Abstract:
Disclosed is a method for preparing a carbon-supported platinum-transition metal alloy nanoparticle catalyst using a stabilizer. According to the method, the transition metal on the nanoparticle surface and the stabilizer are simultaneously removed by treatment with acetic acid. Therefore, the method enables the preparation of a carbon-supported platinum-transition metal alloy nanoparticle catalyst in a simple and environmentally friendly manner compared to conventional methods. The carbon-supported platinum-transition metal alloy nanoparticle catalyst can be applied as a high-performance, highly durable fuel cell catalyst.
Abstract:
The present disclosure relates to an IrO2 electrodeposited porous titanium composite layer of a polymer electrolyte membrane water electrolysis apparatus serving as both a diffusion layer and an oxygen electrode, the apparatus including: a porous titanium (Ti) layer; and an electrodeposited iridium oxide (IrO2) layer on the porous Ti layer. The IrO2 layer may be uniformly deposited on a porous Ti layer through an electrolysis process, and the electrodeposited IrO2 layer may play multiple roles as not only a catalyst layer toward oxygen evolution reaction (OER) on the surface of the Ti layer, but also a corrosion-protection layer which prevents an inner Ti layer from corrosion.
Abstract:
Disclosed is a method for preparing a carbon-supported metal oxide and/or alloy nanoparticle catalyst. According to the method, a carbon-supported metal oxide and/or alloy nanoparticle catalyst is prepared by depositing metal oxide and/or alloy nanoparticles on a water-soluble support and dissolving the metal oxide and/or alloy nanoparticles deposited on the water-soluble support in an anhydrous polar solvent containing carbon dispersed therein to support the metal oxide and/or alloy nanoparticles on the carbon. The anhydrous polar solvent has much lower solubility for the water-soluble support than water and is used to dissolve the water-soluble support. The use of the anhydrous polar solvent instead of water can prevent the water-soluble support present at a low concentration in the solution from impeding the support of the nanoparticles on the carbon, thus providing a solution to the problems of environmental pollution, high cost, and complexity encountered in conventional chemical and physical synthetic methods.
Abstract:
Disclosed are a perovskite compound, a method for producing the perovskite compound, a catalyst for a fuel cell including the perovskite compound, and a method for producing the catalyst. The perovskite compound overcomes the low stability of palladium due to its perovskite structural properties. Therefore, the perovskite compound can be used as a catalyst material for a fuel cell. In addition, the use of palladium in the catalyst instead of expensive platinum leads to an improvement in the price competitiveness of fuel cells. The catalyst is highly durable and catalytically active due to its perovskite structure.
Abstract:
A catalyst containing a carbon support and a core-shell nanoparticle supported on the carbon support, wherein a core of the core-shell nanoparticle is cobalt metal not containing a heterogeneous element and the shell contains carbon. The catalyst for an oxygen reduction reaction of the present disclosure is a catalyst in which the cobalt core-carbon shell nanoparticle is supported on the carbon support through ligand stabilization and heat treatment. The catalyst can be synthesized to have high dispersibility. In particular, it can be used as an electrode catalyst of a cathode to improve the oxygen reduction activity and durability of a fuel cell operating under an alkaline atmosphere.
Abstract:
Provided is a composite polymer electrolyte membrane for a fuel cell, including: a porous fluorinated polymer support; and a perfluorinated sulfonic acid polymer resin membrane which fills the inside of pores of the porous fluorinated polymer support and covers an external surface of the porous fluorinated polymer support.
Abstract:
Provided is a catalyst for oxygen reduction reaction comprising an alloy comprising at least one selected from Pt, Pd and Ir supported on a carbon carrier functionalized with poly(N-isopropylacrylamide) (PNIPAM). The catalyst for oxygen reduction reaction has electronic ensemble effects by virtue of the carbon carrier functionalized with poly(N-isopropylacrylamide) (PNIPAM), and thus shows improved oxygen reduction activity and durability as compared to conventional catalysts supported on carbon.
Abstract:
Disclosed is a catalyst filter, which includes a catalyst support and a nano metallic catalyst sprayed to a surface of the catalyst support. The catalyst filter uses catalyst slurry prepared by using a particulate catalyst, in which a small amount of nano metallic catalyst exhibiting a catalyst performance is sprayed to a surface of the catalyst support, different from an existing patent technique in which catalyst particles are formed and prepared as a support to consume a large amount of catalyst. Therefore, the specific surface area of the catalyst filter is not smaller than the specific surface area of the nano catalyst particles, and thus the catalyst filter may effectively remove and decompose ultra-low concentration gas-state contaminants in an indoor air.
Abstract:
Provided are a method for preparing a Nafion membrane having a through-pore free monolithic porous structure throughout the bulk of the membrane through a one-step process very easily and a Nafion membrane having a through-pore free monolithic porous structure obtained from the method. The Nafion membrane having such a porous structure may have an increased surface area, and thus may improve the membrane/catalyst interfacial area and transport characteristics.
Abstract:
Disclose is a triphenylamine derivative with a low band gap. The triphenylamine derivative is represented by Formula (I): wherein R1 and Ar are as defined in the specification. Further disclosed is a high efficiency organic photovoltaic cell using the derivative.