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公开(公告)号：US6160054A
公开(公告)日：2000-12-12
申请号：US687111
申请日：1996-07-18
IPC分类号： C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/00 , C08F12/04 , C08F36/04 , C08F297/04 , C08F8/30 , C08F8/46
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula:FG--(Q).sub.d --Z--J--[A(R.sup.1 R.sup.2 R.sup.3)].sub.x (I)wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R.sup.1 R.sup.2 R.sup.3)].sub.x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
摘要翻译： 具有式FG-（Q）d-Z-J- [A（R 1 R 2 R 3）] x（I）的异烟酰基聚合物，其中FG是受保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R1R2R3）] x为保护基，其中A为选自元素周期表第Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基 和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。
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公开(公告)号：US5922810A
公开(公告)日：1999-07-13
申请号：US679291
申请日：1996-07-12
CPC分类号： C08C19/00 , C08F8/00 , C08F2810/40
摘要： A process for removing a protecting group from a polymer. Protected functional groups of a polymer may be deprotected by treating the polymer in the presence of an acid catalyst, including organic acids, mineral acids, heterogeneous acid systems, Lewis acids, and fluoride ion sources.
摘要翻译： 从聚合物中除去保护基团的方法。 通过在酸催化剂存在下处理聚合物，包括有机酸，无机酸，多相酸体系，路易斯酸和氟离子源，可以将保护的聚合物的官能团脱保护。
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公开(公告)号：US5919870A
公开(公告)日：1999-07-06
申请号：US660658
申请日：1996-06-05
摘要： Protected functional initiators have been demonstrated to polymerize dienes and alkenyl substituted aromatics. The resultant living anions were linked with a coupling agent, such as divinylbenzene or tin tetrachloride, to afford a protected functionalized star polymer. Subsequent deprotection afforded a star polymer, with functional groups on the end of each arm of the star. The star polymer could be hydrogenated before or after removal of the protecting groups. The newly liberated functional groups can participate in further polymerization chemistry.
摘要翻译： 已经证明保护的官能引发剂聚合二烯和烯基取代的芳族化合物。 所得活性阴离子与偶联剂如二乙烯基苯或四氯化锡连接，得到受保护的官能化星形聚合物。 随后的脱保护得到星形聚合物，其中每个臂的末端具有官能团。 星形聚合物可以在除去保护基团之前或之后被氢化。 新释放的官能团可以参与进一步的聚合化学。
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公开(公告)号：US5827929A
公开(公告)日：1998-10-27
申请号：US631274
申请日：1996-04-12
IPC分类号： C07F1/02 , C08C19/44 , C08F4/48 , C08F8/00 , C08F36/04 , C08F297/04 , C07C43/115
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M--Z--O--C(R.sup.1 R.sup.2 R.sup.3) wherein M is an alkali metal; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkoxy, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkoxy, lower alkylthio, and lower dialkylamino groups, and their employment as initiators in the anionic polymerization of olefin containing monomers in an inert, hydrocarbon solvent comprising reacting an omega-protected-1-haloalkyl with lithium metal dispersion having a particle size between 10 and 300 millimicrons in size, at a temperature between 35.degree. and 130.degree. C. in an alkane solvent containing 5 to 10 carbon atoms.
摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Z-O-C（R 1 R 2 R 3）其中M为碱金属; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; 并且R 1，R 2和R 3独立地选自氢，烷基，含有低级烷氧基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷氧基，低级烷硫基和低级二烷基氨基的芳基或取代芳基， 作为在惰性烃溶剂中含烯烃单体的阴离子聚合中的引发剂，包括使ω-保护的1-卤代烷基与尺寸为10-300毫微米的锂金属分散体在35℃和130℃之间的温度下反应 在含有5至10个碳原子的烷烃溶剂中。
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公开(公告)号：US5780551A
公开(公告)日：1998-07-14
申请号：US657084
申请日：1996-06-03
CPC分类号： C08G81/022 , C08C19/44 , C08F12/06 , C08F297/044 , C08F36/04 , C08F4/461 , C08G64/18
摘要： This invention concerns novel, unsymmetrically protected, telechelically functionalized linear and star or multi-arm polymers, their optionally hydrogenated analogues, the polymers produced by selective removal of the protecting groups, the segmented block polymers produced by further reaction of these selectively deprotected polymers with selected comonomers, and the processes to prepare these polymers.
摘要翻译： 本发明涉及新颖的，不对称保护的，电视功能化的线性和星形或多臂聚合物，它们任选氢化的类似物，通过选择性去除保护基产生的聚合物，通过这些选择性去保护的聚合物与所选择的进一步反应产生的分段嵌段聚合物 共聚单体，以及制备这些聚合物的方法。
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公开(公告)号：US5708092A
公开(公告)日：1998-01-13
申请号：US631524
申请日：1996-04-12
IPC分类号： C08C19/44 , C08F4/08 , C08F4/46 , C08F4/48 , C08F12/04 , C08F12/06 , C08F36/04 , C08F279/02 , C07F1/02
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure: M--Q.sub.n --Z--OA(R.sup.1 R.sup.2 R.sup.3) wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenylsubstituted aromatic hydrocarbons; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from carbon and silicon; R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and n is an integer from 1 to 5, monofunctional ethers produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译： 一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Qn-Z-OA（R1R2R3）其中M定义为碱金属，选自锂，钠和钾，Q 是通过引入选自共轭二烯烃和烯基取代的芳族烃的化合物衍生的饱和或不饱和烃基; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; A是选自碳和硅的元素; R 1，R 2和R 3独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基，n是 1至5的整数，通过该方法产生的单官能醚，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。
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公开(公告)号：US5523447A
公开(公告)日：1996-06-04
申请号：US477843
申请日：1995-06-07
CPC分类号： C07F1/02
摘要： A process for preparing easily separable solutions of organolithium compounds comprising the steps of reacting lithium metal, in the form of cast or extruded ingots or pieces cut therefrom, with an organo halide in mole ratios ranging from 3:1 to 20:1 in a solvent selected form a group of liquid hydrocarbons, alkyl ethers, and mixtures thereof under an inert atmosphere for one to ten hours with moderate stirring, cooling the resulting product, and separating the solution of the organolithium compound from the reacted lithium metal and by-product lithium chloride in the reactor.
摘要翻译： 一种用于制备容易分离的有机锂化合物溶液的方法，包括以下步骤：将以铸造或挤出的锭或其切割的碎片形式的锂金属与摩尔比为3:1至20:1的有机卤化物在溶剂 在惰性气氛下选择形成一组液体烃，烷基醚及其混合物，在适度搅拌下搅拌1至10小时，冷却所得产物，并将有机锂化合物的溶液与反应的锂金属和副产物锂 氯化物在反应器中。
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公开(公告)号：US5486343A
公开(公告)日：1996-01-23
申请号：US232891
申请日：1994-04-25
IPC分类号： C01B21/092 , C01B21/00
CPC分类号： C01B21/0926
摘要： A process for the preparation of lithium amide comprising essentially forming lithium bronze by introducing at least 1 equivalent of anhydrous ammonia over a 1 to 5 hour period into a dispersion containing one equivalent of lithium in a liquid hydrocarbon solvent at a temperature of up to 40.degree. C., then after the lithium bronze is formed, heating the reaction mixture to 50.degree. to 80.degree. C. for 2 to four hours to decompose the lithium bronze and form a suspension of lithium amide in the solvent from which suspension the lithium amide is recovered.
摘要翻译： 一种制备氨基化锂的方法，其包括在1至5小时内将至少1当量的无水氨在至多40℃的温度下在液态烃溶剂中引入含有1当量的锂的分散体中，基本上形成青铜 然后在形成锂青铜之后，将反应混合物加热至50〜80℃2〜4小时，分解锂青铜，形成氨基锂的悬浮液，在该溶剂中，将氨化锂为 恢复。
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公开(公告)号：US4836845A
公开(公告)日：1989-06-06
申请号：US95791
申请日：1987-09-14
申请人： James A. Schwindeman
发明人： James A. Schwindeman
IPC分类号： A01N43/80 , A01N43/82 , C07D413/04 , C07D417/04
CPC分类号： C07D413/04 , A01N43/80 , A01N43/82 , C07D417/04
摘要： The invention relates to certain 3-isoxazolyl-2-imidazolidinone derivatives, namely 3-[5- or 3-substituted-3- or -5-isoxazolyl]-1-substituted-4- or 5-substituted amino-2-imidazolidinones and the use thereof for preemergence or postemergence control of noxious plants, i.e., weeds.
摘要翻译： 本发明涉及某些3-异恶唑基-2-咪唑啉酮衍生物，即3- [5-或3-取代-3-或5-异恶唑基] -1-取代的4-或5-取代的氨基-2-咪唑烷酮，和 其用于对有害植物（即杂草）进行芽前或芽后控制。
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50.发明授权Herbicidally active aryloxy optionally oxo-substituted indane or tetralin derivatives 失效除草活性芳氧基任选氧代取代的二氢化茚或四氢化萘衍生物
公开(公告)号：US4790870A
公开(公告)日：1988-12-13
申请号：US44675
申请日：1987-05-01
IPC分类号： A01N31/14 , A01N35/06 , A01N35/10 , A01N37/38 , A01N43/40 , C07C43/295 , C07C45/71 , C07C49/755 , C07C49/757 , C07D213/64 , C07D213/643
CPC分类号： C07D213/643 , A01N31/14 , A01N35/06 , A01N35/10 , A01N37/38 , A01N43/40 , C07C43/295 , C07C45/71 , C07C49/755 , C07C49/757 , C07C2102/10
摘要： This invention relates to aryloxy optionally oxo-substituted indane or tetralin derivatives having herbicidal activity and to the use of such compounds to control the growth of noxious plants, i.e., weeds.
摘要翻译： 本发明涉及具有除草活性的芳氧基任选氧代取代的二氢化茚或四氢化萘衍生物，以及这些化合物用于控制有害植物即杂草生长的用途。
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