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公开(公告)号：US4237309A
公开(公告)日：1980-12-02
申请号：US957612
申请日：1978-11-03
申请人： James E. Lyons , George Suld , Robert W. Shinn
发明人： James E. Lyons , George Suld , Robert W. Shinn
IPC分类号： C07C69/12 , B01J27/00 , B01J31/00 , C07B61/00 , C07C27/00 , C07C37/055 , C07C45/36 , C07C45/41 , C07C45/54 , C07C51/56 , C07C67/00 , C07C67/05 , C07C69/14 , C07C67/39 , C07C69/157
CPC分类号： C07C69/14 , C07C37/0555 , C07C45/36 , C07C45/41 , C07C45/54 , C07C51/56 , C07C67/00 , C07C67/05 , Y02P20/52
摘要： The oxidation of methyl benzenes with air or oxygen in the presence of acetic anhydride, benzaldehyde and an acid catalyst under mild reaction conditions yields a phenolic acetate and formaldehyde or paraformaldehyde when the ratio of acetic anhydride to methyl benzene is adjusted to provide the selective formation of the phenolic acetate and formaldehyde or paraformaldehyde. In this process, it is essential that the flow of air or oxygen through the reaction medium be maintained at a sufficient rate to provide for the continuous removal of formaldehyde as it is formed. The formaldehyde may then be recovered in the form of paraformaldehyde.
摘要翻译： 在温和的反应条件下，在乙酸酐，苯甲醛和酸催化剂存在下，用空气或氧气氧化甲基苯，当乙酸酐与甲基苯的比例被调整时，产生酚类乙酸酯和甲醛或多聚甲醛，以提供选择性形成 酚类醋酸酯和甲醛或多聚甲醛。 在这个过程中，重要的是通过反应介质的空气或氧气的流动维持在足够的速率以提供甲醛在其形成时的连续除去。 然后可以以多聚甲醛的形式回收甲醛。
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42.发明授权Ion-exchanged transition metal catalysts for the direct oxidation of olefins to epoxyalcohols 失效用于将烯烃直接氧化成环氧醇的离子交换过渡金属催化剂
公开(公告)号：US4182722A
公开(公告)日：1980-01-08
申请号：US617907
申请日：1975-09-29
申请人： James E. Lyons
发明人： James E. Lyons
IPC分类号： B01J31/08 , B01J31/10 , C07D301/06 , C07D303/04 , C07D303/14
CPC分类号： B01J31/10 , B01J31/08 , C07D301/06 , C07D303/04 , C07D303/14 , B01J2231/72
摘要： Acylic or cyclic epoxyalcohols can be prepared by direct oxidation of an olefin when there is employed an ion-exchanged bimetallic catalyst, wherein one metal is from Groups IB or VIII, and the other from Group V.
摘要翻译： 酰基或环状环氧醇可以通过使用离子交换的双金属催化剂直接氧化烯烃来制备，其中一种金属来自IB或VIII族，另一种来自第V族。
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43.发明授权Conversion of benzylidene diacetate to phenyl acetate and methylene diacetate 失效将二乙酸亚苄基酯转化为乙酸苯酯和二乙酸亚甲基酯
公开(公告)号：US4156783A
公开(公告)日：1979-05-29
申请号：US890180
申请日：1978-03-27
申请人： James E. Lyons , Robert W. Shinn , George Suld
发明人： James E. Lyons , Robert W. Shinn , George Suld
IPC分类号： C07C67/05 , C07C69/035 , C07C69/157 , C07C69/14
CPC分类号： C07C67/05
摘要： Benzylidene diacetate may be converted to phenyl acetate and methylene diacetate by an acid-catalyzed reaction in the presence of oxygen or air, and acetic anhydride, at elevated temperatures and pressures.
摘要翻译： 在升高的温度和压力下，在氧气或空气和乙酸酐的存在下，亚苄基二乙酸酯可以通过酸催化反应转化成乙酸苯酯和二乙酸亚苯酯。
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公开(公告)号：US3987112A
公开(公告)日：1976-10-19
申请号：US515762
申请日：1974-10-17
申请人： James E. Lyons
发明人： James E. Lyons
CPC分类号： B01J31/165 , B01J31/08 , B01J31/20 , B01J31/2295 , C07C39/08 , B01J2231/72 , B01J2531/56
摘要： A 4-stage process for the production of catechol, starting with a mixture of cyclohexanol-cyclohexanone ("KA-oil"), is provided herein whereby the starting mixture is first hydrotreated to convert the cyclohexanone to cyclohexanol, the cyclohexanol dehydrated to form cyclohexene which, in turn, is oxidized to 1,2-epoxy-3-hydroxy-cyclohexane. Dehydrogenation of this latter compound yields catechol. Volatiles and residue from the second stage are advantageously recycled to the KA-oil feed stream, and H.sub.2 from the last stage recycled to the hydrotreating step.
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公开(公告)号：US06729190B1
公开(公告)日：2004-05-04
申请号：US10282638
申请日：2002-10-28
申请人： Ronald A. Boyko , Cory F. Guenter , James F. King, Jr. , James E. Lyons , Chester P. Tuttle, Jr.
发明人： Ronald A. Boyko , Cory F. Guenter , James F. King, Jr. , James E. Lyons , Chester P. Tuttle, Jr.
IPC分类号： G01N310
CPC分类号： G01N3/10 , G01N2203/0452
摘要： Methods and apparatus for testing the strength of ceramic honeycomb structures are described. The apparatus includes a chamber that utilizes a flexible, generally cylindrical member including integral flanges to apply compressive force to the periphery of the honeycomb structure. According to some embodiments, a portable apparatus with an open chamber is provided to allow for rapid testing of multiple honeycomb structures.
摘要翻译： 描述了用于测试陶瓷蜂窝结构的强度的方法和装置。 该装置包括一个室，其利用一个柔性的，大致圆柱形的构件，该构件包括一体的凸缘，以向蜂窝结构的周边施加压力。 根据一些实施例，提供具有开放室的便携式设备以允许对多个蜂窝结构的快速测试。
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公开(公告)号：US5767272A
公开(公告)日：1998-06-16
申请号：US769974
申请日：1996-12-19
IPC分类号： B01J31/18 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C07F15/02
CPC分类号： C07F15/025 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/36 , C07C45/53 , C07D487/22 , C07D519/00 , C12C11/02 , B01J2531/025 , B01J2531/842 , C07C2101/14 , C07C2101/16
摘要： Transition metal complexes of meso-haloalkylporphyrins, wherein the haloalkyl groups contain 2 to 8 carbon atoms have been found to be highly effective catalysts for oxidation of alkanes and for the decomposition of hydroperoxides. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solid catalyst. Also disclosed is a process for the preparation of meso-halocarbyl-porphyrins which comprises contacting a halocarbyl dipyrromethane with a halocarbyl-substituted aldehyde in the presence of an acid granular solic catalyst.
摘要翻译： 已经发现，其中卤代烷基含有2至8个碳原子的内消旋烷基卟啉的过渡金属络合物是用于烷烃氧化和氢过氧化物分解的高效催化剂。 还公开了一种制备内消旋咔咔卟啉的方法，其包括在酸性颗粒状固体催化剂存在下使卤代烃基二吡咯烷与卤代烃基取代的醛接触。 还公开了制备内消旋咔咔卟啉的方法，其包括在酸性颗粒状催化剂存在下使卤代烃基二吡咯烷与卤代烃基取代的醛接触。
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47.发明授权Method for hydroperoxide decomposition using novel porphyrins synthesized from dipyrromethanes and aldehydes 失效使用由二吡咯烷和醛合成的新型卟啉进行氢过氧化物分解的方法
公开(公告)号：US5723677A
公开(公告)日：1998-03-03
申请号：US670300
申请日：1996-06-27
IPC分类号： B01J27/24 , B01J31/18 , B01J31/22 , C07B61/00 , C07C27/00 , C07C29/132 , C07C29/50 , C07C31/02 , C07C31/10 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/265 , C07C409/16 , C07D487/22 , C07F15/02 , C07C45/28
CPC分类号： C07F15/025 , B01J27/24 , B01J31/1815 , C07C29/132 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/53 , C07C51/215 , C07C51/235 , C07C51/245 , C07C51/25 , C07C51/252 , C07C51/265 , C07D487/22 , B01J2531/025 , B01J2531/72 , B01J2531/821 , B01J2531/842 , B01J2531/845
摘要： The invention comprises a method for the oxidation of alkanes to alcohols and for decomposition of hydroperoxides to alcohols utilizing new compositions of matter, which are metal complexes of porphyrins. Preferred complexes have hydrogen, haloalkyl or haloaryl groups in meso positions, two of the opposed meso atoms or groups being hydrogen or haloaryl, and two of the opposed meso atoms or groups being hydrogen or haloalkyl, but not all four of the meso atoms or groups being hydrogen. Other preferred complexes are ones in which all four of the meso positions are substituted with haloalkyl groups and the beta positions are substituted with halogen atoms. A new method of synthesizing porphyrinogens is also disclosed.
摘要翻译： 本发明包括使用作为卟啉的金属络合物的物质的新组合物将烷烃氧化成醇并将氢过氧化物分解成醇的方法。 优选的络合物在中间位置具有氢，卤代烷基或卤代芳基，两个相对的内消旋原子或基团是氢或卤代芳基，两个相对的内消旋原子或基团是氢或卤代烷基，但不是全部四个中子原子或基团 是氢。 其它优选的络合物是其中全部四个中间位置被卤代烷基取代并且β位被卤素原子取代的络合物。 还公开了一种合成卟啉原体的新方法。
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48.发明授权
公开(公告)号：US5382662A
公开(公告)日：1995-01-17
申请号：US997815
申请日：1992-12-29
申请人： Paul E. Ellis, Jr. , James E. Lyons
发明人： Paul E. Ellis, Jr. , James E. Lyons
CPC分类号： C07C45/34 , B01J31/1815 , C07C29/50 , C07C45/33 , B01J2531/025 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/842 , B01J2531/845
摘要： New compositions of matter comprising cyano-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has cyano groups attached thereto in meso and/or .beta.-pyrrolic positions.
摘要翻译： 包含卟啉的氰基取代的金属络合物的物质的新组合物是用于烷烃氧化的催化剂。 金属是铁，铬，锰，钌，铜或钴。 卟啉环在内消旋和/或β-吡咯位置上连接有氰基。
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49.发明授权
公开(公告)号：US5345008A
公开(公告)日：1994-09-06
申请号：US73840
申请日：1993-06-09
申请人： James E. Lyons , Paul E. Ellis, Jr.
发明人： James E. Lyons , Paul E. Ellis, Jr.
IPC分类号： B01J31/22 , C07B61/00 , C07C27/00 , C07C29/132 , C07C29/50 , C07C31/12 , C07C37/08 , C07C45/53 , C07C29/48 , C07C31/00 , C07C33/00
CPC分类号： C07C29/132 , C07C29/50 , C07C37/08 , C07C45/53 , C07C2101/14
摘要： Hydroperoxides are decomposed by contact with metalloporphyrin coordination complex catalysts in which hydrogen in the porphyrin molecule has been substituted with at least one nitro group and may be further substituted with other electron-withdrawing elements or groups, for example, halogen or halocarbons, or with hydrocarbon groups. Preferred catalysts are iron tetranitro-.beta.-octaethylporphyrins and iron tetrakispentafluorophenyl-.beta.-nitroporphyrins.
摘要翻译： 氢过氧化物通过与金属卟啉配位络合物催化剂接触而分解，其中卟啉分子中的氢被至少一个硝基取代，并且可以进一步被其它吸电子元素或基团取代，例如卤素或卤代烃，或与烃 团体 优选的催化剂是四硝基-β-八甲基卟啉铁和四五氟苯基-β-硝基卟啉铁。
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公开(公告)号：US5280115A
公开(公告)日：1994-01-18
申请号：US892106
申请日：1992-06-02
申请人： Paul E. Ellis, Jr. , James E. Lyons
发明人： Paul E. Ellis, Jr. , James E. Lyons
IPC分类号： B01J31/22 , B01J31/18 , C07B61/00 , C07C27/12 , C07C29/50 , C07C45/28 , C07C45/33 , C07C45/34 , C07C47/02 , C07C49/04 , C07D487/22
CPC分类号： C07C45/34 , B01J31/1815 , C07C29/50 , C07C45/33 , B01J2531/025 , B01J2531/16 , B01J2531/62 , B01J2531/72 , B01J2531/821 , B01J2531/842 , B01J2531/845
摘要： Compositions of matter comprising nitro-substituted metal complexes of porphyrins are catalysts for the oxidation of alkanes. The metal is iron, chromium, manganese, ruthenium, copper or cobalt. The porphyrin ring has nitro groups attached thereto in meso and/or .beta.-pyrrolic positions.
摘要翻译： 包含卟啉的硝基取代的金属络合物的物质组合物是用于烷烃氧化的催化剂。 金属是铁，铬，锰，钌，铜或钴。 卟啉环在内消旋和/或（β） - 吡咯位置上连接有硝基。
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