摘要:
A non-aqueous electrolyte secondary battery including: a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; a non-aqueous electrolyte; and a porous insulating film adhered to a surface of at least one selected from the group consisting of the positive electrode and the negative electrode, the porous insulating film including an inorganic oxide filler and a film binder, wherein the ratio R of actual volume to apparent volume of the separator is not less than 0.4 and not greater than 0.7, and wherein the ratio R and a porosity P of the porous insulating film satisfy the relational formula: −0.10≦R−P≦0.30.
摘要:
A method for producing lithium ion secondary batteries includes the steps of: (A) preparing an electrode sheet with lead-forming parts, (B) intermittently forming porous insulating layers containing an inorganic oxide filler and a binder on a surface of the electrode sheet excluding the lead-forming parts, (C) connecting a lead to each of the lead-forming parts, and (D) fabricating batteries by using the electrode sheet to which the leads are connected. The step B includes: the step of applying a slurry containing the inorganic oxide filler and the binder to the outer surface of a gravure roll, and transferring the slurry applied to the outer surface of the gravure roll on a surface of the electrode sheet that is being transported by a plurality of guide rolls excluding the lead-forming part; and the step of moving at least one selected from the gravure roll and the guide rolls to make the electrode sheet away from the gravure roll in the lead-forming part.
摘要:
A battery includes a flat wound electrode body formed by winding a positive electrode sheet and a negative electrode sheet with a separator interposed therebetween into a flat shape. The separator has an outer edge adjacent portion adjacent to either an outer edge of a positive electrode active material layer or an outer edge of a negative electrode active material layer. In a curve positioned portion disposed at least in a curved portion of the flat wound electrode body, the outer edge adjacent portion has a suppression portion for suppressing the occurrence or development of a crack.
摘要:
The nonaqueous electrolyte secondary battery of the present invention has a positive electrode, a negative electrode, a separator interposed between the positive electrode and the negative electrode, and a nonaqueous electrolyte solution. The battery further has a porous heat-resistant layer provided between the separator and at least one of the positive electrode and the negative electrode, wherein the porous heat-resistant layer includes an inorganic filler and a binder. The inorganic filler included in the porous heat-resistant layer has a particle size distribution with two peaks, which are a first peak (P1) at a relatively small particle diameter and a second peak (P2) at a relatively large particle diameter. When the particle diameter of the first peak (P1) is D1 be and the particle diameter of the second peak (P2) is D2 being, the peak particle diameter ratio D1/D2 satisfies the condition 0.2≦D1/D2≦0.7.
摘要:
A nonaqueous electrolyte secondary battery 100 according to this invention includes a positive electrode 10, a negative electrode 20, a separator 40 interposed between the positive electrode 10 and the negative electrode 20, and a nonaqueous electrolyte solution. A porous heat-resistant layer 42 is additionally provided between the separator 40 and at least one electrode from among the positive electrode 10 and the negative electrode 20. The porous heat-resistant layer 42 includes hollow particles 44 made of an inorganic material, and a binder 46.
摘要:
The lithium-ion secondary battery 100 includes: a positive electrode current collector 221; a positive electrode active material layer 223 held on the positive electrode current collector 221; a negative electrode current collector 241; and a negative electrode active material layer 243 that is held on the negative electrode current collector 241 and covers the positive electrode active material layer 223. A separator substrate 265 formed of a porous resin sheet is disposed between the positive electrode active material layer 223 and the negative electrode active material layer 243. The separator substrate 265 holds a heat-resistant layer 266. The heat-resistant layer 266 contains an inorganic filler, a binder and a thickener. The weight ratio P between the binder and the thickener (binder/thickener) in the heat-resistant layer is P
摘要:
A nonaqueous electrolyte lithium secondary battery obtained by the present invention has a separator and a porous layer which contains an inorganic filler and a binder and which is formed on the separator, wherein a thickness of the separator ranges from 12 μm to 18 μm, a porosity of the separator ranges from 52% to 67%, a thickness of the porous layer ranges from 3 μm to 15 μm, a porosity of the porous layer ranges from 44% to 70%, and the porous layer-attached separator exhibits a film resistance equal to or lower than 1.35 Ω·cm2 when impregnated with an electrolyte solution.
摘要:
The present invention relates to an improvement in a lithium ion secondary battery including a positive electrode, a negative electrode, a separator, a non-aqueous electrolyte, and a porous film formed on at least one electrode surface. The porous film includes inorganic compound particles and polyvinylidene fluoride. The viscosity of the N-methyl-2-pyrrolidone solution dissolving 8 wt % polyvinylidene fluoride is 600 to 2400 mPa·s at 25° C., and the amount of the polyvinylidene fluoride in the porous film is 1 to 10 parts by weight per 100 parts by weight of the inorganic compound particles.
摘要:
A non-aqueous electrolyte secondary battery including: a positive electrode; a negative electrode; a separator interposed between the positive electrode and the negative electrode; a non-aqueous electrolyte; and a porous insulating film adhered to a surface of at least one selected from the group consisting of the positive electrode and the negative electrode, the porous insulating film including an inorganic oxide filler and a film binder, wherein the ratio R of actual volume to apparent volume of the separator is not less than 0.4 and not greater than 0.7, and wherein the ratio R and a porosity P of the porous insulating film satisfy the relational formula: −0.10≦R−P≦0.30.
摘要:
A secondary battery includes: a positive electrode; a negative electrode; a porous electron-insulating layer adhered to a surface of at least one selected from the group consisting of the positive electrode and the negative electrode; and an electrolyte. The porous electron-insulating layer comprises a particulate filler and a resin binder, and the particulate filler comprises an indefinite-shape particle comprising a plurality of primary particles that are joined to one another. A neck is preferably formed between the primary particles. Since the porous electron-insulating layer has high porosity, it is possible to obtain a secondary battery that exhibits excellent low-temperature characteristics, which are particularly important in actual use, and that is capable of discharging at a large current.