摘要:
It is now possible to provide reaction resin mixtures based on organic polyisocyanates and organic polyepoxides that can be hot-cured to high-quality plastics having isocyanurate and oxazolidinone groups that are largely storage-stable at room temperature, without their curing having to be stopped at any time, so that the systems exist in an intermediate "B-stage" (i.e., in a state that is solid at ambient or moderately elevated temperature but still fusible), so that at any later time, for example after pulverizing or dissolving in a suitable solvent, they can be converted by shaping and further thermal action to their ultimate, crosslinked and no longer fusible final state.
摘要:
The present invention relates to reactive systems comprising(a) a storable mixture of (i) a polyisocyanate component comprising at least one organic polyisocyanate, and (ii) an epoxide component stabilized by heating in the presence of an alkylating agent, wherein said heating is optionally carried out in the further presence of part of the polyisocyanate component (i),(b) an isocyanate-reactive component containing at least two isocyanate-reactive groups in a quantity such that 0.1 to 0.9 isocyanate-reactive groups are present for every isocyanate group in component (a), wherein at least 10% by weight of component (b) comprises compounds having a molecular weight greater than about 2000,(c) optionally, tertiary amines in a quantity such that the total storable mixture contains at least 0.005 mole of tertiary amine nitrogen atoms for each 100 g of the total amount of the storable mixture, and, optionally,(d) other auxiliaries and additives.The present invention also relates to a process for the preparation of optionally foamed polyurethane plastics containing isocyanurate groups comprising (1) mixing the components of such reactive systems at a temperature less than 60.degree. C. and (2) heating said reactive system to a temperature of at least 60.degree. C.
摘要:
The present invention relates to a reaction resin composition comprising a mixture of polyisocyanates, epoxides, and amine catalysts of the formula ##STR1## wherein A is independently alkylene, alkenylene, alkynylene, alkylidene, cycloalkylene, or aralkenylene; m is an integer of from 0 to 30; R.sup.1, R.sup.2 and R.sup.3 are independently optionally substituted aralkyl or polyaralkyl; and R.sup.4 is alkyl, alkenyl, alkynyl, cycloalkyl, or optionally substituted aralkyl or polyaryalkyl.
摘要翻译:本发明涉及一种反应树脂组合物,其包含下式的多异氰酸酯,环氧化物和胺催化剂的混合物,其中A独立地为亚烷基,亚烯基,亚炔基,亚烷基,亚环烷基或芳亚烯基; m为0〜30的整数; R 1,R 2和R 3独立地是任选取代的芳烷基或聚芳烷基; 且R 4为烷基,烯基,炔基,环烷基或任选取代的芳烷基或多芳基烷基。
摘要:
1,2,4-Triazole-blocked polyisocyanates are excellent crosslinking agents for polyhydroxyl compounds. Their comparatively high melting point makes these compositions particularly suitable for coatings which are applied by fluidisation dip coating or electrostatic powder spraying.