公开(公告)号：US07342135B2

公开(公告)日：2008-03-11

申请号：US11657749

申请日：2007-01-25

Applicant: Helmut Springer ,  Paolo Bavaj

Inventor： Helmut Springer ,  Paolo Bavaj

IPC: C07C209/60 ,  C07C211/36 ,  C07C211/38

CPC classification number: C07C211/19 ,  C07C2602/24

Abstract: 3(4),7(8)-bis(aminomethyl)bicyclo[4.3.0]nonane and a process for its preparation, wherein bicyclo[4.3.0]nona-3,7-diene is reacted with synthesis gas in a homogeneous organic phase in the presence of transition metal compounds of Group VIII of the Periodic Table containing complex-bound organophosphorus compounds, and excess organophosphorus compound, at temperatures of 70 to 160° C. and pressures of 5 to 35 MPa, and the 3(4),7(8)-bisformylbicyclo[4.3.0]nonane thus obtained is reductively aminated.

Abstract translation: 3（4），7（8） - 双（氨基甲基）双环[4.3.0]壬烷及其制备方法，其中双环[4.3.0]壬-3,7-二烯与合成气以均匀 在70至160℃的温度和5至35MPa的压力下，在含有复合结合的有机磷化合物的周期表第Ⅷ族的过渡金属化合物和过量的有机磷化合物存在下的有机相和3（4 ），7（8） - 二甲酰基双环[4.3.0]壬烷进行还原胺化。

公开(公告)号：US07122706B2

公开(公告)日：2006-10-17

申请号：US10968760

申请日：2004-10-19

Applicant: Peter Lappe ,  Helmut Springer ,  Rainer Lukas

Inventor： Peter Lappe ,  Helmut Springer ,  Rainer Lukas

IPC: C07C45/50

CPC classification number: C07C47/445 ,  C07C45/50 ,  C07C45/82

Abstract: A process for selectively hydroformylating dicyclopentadiene to 8(9)-formyltricyclo-[5.2.1.02,6]dec-3-ene in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus(III) compounds in complex-bound form, of group VIII of the Periodic Table of the Elements, wherein the water-soluble organic phosphorus(III) compounds are alkali metal or alkaline earth metal salts of sulfonated arylphosphines and aryldiphosphines.

Abstract translation: 使用含水的过渡金属化合物的水溶液在非均相反应体系中选择性地将二环戊二烯加氢甲酰化为8（9） - 甲酰基三环[5.2.1.0 2,6]癸-3-烯的方法 其中水溶性有机磷（III）化合物是磺化芳基膦和芳基二膦的碱金属或碱土金属盐，它们是复合结合形式的元素周期表第Ⅷ族的可溶性有机磷（III）化合物。

公开(公告)号：US20060106249A1

公开(公告)日：2006-05-18

申请号：US11237294

申请日：2005-09-28

Applicant: Helmut Springer ,  Frank Winsberg

Inventor： Helmut Springer ,  Frank Winsberg

IPC: C07C51/235

CPC classification number: C07C51/235 ,  C07C53/126

Abstract: The present invention relates to a process for preparing aliphatic straight-chain and β-alkyl-branched carboxylic acids by catalytic oxidation of aldehydes by means of oxygen or oxygen-containing gas mixtures. Alkali metal carboxylates or alkaline earth metal carboxylates or a mixture thereof in an amount, calculated as alkali metal or alkaline earth metal, of from 1 mmol each to from 10 mmol each per mole of aldehyde used and also metals or compounds of metals of groups 5 to 11 of the Periodic Table of the Elements in amounts of not more than 5 ppm, based on aldehyde used, are present as catalyst.

公开(公告)号：US06800783B2

公开(公告)日：2004-10-05

申请号：US10204619

申请日：2002-09-05

Applicant: Helmut Springer ,  Peter Lappe

Inventor： Helmut Springer ,  Peter Lappe

IPC: C07C51235

CPC classification number: C07C51/235 ,  Y02P20/582 ,  C07C53/126 ,  C07C53/124

Abstract: The invention relates to a method for the synthesis of aliphatic carboxylic acids by the catalytic oxidation of aldehydes with oxygen, or oxygen-containing gas mixtures. Metals of groups 5 11 of the periodic table of elements, or the compounds thereof are used as catalyst, in amounts of up to 5 ppm, based upon the amount of aldehyde used.

Abstract translation: 本发明涉及通过用氧或含氧气体混合物催化氧化醛来合成脂族羧酸的方法。 基于元素周期表的第5组11的金属或其化合物，以所使用的醛的量为基准，最多可用量为5ppm。

公开(公告)号：US06288288B1

公开(公告)日：2001-09-11

申请号：US09199862

申请日：1998-11-25

Applicant: Helmut Springer

Inventor： Helmut Springer

IPC: C07C2914

CPC classification number: C07C29/175 ,  C07C45/74 ,  C07C49/203 ,  C07C31/125

Abstract: A process for preparing saturated alcohols comprising effecting an aldol condensation of alkyl methyl ketones of 6 to 8 carbon atoms which are branched at the &bgr;-carbon atom with aldehydes of 4 to 15 carbon atoms which are branched at the &agr;-carbon atom to form &agr;,&bgr;-unsaturated ketones and subsequent hydrogenation of the &agr;,&bgr;-unsaturated ketones to obtain alcohols, wherein the aldol condensation is carried out at a temperature of 60 to 130° C. in the presence of a 30-55% strength aqueous solution of an alkali metal hydroxide resulting in very low by-product formation.

Abstract translation: 一种制备饱和醇的方法，包括使在碳原子上分支的碳原子数为6至8的烷基甲基酮与醛原子上含有4至15个碳原子的醛进行醛醇缩合从而形成α ，β-不饱和酮和随后氢化α，β-不饱和酮以获得醇，其中醛醇缩合在60至130℃的温度下进行，在30-55％强度的 碱金属氢氧化物导致非常低的副产物形成。

公开(公告)号：US5264600A

公开(公告)日：1993-11-23

申请号：US855731

申请日：1992-03-20

Applicant: Peter Lappe ,  Helmut Springer

Inventor： Peter Lappe ,  Helmut Springer

IPC: B01J31/24 ,  B01J31/40 ,  B01J38/00 ,  B01J38/58 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/313 ,  C07C69/716 ,  C22B11/00 ,  C07F15/00

CPC classification number: B01J31/1845 ,  B01J31/185 ,  B01J31/24 ,  B01J31/2404 ,  B01J31/4046 ,  B01J38/58 ,  C07C45/50 ,  C07C67/293 ,  C07C67/54 ,  B01J2231/321 ,  B01J2531/822 ,  B01J31/04 ,  B01J31/26 ,  Y02P20/584

Abstract: Recovery of rhodium from the distillation residues from the crude products of oxo synthesis, the residue or the starting material containing the residue is treated with oxygen or an oxygen-containing gas in the presence of a monocarboxylic acid with 2 to 5 carbon atoms and of an alkali metal salt of a monocarboxylic acid with 2 to 5 carbon atoms. The rhodium is subsequently extracted with water as a water-soluble compound.

Abstract translation: 从含氧合成的粗产物的蒸馏残余物中回收铑，残余物或含有残余物的原料在具有2-5个碳原子的一元羧酸存在下用氧或含氧气体处理， 具有2至5个碳原子的一元羧酸的碱金属盐。 随后用水将铑作为水溶性化合物萃取。

公开(公告)号：US4918247A

公开(公告)日：1990-04-17

申请号：US361711

申请日：1989-05-26

Applicant: Norbert Breitkopf ,  Wolfgang Hofs ,  Heinz Kalbfell ,  Franz Thonnessen ,  Peter Lappe ,  Helmut Springer

Inventor： Norbert Breitkopf ,  Wolfgang Hofs ,  Heinz Kalbfell ,  Franz Thonnessen ,  Peter Lappe ,  Helmut Springer

IPC: C07C29/38 ,  C07C29/80 ,  C07C45/75

CPC classification number: C07C29/80 ,  C07C29/38 ,  C07C45/75

Abstract: Preparation of 2,2-dimethylpropanediol-1,3 by the aldol addition of isobutyraldehyde and formaldehyde using tri-n-propylamine as a catalyst, followed by hydrogenation of the reaction mixture, and subsequent distillation of the hydrogenation product in the presence of isobutanol and water.

Abstract translation: 通过使用三正丙胺作为催化剂通过醛醇醛加成异丁醛和甲醛制备2,2-二甲基丙二醇-1,3-，随后氢化反应混合物，随后在异丁醇存在下蒸馏氢化产物， 水。

公开(公告)号：US07799945B2

公开(公告)日：2010-09-21

申请号：US11787868

申请日：2007-04-18

Applicant: Helmut Springer

Inventor： Helmut Springer

IPC: C07C51/235

CPC classification number: C07C51/235 ,  C07C53/126

Abstract: A catalytic process for preparing aliphatic straight-chain and β-alkyl-branched carboxylic acids of 5 to 13 carbon atoms by catalytic oxidation of the corresponding aldehydes by means of oxygen or oxygen-containing gas mixtures in the liquid phase in the presence of a catalyst system contains alkali metal carboxylates or alkaline earth metal carboxylates or a mixture thereof in an amount, calculated as alkali metal or alkaline earth metal, of 0.5 mmol to 15 mmol per mol of aldehyde used and also metals of groups 4 to 12 of the Periodic Table of the Elements, cerium or lanthanum in amounts of not more than 5 ppm, based on the aldehyde used, or compounds of such metals, with the catalyst system being the reaction product from an aldehyde oxidation reaction.

Abstract translation: 通过在液相存在下通过含氧或含氧气体混合物的相应醛催化氧化制备具有5至13个碳原子的脂族直链和/或 - 烷基支链羧酸的催化方法 催化剂体系含有碱金属或碱土金属的碱金属羧酸盐或碱土金属羧酸盐或其混合物，其量为碱金属或碱土金属计算，每摩尔使用的醛为0.5mmol至15mmol，以及周期表中第4至12族的金属 表中的元素，铈或镧的量不大于5ppm，基于所使用的醛，或这些金属的化合物，催化剂体系是醛醛氧化反应的反应产物。

公开(公告)号：US20070179323A1

公开(公告)日：2007-08-02

申请号：US11657771

申请日：2007-01-25

Applicant: Helmut Springer ,  Paolo Bavaj

Inventor： Helmut Springer ,  Paolo Bavaj

IPC: C07C35/20

CPC classification number: C07C29/16 ,  C07C31/278 ,  C07C45/50 ,  C07C47/347 ,  C07C2602/08 ,  C07C2602/24

Abstract: The novel chemical compound, 3(4),7(8)-dihydroxymethylbicyclo[4.3.0]nonane and a process for its preparation, wherein bicyclo[4.3.0]nona-3,7-diene is reacted with synthesis gas in homogeneous organic phase in the presence of transition metal compounds of Group VIII of the Periodic Table containing complex-bound organophosphorus compound, at 70 to 160° C. and pressures of 5 to 35 MPa, and the 3(4),7(8)-bisformylbicyclo[4.3.0]nonane thus obtained is hydrogenated.

Abstract translation: 新型化合物3（4），7（8） - 二羟甲基双环[4.3.0]壬烷及其制备方法，其中双环[4.3.0]壬-3,7-二烯与合成气同质化 在含有复合结合有机磷化合物的元素周期表第Ⅷ族过渡金属化合物存在下，在70至160℃和5至35MPa的压力以及3（4），7（8） - 由此获得的双甲酰基双环[4.3.0]壬烷被氢化。

公开(公告)号：US06939997B2

公开(公告)日：2005-09-06

申请号：US10967580

申请日：2004-10-18

Applicant: Peter Lappe ,  Helmut Springer ,  Rainer Lukas

Inventor： Peter Lappe ,  Helmut Springer ,  Rainer Lukas

IPC: B01J31/24 ,  C07B61/00 ,  C07C29/141 ,  C07C29/16 ,  C07C31/27 ,  C07C45/50 ,  C07C47/347 ,  C07C47/445 ,  C07C35/22

CPC classification number: C07C29/141 ,  C07C29/16 ,  C07C45/50 ,  C07C47/347 ,  C07C2603/68 ,  C07C31/278 ,  C07C47/12 ,  C07C47/02

Abstract: A process for preparing 3(4),8(9)-dihydroxymethyltricyclo[5.2.1.02,6]decane by hydroformylating dicyclopentadiene with subsequent distillation wherein the hydroformylation of dicyclopentadiene is carried out in two stages, and, in a first hydroformylation stage, the reaction is effected in a heterogeneous reaction system using an aqueous solution of transition metal compounds, containing water-soluble organic phosphorus (III) compounds in complex-bound form, of group VIII of the Periodic Table to give 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene, and, in a second hydroformylation stage, the thus obtained 8(9)-formyltricyclo[5.2.1.02,6]dec-3-ene is converted, in homogeneous organic phase in the presence of transition metal compounds of group VIII of the Periodic Table of the Elements to 3(4),8(9)-bisformyltricyclo[5.2.1.02,6]decane.

Abstract translation: 通过加氢甲酰化二环戊二烯制备3（4），8（9） - 二羟基甲基三环[5.2.1.0 2,6]癸烷的方法，随后蒸馏，其中二环戊二烯的加氢甲酰化分两个阶段进行， 在第一加氢甲酰化阶段，反应在非均相反应体系中使用过渡金属化合物的水溶液进行，该过渡金属化合物含有复合结合形式的元素周期表第Ⅷ族的水溶性有机磷（III）化合物，得到 8（9） - 甲酰三环[5.2.1.0 2,6]癸-3-烯，并在第二加氢甲酰化阶段，由此得到的8（9） - 甲酰基三环[5.2.1.0 < 在3元周期表的第Ⅷ族过渡金属化合物存在下，在均相有机相中转变为3,6-亚甲基三环，8（9） - 二甲基三环 [5.2.1.0 2,6]癸烷。