料机构中的圆柱体的内腔基座上; 在扇形板下设置驱动轮; 滑动销紧固在驱动轮中; 滑动销以扇形板上的滑动方式安装，在滑动方向上滑动方式在驱动轮旋转之后上下滑动，并使扇形板围绕圆柱体中的销重复摆动。 造粒机一次性进行大量喂养，可大大减少劳动力。 本发明的造粒机在单次进料中提供大量物料的造粒。 这大大降低了劳动力并增加了造粒效率。

公开(公告)号：US20230002554A1

公开(公告)日：2023-01-05

申请号：US17619402

申请日：2020-06-29

申请人： Changchun Institute of Applied Chemistry Chinese Academy of Sciences

发明人： Chaoliang HE ,  Zhen ZHANG ,  Hui REN ,  Xuesi CHEN

IPC分类号： C08G65/333 ,  C08J3/075

摘要： The present invention provides a polyethylene glycol derivative comprising a repeat unit having the structure of Formula (I) and a terminal group having the structure of Formula (II). The polyethylene glycol derivative provided by the present invention has good biocompatibility, due to the repeat unit having the structure of Formula (I); and can react with various groups such as amino, (acyl)hydrazino, and aminooxy with a fast reaction rate under mild reaction conditions, due to the o-phthalaldehyde terminal group having the structure of Formula (II). The polyethylene glycol derivative provided by the present invention is mixed with polyethylene glycol having an amino-containing terminal group in an aqueous medium, to rapidly form a chemically cross-linked hydrogel material. The hydrogel material has mild preparation conditions, fast gel-forming speed, high mechanical strength, and good stability. This polyethylene glycol hydrogel can be applied as drug sustained-release carrier, tissue engineering scaffold, etc. in the field of biomedical materials.

公开(公告)号：US20220205065A1

公开(公告)日：2022-06-30

申请号：US17601887

申请日：2019-10-10

申请人： CHANGCHUN INSTITUTE OF APPLIED CHEMISTRY CHINESE ACADEMY OF SCIENCES

发明人： Ji CHEN ,  Yuefeng DENG ,  Deqian LI ,  Hailian LI ,  Maohua YANG ,  Yu LIU ,  Dan ZOU ,  Yan BAI ,  Yongqing CHANG

IPC分类号： C22B59/00 ,  C22B3/40 ,  C01F17/218 ,  C01F17/229

摘要： The present disclosure relates to a method for separating yttrium oxide from a high-yttrium rare earth ore by a grouping manner and a method for separating yttrium oxide from a medium-yttrium and europium-rich rare earth ore by a grouping manner, and belongs to the technical field of rare earth extraction and separation. The separating method by a grouping manner according to the present disclosure have advantages such as being advanced and reasonable, short process, low production cost, good adaptability, and easy operation and control. The method has better overall technical and economic indicator performance than the naphthenic acid process and has the value of practical application.

公开(公告)号：US11111561B2

公开(公告)日：2021-09-07

申请号：US16108688

申请日：2018-08-22

申请人： Changchun Institute of Applied Chemistry Chinese Academy of Sciences

发明人： Weilin Xu ,  Fa Yang ,  Mingbo Ruan ,  Yuwei Zhang ,  Ping Song

IPC分类号： C22C12/00 ,  B82Y30/00 ,  B82Y40/00 ,  C25B3/25

摘要： The present disclosure relates to a preparation method and use of a thickness-controllable bismuth nanosheet and its alloy, in order to solve the technical problems that the existing metal catalysts for the conversion of carbon dioxide to formic acid exhibit a low efficiency, a high overpotential, a relatively positive hydrogen evolution potential, and a poor stability. In the present disclosure, a bismuth nanosheet of a single atom layer thickness with a thickness of only 0.7 nm is obtained through an aqueous solution reduction method by using a bismuth salt compound as a raw material, using ethylene glycol ethyl ether as a solvent, and using a highly reductive aqueous solution containing NaBH4, LiBH4 or the like as a reducing agent, under a protection atmosphere of an inert gas.

公开(公告)号：US10700294B2

公开(公告)日：2020-06-30

申请号：US15522635

申请日：2014-11-20

申请人： Changchun Institute of Applied Chemistry Chinese Academy of Sciences

发明人： Liang Zhou ,  Hongjie Zhang ,  Yunlong Jiang

IPC分类号： H01L51/00 ,  C09K11/06 ,  H01L51/56 ,  H01L51/52 ,  H01L51/50

摘要： The invention provides a blue organic electroluminescent device, composed of a substrate, an anode layer, an anode modification layer, a hole transporting-electron blocking layer, a hole-dominated light-emitting layer, an electron-dominated light-emitting layer, a hole blocking-electron transporting layer, a cathode modification layer, and a cathode layer arranged in turn, wherein the electron-dominated light-emitting layer is composed of an organic sensitive material, a blue organic light-emitting material, and an electron-type organic host material. A rare earth complex having a matched energy level, such as Tm(acac)3phen or Dy(acac)3phen is selected as the organic sensitive material, and a trace amount of the same is doped into the electron-dominated light-emitting layer, which has the function of an energy transporting ladder and a deep binding center for charge carriers, so as to improve the luminescence efficiency, spectral stability, and service life of the device, reduce the operating voltage of the device, and delay the attenuation of the effectiveness of the device.

公开(公告)号：US10683380B2

公开(公告)日：2020-06-16

申请号：US16362992

申请日：2019-03-25

申请人： Changchun Institute of Applied Chemistry Chinese Academy of Sciences

发明人： Chunji Wu ,  Bo Liu ,  Dongmei Cui

IPC分类号： C08F236/06 ,  B60C1/00 ,  C08F4/54

摘要： A copolymer of ethylene and a conjugated diene is provided, in which ethylene content in the copolymer is greater than 20 mol %, the copolymer has a glass transition temperature between −110° C. and −90° C., and continuous methylene sequence lengths (MSL) in the copolymer are in a range of 12-162 methylene units. A method for producing the copolymer, comprising copolymerizing ethylene and a conjugated diene in the presence of a catalyst system to obtain the copolymer is also provided, in which the catalyst system comprises a heterocyclic-fused cyclopentadienyl rare-earth metal complex, an organoboron salt compound and an organoaluminum compound, wherein the heterocyclic-fused cyclopentadienyl rare-earth metal complex is represented by the structural formula:

公开(公告)号：US10246536B2

公开(公告)日：2019-04-02

申请号：US15501737

申请日：2015-08-13

申请人： Changchun Institute of Applied Chemistry Chinese Academy of Sciences

发明人： Dongmei Cui ,  Dongtao Liu ,  Zichuan Wang

IPC分类号： C08F4/52 ,  C08F212/08 ,  C08F212/14 ,  C08F4/54 ,  C08F2/02 ,  C08F2/06 ,  C08F4/12 ,  C08L25/06 ,  C08L25/16 ,  C08F12/22 ,  C08F12/30 ,  C08F112/14

摘要： Compared to the prior art, this invention provides a functionalized highly syndiotactic polystyrene, comprising a repeating unit having a structure represented by formula (I), or comprising a repeating unit having a structure represented by formula (I) and a repeating unit having a structure represented by formula (II). It is indicated by the experimental results that the syndiotacticity selectivity of the highly syndiotactic polymer provided by this invention is no less than 90%, and the proportion of the repeating unit having a structure represented by formula (I) in the polymer may be arbitrarily adjusted and may be up to 100%. Meanwhile, the oxygen- or sulfur-containing groups in the polymer may increase the polarity of the highly syndiotactic polystyrene so as to increase the blendability of the highly syndiotactic polystyrene with other polymers.