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41.发明申请THERMOPLASTIC COMPOSITIONS, METHODS OF MAKING, AND ARTICLES FORMED THEREFROM 审中-公开热塑性组合物，制备方法和形成的制品公开(公告)号：US20080081892A1
公开(公告)日：2008-04-03
申请号：US11537021
申请日：2006-09-29
Applicant: Jianbo Di , Brian D. Mullen , Paul D. Sybert
Inventor： Jianbo Di , Brian D. Mullen , Paul D. Sybert
IPC: C08G77/04
CPC classification number: C08G77/448 , C08G63/64 , C08G64/14 , C08L53/02 , C08L55/02 , C08L2666/02 , C08L2666/14
Abstract: A thermoplastic composition comprises a polycarbonate having repeating structural carbonate units of the formula (1): wherein at least 60 percent of the total number of R1 groups contain aromatic organic groups and the balance thereof are aliphatic, alicyclic, or aromatic groups; and wherein the polycarbonate comprises terminal groups derived from reaction with a cyanophenol of the formula wherein Y is a halogen, C1-3 alkyl group, C1-3 alkoxy group, C7-12 arylalkyl, C7-12 alkylaryl, or nitro group, y is 0 to 4, and c is 1 to 5, provided that y+c is 1 to 5; and a flame retardant. The compositions are useful in the manufacture of a wide variety of parts, particularly those having a thin wall.
Abstract translation: 热塑性组合物包含具有式（1）的重复结构碳酸酯单元的聚碳酸酯：其中R 1〜2个基团的总数的至少60％含有芳族有机基团，其余为脂肪族，脂环族 或芳族基团; 并且其中所述聚碳酸酯包含衍生自下式的氰基苯酚的端基：其中Y是卤素，C 1-3烷基，C 1-3烷氧基， C 7-12-12芳烷基，C 7-12烷基芳基或硝基，y为0至4，c为1至5，条件是y + c为1 至5; 和阻燃剂。 组合物可用于制造各种各样的部件，特别是具有薄壁的部件。
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42.发明授权公开(公告)号：US07326764B2
公开(公告)日：2008-02-05
申请号：US11263516
申请日：2005-10-31
Applicant: Jianbo Di , Brian D. Mullen , Paul D. Sybert
Inventor： Jianbo Di , Brian D. Mullen , Paul D. Sybert
IPC: C08G63/02
CPC classification number: C08G64/42 , C08G63/64 , C08L69/005 , C08L2666/18 , C08L69/00
Abstract: A reaction product comprises a first polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, a second polyester-polycarbonate comprising a polyester unit and a polycarbonate unit, and a transesterification catalyst. The reaction product has a haze of less than 1.7%, specifically less than 1.0% as measured at a thickness of 3.2 mm according to ASTM D1003-00. A thermoplastic composition comprising the reaction product and articles formed from therefrom are disclosed. A method of forming the reaction product is also disclosed.
Abstract translation: 反应产物包括包含聚酯单元和聚碳酸酯单元的第一聚酯 - 聚碳酸酯，包含聚酯单元和聚碳酸酯单元的第二聚酯 - 聚碳酸酯和酯交换催化剂。 根据ASTM D1003-00，反射产物的雾度小于1.7％，特别是小于1.0％，其厚度为3.2mm。 公开了一种包含反应产物和由其形成的制品的热塑性组合物。 还公开了形成反应产物的方法。
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43.发明授权公开(公告)号：US07321014B2
公开(公告)日：2008-01-22
申请号：US11025249
申请日：2004-12-29
Applicant: Katherine Glasgow , Brian Mullen , Paul D. Sybert
Inventor： Katherine Glasgow , Brian Mullen , Paul D. Sybert
CPC classification number: C08L83/10 , C08G63/64 , C08G77/445 , C08G77/448
Abstract: A thermoplastic composition is disclosed, comprising the reaction product of: a polyester polycarbonate comprising a polyester unit and a polycarbonate unit; a polysiloxane polycarbonate copolymer having a haze of 30% or less, comprising a polycarbonate unit and a polysiloxane unit; and a transesterification catalyst. The resulting thermoplastic composition has a haze of 30% or less as measured according to ASTM D1003-00 at a thickness of 3.2 millimeters. A method of forming the composition and articles formed from the composition are also disclosed.
Abstract translation: 公开了一种热塑性组合物，其包含以下反应产物：包含聚酯单元和聚碳酸酯单元的聚酯聚碳酸酯; 具有30％以下的雾度的聚硅氧烷聚碳酸酯共聚物，其包含聚碳酸酯单元和聚硅氧烷单元; 和酯交换催化剂。 所得热塑性组合物的雾度为30％以下，根据ASTM D1003-00测定，厚度为3.2毫米。 还公开了形成由组合物形成的组合物和制品的方法。
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公开(公告)号：US06627303B1
公开(公告)日：2003-09-30
申请号：US10348064
申请日：2003-01-17
Applicant: Robert R. Gallucci , Xiangyang Li , Paul D. Sybert
Inventor： Robert R. Gallucci , Xiangyang Li , Paul D. Sybert
IPC: C08L6900
CPC classification number: C08K7/02 , C08K7/14 , Y10T428/24942 , Y10T428/31507 , Y10T428/31565
Abstract: Articles made from a thermoplastic resin composition comprising a high modulus fiber and a resorcinol polyester or resorcinol polyester carbonate resin showing high strength and stiffness along with surprisingly good retention of gloss and color when exposed to weathering.
Abstract translation: 由包含高模量纤维和间苯二酚聚酯或间苯二酚聚酯碳酸酯树脂的热塑性树脂组合物制成的物品显示出高强度和刚度，同时暴露于风化时具有惊人的良好的光泽和颜色保留性。
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公开(公告)号：US5510449A
公开(公告)日：1996-04-23
申请号：US241306
申请日：1994-05-10
Applicant: Larry I. Flowers , Paul D. Sybert , David L. Ramsey
Inventor： Larry I. Flowers , Paul D. Sybert , David L. Ramsey
Abstract: A method is provided for making polycarbonates utilizing an effective amount of a binary phase transfer catalyst, such as tetrabutylammonium bromide and a methyl tertiary amine as a condensation catalyst during the interfacial phosgenation of a bisphenol, such as bisphenol A. Improved phosgene utilization is achieved.
Abstract translation: 提供了一种在双酚（例如双酚A）的界面光气化期间利用有效量的二元相转移催化剂如四丁基溴化铵和甲基叔胺作为缩合催化剂制备聚碳酸酯的方法。改善了光气利用率。
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Patent Agency Ranking
公开(公告)号：US5135990A
公开(公告)日：1992-08-04
申请号：US593453
申请日：1990-10-05
Applicant: Dana C. Bookbinder , Paul D. Sybert
Inventor： Dana C. Bookbinder , Paul D. Sybert
Abstract: Improved blends of polyetherimide/liquid crystalline polymer are provided. The blends are obtained by melt blending amine terminated polyetherimide resin with liquid crystalline polyester resins and exhibit improved levels of tensile strength compared to blends of phthalic anhydride capped polyetherimide resin with liquid crystalline polyester resin. The blends are useful as molding compositions.
Abstract translation: 提供改进的聚醚酰亚胺/液晶聚合物的共混物。 通过将胺封端的聚醚酰亚胺树脂与液晶聚酯树脂熔融共混获得共混物，与邻苯二甲酸酐封端的聚醚酰亚胺树脂与液晶聚酯树脂的共混物相比，显示出提高的拉伸强度水平。 共混物可用作模塑组合物。
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公开(公告)号：US4950782A
公开(公告)日：1990-08-21
申请号：US286827
申请日：1988-12-20
Applicant: Daniel W. Fox , Edward N. Peters , Paul D. Sybert
Inventor： Daniel W. Fox , Edward N. Peters , Paul D. Sybert
Abstract: Polycarbonate resins are chain-terminated with a group selected from those of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group consisting of hydrogen, halogen, hydrocarbyl of from 1 to 12 carbon atoms, inclusive; and halogen-substituted hydrocarbyl of 1 to 12 carbon atoms, inclusive; R.sub.1 is attached to a ring carbon atom at one of the 4, 5 or 6 positions; and R.sub.2 and R.sub.3 when taken together represent the divalent moiety of formula: --CH.dbd.CH.sub.2 --CH.sub.2 .dbd.CH--which effectively creates an additional fused aromatic ring structure. The resins exhibit a low plate-out when processed thermally.
Abstract translation: 聚碳酸酯树脂用选自下式的基团链终止：其中R 1，R 2和R 3各自独立地选自氢，卤素，含1至12个碳原子的烃基; 和含有1至12个碳原子的卤素取代的烃基; 在4-5个或6个位置的R1连接到环碳原子上; 并且R 2和R 3一起表示式：-CH = CH 2 -CH 2 = CH-的二价部分，其有效地产生另外的稠合芳环结构。 当热处理时，树脂表现出低的平板。
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48.发明授权
公开(公告)号：US4845160A
公开(公告)日：1989-07-04
申请号：US152509
申请日：1988-02-05
Applicant: Paul D. Sybert
Inventor： Paul D. Sybert
CPC classification number: C08L67/00 , C08G63/66 , C08G81/00 , C08L71/126 , C08L71/12
Abstract: Polyphenylene ether-polyester copolymers, useful for compatibilizing blends of polyphenylene ethers with polyesters such as poly(alkylene terephthalates), are prepared by heating a polyphenylene ether with a polyester containing olefinic structural units, such as those derived from maleic or fumaric acid.
Abstract translation: 通过用含有烯属结构单元的聚酯，如衍生自马来酸或富马酸的聚酯加热聚苯醚，可制备聚苯醚与聚酯如聚（对苯二甲酸亚烷基酯）的相容性共混物的聚苯醚 - 聚酯共聚物。
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公开(公告)号：US4841015A
公开(公告)日：1989-06-20
申请号：US136664
申请日：1987-12-22
Applicant: Daniel W. Fox , Edward N. Peters , Paul D. Sybert
Inventor： Daniel W. Fox , Edward N. Peters , Paul D. Sybert
Abstract: Polycarbonate resins are chain-terminated with a group selected from those of the formula: ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 are each independently selected from the group consisting of hydrogen, halogen, hydrocarbyl of from 1 to 12 carbon atoms, inclusive; and halogen-substituted hydrocarbyl of 1 to 12 carbon atoms, inclusive; R.sub.1 is attached to a ring carbon atom at one of the 4, 5 or 6 positions; and R.sub.2 and R.sub.3 when taken together represent the divalent moiety of formula:--CH.dbd.CH.sub.2 --CH.sub.2 .dbd.CH--which effectively creates an additional fused aromatic ring structure. The resins exhibit a low plate-out when processed thermally.
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公开(公告)号：US4533693A
公开(公告)日：1985-08-06
申请号：US616469
申请日：1983-09-15
Applicant: James F. Wolfe , Paul D. Sybert , Joanne R. Sybert
Inventor： James F. Wolfe , Paul D. Sybert , Joanne R. Sybert
CPC classification number: C09K19/3823 , C08G73/18 , C08G75/32 , C08G85/00 , C08L57/00
Abstract: Novel compositions comprising a high concentration of one or more extended chain homopolymer, copolymer, or block polymer and certain polyphosphoric acids are prepared. Such compositions are optically anisotropic (liquid crystalline), capable of exhibiting excellent cohesive strength, and are especially suited to the production of high molecular weight ordered polymer fibers by dry-jet wet spinning. These liquid crystalline compositions are capable of being drawn through long air gap distances and spun at exceptionally high spin draw ratios. Fibers, films and other articles formed from these liquid crystalline compositions exhibit exceptionally high physical and heat resistant properties.
Abstract translation: PCT No.PCT / US83 / 01437第 371日期1983年9月15日 102（e）日期1983年9月15日PCT提交1983年9月15日PCT公布。 公开号WO84 / 01162 日期为1984年3月29日。制备包含高浓度一种或多种延伸链均聚物，共聚物或嵌段聚合物和某些多磷酸的新型组合物。 这种组合物是光学各向异性（液晶），能够表现出优异的内聚强度，并且特别适用于通过干喷湿法纺丝生产高分子量有序聚合物纤维。 这些液晶组合物能够通过长的气隙距离被拉伸并以非常高的旋转拉伸比旋转。 由这些液晶组合物形成的纤维，薄膜和其它制品表现出极高的物理和耐热性能。
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