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41.发明授权Membrane-based gas separation processes to separate dehydrogenation reaction products 有权基于膜的气体分离方法分离脱氢反应产物公开(公告)号：US09517981B2
公开(公告)日：2016-12-13
申请号：US14099267
申请日：2013-12-06
申请人： Nicholas P. Wynn , Alvin Ng , Douglas Gottschlich , Paul Su , Meijuan Zhou , Sylvie Thomas-Droz
发明人： Nicholas P. Wynn , Alvin Ng , Douglas Gottschlich , Paul Su , Meijuan Zhou , Sylvie Thomas-Droz
CPC分类号： C07C7/005 , B01D53/002 , B01D53/22 , B01D53/226 , C01B3/501 , C01B2203/0266 , C01B2203/041 , C01B2203/043 , C01B2203/147 , C01B2203/148 , C07C7/144 , F25J3/0271 , F25J2205/80 , F25J2270/90 , C07C11/06 , C07C11/09
摘要： Gas separation processes are provided for separating dehydrogenation reaction products from a raw gas stream to recover hydrocarbons, specifically olefins, such as propylene and iso-butene, as well as unreacted feedstock. The processes employ a sequence of partial condensation steps, interspersed with membrane separation steps to raise the hydrocarbon dewpoint of the uncondensed gas, thereby avoiding the use of low-temperature or cryogenic conditions.
摘要翻译： 提供气体分离方法用于从原始气流中分离脱氢反应产物以回收烃，特别是烯烃，如丙烯和异丁烯，以及未反应的原料。 该方法采用部分冷凝步骤序列，散布有膜分离步骤以提高未冷凝气体的烃露点，从而避免使用低温或低温条件。
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公开(公告)号：US09403120B2
公开(公告)日：2016-08-02
申请号：US14330714
申请日：2014-07-14
CPC分类号： B01D71/32 , B01D53/228 , B01D2256/245 , B01D2257/102 , B01D2257/108 , B01D2257/11 , B01D2257/504 , Y02C10/10
摘要： Disclosed herein is a process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of perfluorodioxolane monomers. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
摘要翻译： 本文公开了使用气体分离共聚物膜分离气体混合物的组分的方法。 这些膜使用由全氟二氧戊环单体的共聚物制成的选择层。 与使用常规全氟聚合物制备的膜相比，所得膜对于气体对来说具有优异的选择性，同时保持快速的气体渗透性，如Teflon AF，Hyflon AD和Cytop®。
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公开(公告)号：US20160195014A1
公开(公告)日：2016-07-07
申请号：US15066771
申请日：2016-03-10
CPC分类号： B01D53/22 , B01D53/229 , B01D53/62 , B01D2053/221 , B01D2256/22 , B01D2257/102 , B01D2257/104 , B01D2257/504 , B01D2258/0283 , F01K5/00 , F01K23/10 , F02C3/34 , F02C6/18 , F05D2260/61 , F05D2260/611 , F23C9/00 , F23L2900/07001 , Y02C10/04 , Y02C10/10 , Y02E20/16 , Y02E20/18 , Y02E20/185 , Y02E20/322
摘要： Disclosed herein is a power generation process in which a portion of the carbon dioxide generated by gaseous fuel combustion is recycled back to the power generation process, either pre-combustion, post-combustion, or both. The power generation process of the invention may be a combined cycle process or a traditional power generation process. The process utilizes sweep-based membrane separation.
摘要翻译： 本文公开了一种发电过程，其中通过气体燃料燃烧产生的二氧化碳的一部分被循环回到燃烧前，后燃烧或两者的发电过程。 本发明的发电过程可以是联合循环过程或传统的发电过程。 该方法利用基于扫描的膜分离。
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公开(公告)号：US09309171B2
公开(公告)日：2016-04-12
申请号：US14789166
申请日：2015-07-01
申请人： Paul Su
发明人： Paul Su
CPC分类号： C07C7/144 , B01D53/002 , B01D53/225 , B01D53/229 , B01D2256/24 , B01D2257/108 , B01D2257/702 , C01B3/501 , C01B2203/0405 , C01B2203/048 , C07C7/005 , C07C7/09 , Y02P20/582 , C07C11/04 , C07C11/06 , C07C11/08
摘要： A process for treating an effluent gas stream arising from a manufacturing operation that produces an olefin or a non-polymeric olefin derivative. The process involves cooling and condensing the effluent gas stream, which comprises an olefin, a paraffin, and a third gas, to produce a liquid condensate and an uncondensed (residual) gas stream. Both streams are then passed through membrane separation steps. The membrane separation of the uncondensed gas stream results in an olefin-enriched stream and an olefin-depleted stream. The olefin-enriched stream is recirculated within the process prior to the condensation step. The membrane separation of the condensate also results in an olefin-enriched stream, which may be recycled for use within the manufacturing operation, and an olefin-depleted stream, which may be purged from the process.
摘要翻译： 一种处理由产生烯烃或非聚合烯烃衍生物的制造操作产生的流出气流的方法。 该方法包括冷却和冷凝包含烯烃，石蜡和第三气体的废气流，以产生液体冷凝物和未冷凝（残余）气流。 然后将两个流通过膜分离步骤。 未冷凝的气流的膜分离产生富烯烃流和烯烃贫化流。 在冷凝步骤之前，在该过程中再循环富烯烃流。 冷凝物的膜分离还导致富含烯烃的物流，其可以在制造操作中再循环使用，以及可以从该方法中清除的烯烃贫化物流。
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45.发明申请公开(公告)号：US20160045859A1
公开(公告)日：2016-02-18
申请号：US14921382
申请日：2015-10-23
申请人： Hao Zhang , Zhenjie He , Timothy C. Merkel , Yoshiyuki Okamoto , Yasuhiro Koike
发明人： Hao Zhang , Zhenjie He , Timothy C. Merkel , Yoshiyuki Okamoto , Yasuhiro Koike
CPC分类号： B01D53/228 , B01D71/32 , B01D2256/245 , B01D2257/102 , B01D2257/108 , B01D2257/11 , B01D2257/504 , Y02C10/10
摘要： A process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of partially fluorinated or perfluorinated dioxolane monomers and a second monomer, such as dioxane or a partially fluorinated dioxolane. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon® AF, Hyflon® AD, and Cytop®.
摘要翻译： 使用气体分离共聚物膜分离气体混合物的组分的方法。 这些膜使用由部分氟化或全氟化二氧戊环单体和第二单体如二恶烷或部分氟化二氧戊环的共聚物制成的选择层。 与使用常规全氟聚合物制备的膜相比，所得膜对于气体对来说具有优异的选择性，同时保持快速的气体渗透性，如Teflon AF，Hyflon AD和Cytop®。
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46.发明授权公开(公告)号：US09205380B2
公开(公告)日：2015-12-08
申请号：US13776362
申请日：2013-02-25
申请人： Paul Su
发明人： Paul Su
摘要： Disclosed herein is a methanol-to-propylene (MTP) conversion process that utilizes a membrane separation step to increase the recycle of C2 hydrocarbons back to the MTP reactor, thereby increasing propylene product yield and reducing raw material loss.
摘要翻译： 本文公开了甲醇 - 丙烯（MTP）转化方法，其利用膜分离步骤将C2烃的再循环增加回MTP反应器，从而提高丙烯产物产率并减少原料损失。
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47.发明授权Sweep-based membrane gas separation integrated with gas-fired power production and CO2 recovery 有权基于扫描的膜气分离与燃气发电和二氧化碳回收相结合公开(公告)号：US09140186B2
公开(公告)日：2015-09-22
申请号：US13830530
申请日：2013-03-14
IPC分类号： B01D53/22 , F02C7/00 , H02K7/18 , B01D53/62 , F02C3/34 , F23C9/00 , F23J15/02 , F23L7/00 , B01D53/14
CPC分类号： F02C7/00 , B01D53/1475 , B01D53/22 , B01D53/62 , B01D2251/306 , B01D2251/606 , B01D2252/10 , B01D2252/20478 , B01D2256/22 , B01D2257/102 , B01D2257/104 , B01D2257/504 , B01D2258/0283 , F02C3/34 , F23C9/00 , F23J15/02 , F23J2215/50 , F23L7/007 , F23L2900/07001 , H02K7/1823 , Y02A50/2342 , Y02C10/04 , Y02C10/06 , Y02C10/10 , Y02E20/16 , Y02E20/18 , Y02E20/322 , Y02E20/326 , Y02E20/344
摘要： A process involving membrane-based gas separation and power generation, specifically for controlling carbon dioxide emissions from gas-fired power plants. The process includes a compression step, a combustion step, and an expansion/electricity generation step, as in traditional power plants. The process also includes a sweep-driven membrane separation step and a carbon dioxide removal or capture step. The carbon dioxide removal step is carried out on a portion of gas from the compression step.
摘要翻译： 涉及膜基气体分离和发电的过程，专门用于控制燃气发电厂的二氧化碳排放。 该方法包括压缩步骤，燃烧步骤和膨胀/发电步骤，如在传统发电厂中。 该方法还包括扫掠驱动的膜分离步骤和二氧化碳去除或捕获步骤。 二氧化碳去除步骤对来自压缩步骤的一部分气体进行。
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48.发明授权公开(公告)号：US09138678B2
公开(公告)日：2015-09-22
申请号：US13370062
申请日：2012-02-09
申请人： Yu Huang , Richard W. Baker , Benjamin McCool , Rong Dong
发明人： Yu Huang , Richard W. Baker , Benjamin McCool , Rong Dong
CPC分类号： B01D53/228 , B01D3/145 , B01D61/362 , B01D71/32 , B01D71/44 , B01D2311/2669 , C07C29/76 , C07C31/08
摘要： Disclosed herein are processes for removing water from organic solvents, such as ethanol. The processes include distillation in two columns operated at sequentially higher pressure, followed by treatment of the overhead vapor by one or two membrane separation steps.
摘要翻译： 本文公开了从有机溶剂如乙醇中除去水的方法。 这些方法包括在连续较高压力下运行的两个塔中进行蒸馏，然后通过一个或两个膜分离步骤处理塔顶蒸气。
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公开(公告)号：US09073808B1
公开(公告)日：2015-07-07
申请号：US14486382
申请日：2014-09-15
申请人： Paul Su , Nicholas P Wynn , Marc Jacobs , Xiaotong Wei , Sylvie Thomas-Droz , Xuezhen Wang
发明人： Paul Su , Nicholas P Wynn , Marc Jacobs , Xiaotong Wei , Sylvie Thomas-Droz , Xuezhen Wang
摘要： A process for recovering unreacted olefin in a polyolefin manufacturing process comprising the treatment of a purge bin vent gas. The process involves cooling and condensing the vent gas (purge stream), which contains at least an olefin, a paraffin, and nitrogen, to produce a liquid condensate and an uncondensed (residual) gas stream. Both streams are then passed through membrane separation steps. The membrane separation of the uncondensed gas stream results in a residue stream containing mostly nitrogen and/or paraffin and a permeate stream enriched in either C2+ hydrocarbons or olefin, depending on the type of separation. The permeate from this step is recirculated within the process prior to the condensation step. The membrane separation of the condensate results in a residue stream containing paraffin and a permeate stream enriched in olefin, which may be recycled to the polymerization reactor.
摘要翻译： 一种在聚烯烃制造方法中回收未反应烯烃的方法，包括处理净化箱排气。 该方法包括冷却和冷凝含有至少一种烯烃，石蜡和氮气的排出气体（吹扫流），以产生液体冷凝物和未冷凝（残余）气流。 然后将两个流通过膜分离步骤。 未冷凝的气流的膜分离导致根据分离类型，主要含有氮和/或石蜡的残留物流和富含C 2 +烃或烯烃的渗透物流。 来自该步骤的渗透物在冷凝步骤之前在该过程中再循环。 冷凝物的膜分离产生含有石蜡和富含烯烃的渗透物流的残余物流，其可循环至聚合反应器。
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50.发明授权公开(公告)号：US09017451B2
公开(公告)日：2015-04-28
申请号：US13422344
申请日：2012-03-16
IPC分类号： B01D53/22 , B01D53/047 , B01D53/14
CPC分类号： B01D53/229 , B01D53/047 , B01D53/14 , B01D53/226 , B01D2256/245
摘要： A gas separation process that utilizes ejector recycle with a membrane separation step in combination with a second separation step. The second separation step may be a second membrane separation, or may involve a different type of separation process. At least a portion of the non-product (i.e. residue) stream withdrawn from the second separation step is directed back to the ejector to form a processing loop. The ejector drives the gas flow in the loop and recycles the non-product stream to the first separation step.
摘要翻译： 一种气体分离方法，其利用具有膜分离步骤的喷射器再循环与第二分离步骤组合。 第二分离步骤可以是第二膜分离，或者可以涉及不同类型的分离过程。 从第二分离步骤取出的至少一部分非产物（即残余物）流被引导回喷射器以形成处理回路。 喷射器驱动环路中的气流，并将非产物流再循环到第一分离步骤。
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