Composition for optical materials and use thereof
    46.
    发明授权
    Composition for optical materials and use thereof 失效
    用于光学材料的组合物及其用途

    公开(公告)号:US5652321A

    公开(公告)日:1997-07-29

    申请号:US550352

    申请日:1995-10-30

    摘要: A composition for optical materials is herein disclosed which comprises the following two components (a) and (b):(a) a component containing at least one of poly isocyanates represented by the formula (1)A.paren open-st.S--B--NCO).sub.n (1)wherein A is an alkanediyl group or an alkanetetrayl group which may contain a sulfur atom, or a dithianetetrayl group, and the alkanediyl group or the alkanetetrayl group may be substituted by a phenyl group; B is a methylene chain represented by .paren open-st.CH.sub.2 .paren close-st..sub.m (m is an integer of 1 to 4) which may contain a sulfur atom, and B's may be the same or different; and n is an integer of 2 or 4, and(b) a component containing at least one of polythiols having two or more mercapto groups. The composition is useful to provide optical products such as plastic lenses, filters, substrates for recording media and optical fibers which have a very high refractive index and which are excellent in heat resistance.

    摘要翻译: 本文公开了用于光学材料的组合物,其包含以下两种组分(a)和(b):(a)含有由式(1)表示的聚异氰酸酯中的至少一种的组分A + 545 SB-NCO)n( 1)其中A是可以含有硫原子的烷二基或烷基四
    氮杂基团,或二硫代氨基甲酰基,并且烷二基或烷基四氮杂基可被苯基取代; B是可以含有硫原子的+545CH2 +546μm(m为1〜4的整数)表示的亚甲基,B可以相同或不同, n为2或4的整数,(b)含有具有两个以上巯基的多硫醇中的至少一种的成分。 该组合物可用于提供诸如塑料透镜,滤光器,用于记录介质的基底和具有非常高的折射率并且耐热性优异的光纤的光学产品。

    High refractive index plastic lens and composition therefor
    47.
    发明授权
    High refractive index plastic lens and composition therefor 失效
    高折射率塑料镜片及其组成

    公开(公告)号:US5306799A

    公开(公告)日:1994-04-26

    申请号:US95346

    申请日:1993-07-23

    摘要: The present invention discloses a composition for high refractive index plastic lens consisting of a monomer mixture wherein a particular aliphatic thiol compound is added to a polyisocyanate represented by general formula (1): ##STR1## wherein each X represents a hydrogen atom or a methyl group; each R represents a chlorine atom, a bromine atom, a methyl group or an ethyl group; m represents an integer of 0-4; and n represents an integer of 2-4, and a polythiol of formula (2): ##STR2## and a high refractive index plastic lens made of a urethane-containing resin obtained by polymerizing said composition.

    摘要翻译: 本发明公开了一种由单体混合物组成的高折射率塑料透镜组合物,其中将特定的脂族硫醇化合物加入由通式(1)表示的多异氰酸酯中:(*化学结构*)(1)其中每个X表示 氢原子或甲基; 每个R表示氯原子,溴原子,甲基或乙基; m表示0-4的整数; 和n表示2-4的整数,和式(2)的多硫醇:(*化学结构*)(2)和由通过聚合所述组合物获得的含氨基甲酸酯的树脂制成的高折射率塑料透镜。

    Alicyclic diamines, alicyclic diisocyanates and
polyisocyanato-isocyanurates and method for the preparation thereof
    48.
    发明授权
    Alicyclic diamines, alicyclic diisocyanates and polyisocyanato-isocyanurates and method for the preparation thereof 失效
    脂环族二胺,脂环族二异氰酸酯和多异氰酸酯 - 异氰脲酸酯及其制备方法

    公开(公告)号:US5210286A

    公开(公告)日:1993-05-11

    申请号:US866551

    申请日:1992-04-10

    摘要: Herein disclosed are an .alpha.-(aminocyclohexyl)alkylamine represented by the following general formula (II): ##STR1##wherein R represents hydrogen atom or a lower alkyl group having 1 to 5 carbon atoms, provided that the amino group bonded to the cyclohexyl group may be in either of the 2-, 3- and 4-positions and a method for preparing it; an .alpha.-(isocyanatocyclohexyl)alkylisocyanate of Formula (II) wherein the amino groups are replaced with isocyanato groups and a method for preparing it; polyisocyanato-isocyanurate represented by the following general formula (IV): ##STR2##wherein R.sub.1, R.sub.2 and R.sub.3 may be the same or different and each represents a group represented by the following general formula: ##STR3##wherein R represents hydrogen atom or an alkyl group having 1 to 5 carbon atoms and n is an integer ranging from 1 to 5 and a method for preparing it; and a resin obtained by polymerizing an organic polyisocyanate containing not lower than 10% by weight of the polyisocyanato-isocyanurate represented by Formula (IV) and a compound having at least two active hydrogen atoms as well as a resin composition for coating materials which comprises the resin.

    摘要翻译: 本文公开的是由以下通式(II)表示的α-(氨基环己基)烷基胺:其中R表示氢原子或具有1至5个碳原子的低级烷基,条件是与 环己基可以在2-,3-和4-位中的任一个和其制备方法; 其中氨基被异氰酸酯基取代的式(II)的α-(异氰酸根合环己基)烷基异氰酸酯及其制备方法; 由下列通式(IV)表示的多异氰酸酯 - 异氰脲酸酯:其中R 1,R 2和R 3可以相同或不同,并且各自表示由以下通式表示的基团:其中R表示氢 原子或碳原子数为1〜5的烷基,n为1〜5的整数,及其制备方法。 和通过使由式(IV)表示的多异氰酸酯基 - 异氰脲酸酯的10重量%以上的有机多异氰酸酯和具有至少2个活性氢原子的化合物以及用于涂料的树脂组合物聚合而得到的树脂,其包含 树脂。