公开(公告)号：US06358419B1

公开(公告)日：2002-03-19

申请号：US08641514

申请日：1996-05-01

Applicant: Mariola Rötzheim ,  Wolfgang Greb ,  Wolfgang Zgorzelski ,  Carl Dieter Frohning ,  Klaus Denkmann ,  Heinz Kalbfell

Inventor： Mariola Rötzheim ,  Wolfgang Greb ,  Wolfgang Zgorzelski ,  Carl Dieter Frohning ,  Klaus Denkmann ,  Heinz Kalbfell

IPC: C02F144

CPC classification number: C02F1/26 ,  C02F2101/34 ,  C02F2103/36 ,  C02F2209/06 ,  Y10S210/05 ,  Y10S210/908 ,  Y10S210/909

Abstract: Wastewater from the aldolization reaction is purified by adjusting its pH to 0 to 6, followed by extraction with monohydric alcohols having at least 8 carbon atoms, hydrocarbons having at least 6 carbon atoms, and mixtures thereof. In some cases, adjustment of the pH causes the formation of an organic phase, which is separated from the remaining wastewater before extraction.

Abstract translation: 通过将其pH调节至0至6，然后用具有至少8个碳原子的一元醇，具有至少6个碳原子的烃及其混合物进行萃取来纯化来自醛糖醛酸化反应的废水。 在某些情况下，pH的调节会导致有机相的形成，其在萃取之前与剩余废水分离。

公开(公告)号：US4533755A

公开(公告)日：1985-08-06

申请号：US558788

申请日：1983-12-07

Applicant: Boy Cornils ,  Josef Hibbel ,  Gunther Kessen ,  Werner Konkol ,  Bernhard Lieder ,  Ernst Wiebus ,  Heinz Kalbfell ,  Hanswilhelm Bach

Inventor： Boy Cornils ,  Josef Hibbel ,  Gunther Kessen ,  Werner Konkol ,  Bernhard Lieder ,  Ernst Wiebus ,  Heinz Kalbfell ,  Hanswilhelm Bach

IPC: B01J31/00 ,  B01J31/28 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/00 ,  C07C27/20

CPC classification number: C07C45/50

Abstract: A process for the hydroformylation of olefins having 2 to 5 carbon atoms using rhodium catalysts in a low pressure process, wherein the waste gas from the low pressure plant containing the olefin is compressed and used in a high pressure plant.

Abstract translation: 在低压方法中使用铑催化剂加氢甲酰化具有2至5个碳原子的烯烃的方法，其中来自含有烯烃的低压装置的废气被压缩并用于高压设备中。

公开(公告)号：US5808168A

公开(公告)日：1998-09-15

申请号：US839328

申请日：1997-04-17

Applicant: Helmut Bahrmann ,  Dieter Frohning ,  Wilhelm Gick ,  Wolfgang Hofs ,  Heinz Kalbfell ,  Harald Kappesser ,  Peter Lappe ,  Kurt Schalapski ,  Ernst Wiebus ,  Wolfgang Zgorzelski

Inventor： Helmut Bahrmann ,  Dieter Frohning ,  Wilhelm Gick ,  Wolfgang Hofs ,  Heinz Kalbfell ,  Harald Kappesser ,  Peter Lappe ,  Kurt Schalapski ,  Ernst Wiebus ,  Wolfgang Zgorzelski

IPC: B01J31/24 ,  C07B61/00 ,  C07C45/50 ,  C07C47/02

CPC classification number: C07C45/50

Abstract: Waste gas obtained in the hydroformylation of olefinically unsaturated compounds in the presence of an aqueous catalyst solution comprising water-soluble rhodium complexes (1st reaction stage) is fed to a homogeneous reaction system in which residual amounts of the olefinically unsaturated compounds from the first reaction stage are reacted in a homogeneous reaction system (2nd reaction stage).

Abstract translation: 在包含水溶性铑络合物的水性催化剂溶液（第一反应阶段）的存在下，在烯属不饱和化合物的加氢甲酰化中获得的废气进料至均相反应体系，其中残余量的来自第一反应阶段的烯属不饱和化合物 在均相反应体系（第二反应阶段）中反应。

公开(公告)号：US5410072A

公开(公告)日：1995-04-25

申请号：US311557

申请日：1994-09-23

Applicant: Helmut Bahrmann ,  Wolfgang Greb ,  Georg Dambkes ,  Peter Heymanns ,  Heinz Kalbfell ,  Peter Lappe ,  Helmut Springer ,  Eberhard von Mulmann ,  Jurgen Weber ,  Ernst Wiebus ,  Carl D. Frohning ,  Harald Kappesser

Inventor： Helmut Bahrmann ,  Wolfgang Greb ,  Georg Dambkes ,  Peter Heymanns ,  Heinz Kalbfell ,  Peter Lappe ,  Helmut Springer ,  Eberhard von Mulmann ,  Jurgen Weber ,  Ernst Wiebus ,  Carl D. Frohning ,  Harald Kappesser

IPC: B01J31/24 ,  C07B61/00 ,  C07C45/50 ,  C07C51/235 ,  C07C53/126 ,  C07C53/128 ,  C07C69/22 ,  C07C69/33 ,  C10M105/32 ,  C10M105/34 ,  C10M105/38 ,  C10M171/00 ,  C10N40/30 ,  C10N70/00

CPC classification number: C10M171/008 ,  C07C45/50 ,  C07C53/126 ,  C07C53/128 ,  C10M105/38 ,  C10M2207/281 ,  C10M2207/282 ,  C10M2207/283 ,  C10M2207/286 ,  C10M2211/022 ,  C10M2211/06 ,  C10N2240/00 ,  C10N2240/22 ,  C10N2240/30 ,  C10N2240/50 ,  C10N2240/52 ,  C10N2240/54 ,  C10N2240/56 ,  C10N2240/58 ,  C10N2240/60 ,  C10N2240/66

Abstract: Isomeric mixtures of pentanoic acids are prepared by subjecting butene-1/butene-2 mixtures to hydroformylation to form aldehyde mixtures, followed by oxidation of the aldehyde mixtures which have been separated off from the reaction product. The hydroformylation is carried out in a heterogeneous system in the presence of rhodium catalysts which are dissolved in water. The mixture of isomeric 5 carbon monocarboxylic acids produced, when esterified with polyhydric alcohols, yields mixtures of isomeric esters which are useful as lubricants for refrigerant compressors operated with chlorine-free, at least partly fluorinated hydrocarbons as the refrigerant.

Abstract translation: 戊烯的异构混合物是通过使丁烯-1 /丁烯-2混合物进行加氢甲酰化形成醛混合物，然后氧化从反应产物中分离的醛混合物来制备的。 加氢甲酰化在异相体系中在溶解在水中的铑催化剂存在下进行。 当用多元醇酯化时，产生异构体5碳一元羧酸的混合物产生异构酯的混合物，其可用作用于无氯，至少部分氟化的烃作为制冷剂的制冷剂压缩机的润滑剂。

公开(公告)号：US4918247A

公开(公告)日：1990-04-17

申请号：US361711

申请日：1989-05-26

Applicant: Norbert Breitkopf ,  Wolfgang Hofs ,  Heinz Kalbfell ,  Franz Thonnessen ,  Peter Lappe ,  Helmut Springer

Inventor： Norbert Breitkopf ,  Wolfgang Hofs ,  Heinz Kalbfell ,  Franz Thonnessen ,  Peter Lappe ,  Helmut Springer

IPC: C07C29/38 ,  C07C29/80 ,  C07C45/75

CPC classification number: C07C29/80 ,  C07C29/38 ,  C07C45/75

Abstract: Preparation of 2,2-dimethylpropanediol-1,3 by the aldol addition of isobutyraldehyde and formaldehyde using tri-n-propylamine as a catalyst, followed by hydrogenation of the reaction mixture, and subsequent distillation of the hydrogenation product in the presence of isobutanol and water.

Abstract translation: 通过使用三正丙胺作为催化剂通过醛醇醛加成异丁醛和甲醛制备2,2-二甲基丙二醇-1,3-，随后氢化反应混合物，随后在异丁醇存在下蒸馏氢化产物， 水。

公开(公告)号：US4577043A

公开(公告)日：1986-03-18

申请号：US670357

申请日：1984-11-09

Applicant: Heinz Kalbfell ,  Bernhard Lieder ,  Herbert Mercamp

Inventor： Heinz Kalbfell ,  Bernhard Lieder ,  Herbert Mercamp

IPC: B01J31/00 ,  B01J31/24 ,  C07B61/00 ,  C07C45/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/00

CPC classification number: C07C45/50

Abstract: The preparation of aldehydes by the reaction of olefins with carbon monoxide and hydrogen in the presence of water and water-soluble rhodium/phosphine complex compounds as catalysts. The method comprises first cooling the organic part of the liquid phase to 70.degree. to 90.degree. C. in a stripping column by treatment with the carbon monoxide/hydrogen mixture fed into the reactor, further cooling the organic part to 20.degree. to 40.degree. C. by heat exchange with the feed olefin, subsequently relieving the pressure with the consequent formation of waste gas and aqueous and organic phases, and finally separating the phases so as to recover substantially all of the catalyst and the heat of reaction.

Abstract translation: 在水和水溶性铑/膦络合物作为催化剂存在下，通过烯烃与一氧化碳和氢气的反应制备醛类。 该方法包括首先在进料到反应器中的一氧化碳/氢气混合物处理后，在汽提塔中将液相的有机部分冷却至70〜90℃，再将有机部分冷却至20〜40℃ 通过与进料烯烃进行热交换，随后释放压力，从而形成废气和水相和有机相，最后分离相，以便基本上回收所有的催化剂和反应热。