公开(公告)号：US20130071733A1

公开(公告)日：2013-03-21

申请号：US13701193

申请日：2011-06-03

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Shoji Shikita ,  Kei Shimamoto

IPC分类号： H01M10/0566

CPC分类号： H01M10/0567 ,  H01G11/58 ,  H01M10/052 ,  H01M10/0566 ,  H01M10/0569 ,  H01M2300/0025 ,  Y02E60/122 ,  Y02E60/13 ,  Y02T10/7011 ,  Y02T10/7022

摘要： The present invention provides a nonaqueous electrolytic solution which can improve the electrochemical characteristics in a broad temperature range, an electrochemical element produced by using the same and a sulfonic ester compound having a branched structure which is used for the same.The present invention relates to a nonaqueous electrolytic solution prepared by dissolving an electrolyte salt in a nonaqueous solvent, which comprises a sulfonic ester compound represented by the following Formula (I) in an amount of 0.001 to 5% by mass of the nonaqueous electrolytic solution: (wherein R represents an alkyl group or an aryl group; A represents a >CH group or a >SiZ group (Z represents an alkyl group or an aryl group); X represents an alkyl group, a cycloalkyl group or an aryl group; Y represents a cycloalkyl group, a -L1CHRaOSO2Rb group or a —Si(Rc)(Rd)OSO2Rb group; W represents 1 or 2; Ra represents an alkyl group; Rb, Rc and Rd represent an alkyl group or an aryl group; L1 represents an alkylene group in which at least one hydrogen atom may be substituted with —OSO2Re (Re has the same meaning as that of R), a divalent linkage group containing at least one ether bond or a single bond).

摘要翻译： 本发明提供一种可以提高宽温度范围内的电化学特性的非水电解液，使用该电解质的电化学元件和具有分支结构的磺酸酯化合物。 本发明涉及通过将电解质盐溶解在非水溶剂中而制备的非水电解液，该非水溶剂包含以下式（I）表示的磺酸酯化合物：非水电解液的0.001〜5质量％ （其中R表示烷基或芳基; A表示> CH基或> SiZ基（Z表示烷基或芳基）; X表示烷基，环烷基或芳基; Y 表示环烷基，-L1CHRaOSO2Rb基或-Si（Rc）（Rd）OSO2Rb基; W表示1或2; Ra表示烷基; Rb，Rc和Rd表示烷基或芳基; L1表示 其中至少一个氢原子可以被-OSO 2 Re取代的亚烷基（Re具有与R相同的含义），含有至少一个醚键或单键的二价连接基团）。

公开(公告)号：US07781106B2

公开(公告)日：2010-08-24

申请号：US10567902

申请日：2004-08-09

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata ,  Yasuo Matsumori

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata ,  Yasuo Matsumori

IPC分类号： H01M6/16

CPC分类号： H01M6/16 ,  H01M4/131 ,  H01M4/133 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

摘要： The invention provides a lithium secondary battery which is excellent in long-term cycle property and in battery characteristics, such as electric capacity and storage property, and a nonaqueous electrolytic solution usable for such a lithium secondary battery. The present invention relates to a lithium secondary battery including a positive electrode, a negative electrode, and a nonaqueous electrolytic solution containing an electrolyte salt dissolved in a nonaqueous solvent, characterized in that the positive electrode is made of a material including a lithium compound oxide, in that the negative electrode is made of a material including graphite, and in that the nonaqueous electrolytic solution contains dialkyl oxalate and further contains vinylene carbonate and/or 1,3-propanesultone, and a nonaqueous electrolytic solution for use in such a battery.

摘要翻译： 本发明提供一种锂电池，该锂二次电池具有优异的长期循环性能和电容特性以及蓄电性等电池特性，以及可用于这种锂二次电池的非水电解液。 本发明涉及一种锂二次电池，其包括正极，负极和含有溶解在非水溶剂中的电解质盐的非水电解液，其特征在于，所述正极由包含锂复合氧化物的材料制成， 由于负极由包括石墨的材料制成，并且非水电解液含有草酸二烷基酯，还含有碳酸亚乙烯酯和/或1,3-丙磺酸内酯，以及用于这种电池的非水电解液。

公开(公告)号：US07550233B2

公开(公告)日：2009-06-23

申请号：US10472202

申请日：2002-03-22

申请人： Koji Abe ,  Motoki Yuguchi ,  Yasuo Matsumori ,  Kazuhiro Miyoshi

发明人： Koji Abe ,  Motoki Yuguchi ,  Yasuo Matsumori ,  Kazuhiro Miyoshi

IPC分类号： H01M6/16

CPC分类号： H01M10/0567 ,  H01M2/0222 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/4235 ,  H01M2300/0037 ,  H01M2300/004

摘要： A non-aqueous electrolytic solution containing a ketone compound having the formula (I): in which each of R1 and R2 is linear or branched alkyl; and each of R3, R4, R5 and R6 is hydrogen or linear or branched alkyl; however, R1 and R4 can be combined to form a cycloalkanone ring in conjunction with a propanone skeleton to which R1 and R4 are connected, and two or more of alkyl of R2, alkyl of R5, a branched chain of alkyl of R1, and a branched chain of alkyl of R4 can be combined to form a cycloalkane ring, or alkyl of R1 and alkyl of R2 and/or alkyl of R4 and alkyl of R5 can be combined to each other to form a cycloalkane ring, is favorably employed for manufacturing a lithium secondary battery that is excellent in the battery performances and cycle performance.

摘要翻译： 含有具有式（I）的酮化合物的非水电解液：其中R1和R2各自为直链或支链烷基; R3，R4，R5和R6各自为氢或直链或支链烷基; 然而，R1和R4可以与R1和R4连接的丙酮骨架结合形成环烷酮环，R2和R2的烷基，R5的烷基，R1的烷基支链和 可以将R4的烷基的支链结合形成环烷烃环，或者R 1的烷基和R 2的烷基和/或R 4的烷基和/或R 5的烷基可以相互结合形成环烷烃环，有利地用于制造 具有优异的电池性能和循环性能的锂二次电池。

公开(公告)号：US20070231707A1

公开(公告)日：2007-10-04

申请号：US11597652

申请日：2005-05-30

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata

IPC分类号： H01M10/40

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/133 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0567 ,  H01M2300/004

摘要： A nonaqueous electrolytic solution for a lithium secondary battery, in which 0.01 to 10 wt. % of a sulfur-containing acid ester and 0.01 to 10 wt. % of a triple bond-containing compound are dissolved in a nonaqueous solvent, and a lithium secondary battery employing the nonaqueous electrolytic solution.

摘要翻译： 一种锂二次电池用非水电解液，其中，0.01〜10重量％ ％的含硫酸酯和0.01〜10wt。 将含三价键的化合物的％溶解在非水溶剂中，使用该非水电解液的锂二次电池。

公开(公告)号：US20060246356A1

公开(公告)日：2006-11-02

申请号：US10567902

申请日：2004-08-09

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata ,  Yasuo Matsumori

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Takaaki Kuwata ,  Yasuo Matsumori

IPC分类号： H01M10/40 ,  H01M4/58 ,  H01M4/48

CPC分类号： H01M6/16 ,  H01M4/131 ,  H01M4/133 ,  H01M4/485 ,  H01M4/505 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0525 ,  H01M10/0567 ,  H01M10/0568 ,  H01M10/0569

摘要： The invention provides a lithium secondary battery which is excellent in long-term cycle property and in battery characteristics, such as electric capacity and storage property, and a nonaqueous electrolytic solution usable for such a lithium secondary battery. The present invention relates to a lithium secondary battery including a positive electrode, a negative electrode, and a nonaqueous electrolytic solution containing an electrolyte salt dissolved in a nonaqueous solvent, characterized in that the positive electrode is made of a material including a lithium compound oxide, in that the negative electrode is made of a material including graphite, and in that the nonaqueous electrolytic solution contains dialkyl oxalate and further contains vinylene carbonate and/or 1,3-propanesultone, and a nonaqueous electrolytic solution for use in such a battery.

摘要翻译： 本发明提供一种锂电池，该锂二次电池具有优异的长期循环性能和电容特性以及蓄电性等电池特性，以及可用于这种锂二次电池的非水电解液。 本发明涉及一种锂二次电池，其包括正极，负极和含有溶解在非水溶剂中的电解质盐的非水电解液，其特征在于，所述正极由包含锂复合氧化物的材料制成， 由于负极由包括石墨的材料制成，并且非水电解液含有草酸二烷基酯，还含有碳酸亚乙烯酯和/或1,3-丙磺酸内酯，以及用于这种电池的非水电解液。

公开(公告)号：US20060166096A1

公开(公告)日：2006-07-27

申请号：US10563124

申请日：2005-02-18

申请人： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

发明人： Koji Abe ,  Kazuhiro Miyoshi ,  Yasufumi Takahashi ,  Hiroyuki Fujimoto ,  Akira Kinoshita ,  Shingo Tode ,  Ikuro Nakane ,  Shin Fujitani

IPC分类号： H01M4/58 ,  H01M4/52 ,  H01M10/40

CPC分类号： H01M10/0525 ,  H01M4/131 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M10/0567 ,  H01M10/0569 ,  H01M2010/4292 ,  H01M2300/0025

摘要： A nonaqueous electrolyte secondary battery including a negative electrode containing a graphite material as the negative active material, a positive electrode containing lithium cobalt oxide as a main component of the positive active material and a nonaqueous electrolyte solution, the battery being characterized in that the lithium cobalt oxide contains a group IVA element and a group IIA element of the periodic table, the nonaqueous electrolyte solution contains 0.2-1.5% by weight of a sulfonyl-containing compound and preferably further contains 0.5-4% by weight of vinylene carbonate.

摘要翻译： 包含含有作为负极活性物质的石墨材料的负极，含有钴酸锂作为正极活性物质的主要成分的正极和非水电解液的非水电解质二次电池，其特征在于，所述锂钴 氧化物含有元素周期表IVA族元素和IIA族元素，非水电解质溶液含有0.2-1.5重量％的含磺酰基化合物，优选还含有0.5-4重量％的碳酸亚乙烯酯。

公开(公告)号：US09371268B2

公开(公告)日：2016-06-21

申请号：US13061329

申请日：2009-08-31

申请人： Koji Abe ,  Akikazu Ito

发明人： Koji Abe ,  Akikazu Ito

IPC分类号： C07C69/96 ,  C07C68/00

CPC分类号： C07C68/00 ,  C07C69/96

摘要： An asymmetric chain carbonate can be produced in a single-step reaction comprising a step of reacting methyl nitrite, carbon monoxide, and 0.05-1.5 moles of an aliphatic alcohol having 2-6 carbon atoms or an alicyclic alcohol having 5-6 carbon atoms per one mole of methyl nitrile in a gaseous phase in the presence of a solid catalyst comprising a platinum group metal or a compound thereof placed on a support.

摘要翻译： 可以在单步反应中制备不对称链碳酸酯，其包括使亚硝酸甲酯，一氧化碳和0.05-1.5摩尔具有2-6个碳原子的脂族醇或具有5-6个碳原子的脂环族醇反应的步骤 在含有铂族金属或其化合物的固体催化剂存在下，在气相中加入1摩尔甲基腈。

公开(公告)号：US09364400B2

公开(公告)日：2016-06-14

申请号：US14002124

申请日：2012-08-09

申请人： Yosuke Ikebe ,  Koji Abe

发明人： Yosuke Ikebe ,  Koji Abe

IPC分类号： A61Q17/04 ,  A61K8/06 ,  A61K8/895 ,  A61K8/81 ,  A61K8/894 ,  A61K8/02

CPC分类号： A61K8/064 ,  A61K8/0254 ,  A61K8/8152 ,  A61K8/894 ,  A61K8/895 ,  A61K2800/612 ,  A61Q17/04

摘要： The present invention provides a water-in-oil emulsified sunscreen cosmetic characteristically comprising the following (a) through (g): (a) Ultraviolet absorbent (b) Silicone backbone powder (c) Methyl polymethacrylate powder (d) Hydrophobicized platelike powder (e) Surfactant (f) Oil component (g) Water The object of the present invention is to provide a water-in-oil emulsified sunscreen cosmetic that manifests a superior texture during use, a high ultraviolet protection effect, and superior stability.

摘要翻译： 本发明提供一种油包水乳化防晒化妆品，其特征在于包括以下（a）至（g）：（a）紫外线吸收剂（b）硅酮骨架粉末（c）聚甲基丙烯酸甲酯粉末（d）疏水性扁平粉末 ）表面活性剂（f）油成分（g）水本发明的目的是提供一种油包水乳化防晒化妆品，其在使用中表现出优异的质地，高的紫外线防护效果和优异的稳定性。

公开(公告)号：US09236635B2

公开(公告)日：2016-01-12

申请号：US14237492

申请日：2012-08-07

申请人： Koji Abe ,  Kei Shimamoto

发明人： Koji Abe ,  Kei Shimamoto

IPC分类号： H01M10/0567 ,  H01M10/0569 ,  H01M10/0525 ,  H01M4/131 ,  H01M4/505 ,  H01M4/52 ,  H01M4/58 ,  H01M4/583 ,  H01M4/38 ,  H01M4/485 ,  C07C309/65 ,  H01M10/052 ,  C07C69/65 ,  C07D327/00 ,  H01M10/0568

CPC分类号： H01M10/0567 ,  C07C69/65 ,  C07C309/65 ,  C07D327/00 ,  H01M4/13 ,  H01M4/131 ,  H01M4/386 ,  H01M4/387 ,  H01M4/485 ,  H01M4/505 ,  H01M4/52 ,  H01M4/525 ,  H01M4/5825 ,  H01M4/583 ,  H01M4/587 ,  H01M10/052 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  Y02E60/122 ,  Y02T10/7011

摘要： The present invention provides a nonaqueous electrolytic solution capable of improving electrochemical characteristics in a broad temperature range, such as low-temperature cycle properties and low-temperature discharge properties after high-temperature storage, and provides an energy storage device using the nonaqueous electrolytic solution. The invention includes (1) a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, which comprises from 0.001 to 10% by mass of a compound represented by the following general formula (I), and (2) an energy storage device comprising a positive electrode, a negative electrode, and a nonaqueous electrolytic solution of an electrolyte salt dissolved in a nonaqueous solvent, wherein the nonaqueous electrolytic solution is the nonaqueous electrolytic solution of (1). (In the formula, Y represents a group —C(═O)— or a group —S(═O)2—; R3 and R4 each independently represent an aryl group having from 6 to 10 carbon atoms in which at least one hydrogen atom is substituted with a halogen atom, or R3 and R4 bonding to each other represent a cycloalkanediyl group or a benzenediyl group, having from 5 to 12 carbon atoms. R represents —C(R1)(R2)— or -L-; R1 and R2 each independently represent a hydrogen atom, a halogen atom, or an alkyl group having from 1 to 4 carbon atoms; and L represents a divalent linking group having from 1 to 6 carbon atoms and optionally substituted with a halogen atom).

摘要翻译： 本发明提供一种能够在高温保存后的低温循环特性和低温放电性等宽温度范围内提高电化学特性的非水电解液，提供使用该非水电解液的储能装置。 本发明包括（1）溶解在非水溶剂中的电解质盐的非水电解液，其含有0.001〜10质量％的下述通式（I）表示的化合物，和（2）能量储存装置 包括正极，负极和溶解在非水溶剂中的电解质盐的非水电解液，其中非水电解液是（1）的非水电解液。 （在该式中，Y表示基团-C（= O） - 或基团-S（= O）2 - ; R 3和R 4各自独立地表示具有6至10个碳原子的芳基，其中至少一个氢 原子被卤素原子取代，或者R 3和R 4彼此键合表示具有5至12个碳原子的环烷二基或苯二基，R表示-C（R 1）（R 2） - 或-L-; R 1 和R 2各自独立地表示氢原子，卤素原子或具有1〜4个碳原子的烷基; L表示具有1〜6个碳原子并且任选被卤素原子取代的二价连接基团）。

公开(公告)号：US08948652B2

公开(公告)日：2015-02-03

申请号：US13426756

申请日：2012-03-22

申请人： Koji Abe

发明人： Koji Abe

IPC分类号： G03G21/18

CPC分类号： G03G15/0194 ,  G03G21/1619 ,  G03G21/1676 ,  G03G2215/0141 ,  G03G2221/1684

摘要： In an image forming apparatus, photosensitive bodies are mounted in a first frame. Developing units are detachably mounted in the first frame. A second frame is movable relative to the first frame. Each developing unit is movable relative to the first frame between a separate position, at which a developing roller is separate from a photosensitive body, and a contact position, at which the developing roller is in contact with the photosensitive body. The second frame moves relative to the first frame, thereby moving the developing units relative to the first frame between the separate positions and the contact positions. The second frame positions each developing unit relative to the first frame in a direction to move the developing roller toward the corresponding photosensitive body when the developing unit is in the contact position.

摘要翻译： 在图像形成装置中，感光体安装在第一框架中。 显影单元可拆卸地安装在第一框架中。 第二框架可相对于第一框架移动。 每个显影单元可以在显影辊与感光体分开的分离位置与显影辊与感光体接触的接触位置之间相对于第一框架移动。 第二框架相对于第一框架移动，从而相对于第一框架在分开的位置和接触位置之间移动显影单元。 当显影单元处于接触位置时，第二框架在使显影辊朝向相应感光体的方向上相对于第一框架定位每个显影单元。