摘要:
A polymer comprises at least one methacrylamide functional group on the average per polymer molecule, which polymer comprises the reaction product of at least one hydroxy functional polymer with at least one isopropenyl azlactone in the presence of an acidic catalyst, said hydroxy functional polymer having a number average molecular weight above 20,000.
摘要:
Azlactone-functional polymer beads are useful reactive supports for the attachment of functional materials to provide novel adduct beads. The adduct beads are useful as complexing agents, catalysts, reagents, and as enzyme or other protein-bearing supports. Novel carboxylate-functional polymer beads, are intermediates in the preparation of the azlactone-functional beads.Azlactone-functional beads have units of the formula: ##STR1## wherein R.sup.1 is H or CH.sub.3,R.sup.2 and R.sup.3 independently can be an alkyl group having 1 to 14 carbon atoms, a cycloalkyl group having 3 to 14 carbon atoms, an aryl group having 5 to 12 ring atoms, an arenyl group having 6 to 26 carbon and 0 to 3 S, N, and nonperoxidic O heteroatoms, or R.sup.1 and R.sup.3 taken together with the carbon to which they are joined can form a carbocyclic ring containing 4 to 12 ring atoms,andn is an integer 0 or 1.
摘要:
A constrained-layer construction comprising a stiff layer or substrate and a layer of a viscoelastic polymer which is the reaction product of (a) 25 to 75 weight percent of an acryloyl or methacryloyl derivative of at least one oligomer, said oligomer having a glass transition temperature of less than 25.degree. C. and a molecular weight per oligomer of 600 to 20,000, and (b) 75 to 25 weight percent of a copolymerizable monomer whose homopolymer has a glass transition temperature of at least 50.degree. C., the copolymer being suitable for damping vibrations at relatively high temperatures, e.g., 50.degree.-150.degree. C., is disclosed. Also included is a process for damping vibrations in component parts of devices used in automotive, aerospace, and computer industries.
摘要:
A composition comprising a radiation-curable polymer, said polymer being crosslinkable and having pendant ethylenically unsaturated peptide groups is disclosed. Such polymers are useful in the field of graphic arts.
摘要:
Hydrophilic compositions are described, which are prepared from a first component oligomer containing pendent hydrophilic groups and pendent reactive functional groups capable of reaction at effective rates (at normal processing temperatures), with a co-reactive second component possessing functionality that is complementary to that of the first oligomer. The compositions may be used as in preparation of hydrophilic gel coatings or layers for medical devices.
摘要:
The present invention provides crosslinkable compositions useful in the preparation of hydrophilic gels, and are prepared from oligomers having pendent hydrophilic, poly(alkylene oxide) groups, pendent photoinitiator groups, and optionally polymerizable functional groups, and crosslinked by polyfunctional poly(alkylene oxides).
摘要:
Photoiniferters for controlled radical polymerizations are described. The photoiniferters have an azlactone or ring-opened azlactone moiety to provide telechelic (co)polymers.
摘要:
Photoiniferters for controlled radical polymerizations are described. The photoiniferters have an azlactone or ring-opened azlactone moiety to provide telechelic (co)polymers.
摘要:
Initiators for atom transfer radical polymerizations are described. The initiators have an azlactone or ring-opened azlactone moiety to provide telechelic (co)polymers.
摘要:
A process for preparing a polarizer is described whereby an article comprising an oriented, vinylalcohol polymer film layer, and an acid donor layer comprising a photoacid generator, is exposed to radiant energy at a temperature sufficient to effect a partial dehydration of the vinylalcohol polymer to a vinylalcohol/poly(acetylene) copolymer.