Process for the production of graft polymers
    46.
    发明授权
    Process for the production of graft polymers 失效
    生产接枝聚合物的方法

    公开(公告)号:US4426499A

    公开(公告)日:1984-01-17

    申请号:US344486

    申请日:1982-02-01

    CPC分类号: C08F265/04 C08F279/02

    摘要: This invention relates to a process for the graft polymerization of (A) from 95 to 40 parts, by weight, of at least one ethylenically unsaturated monomer in the presence of (B) from 5 to 60 parts, by weight, of a partially or completely cross-linked rubber, in which the one or more than one monomer (A) and rubber (B) in the form of a latex or of a dispersion in an organic solvent are polymerized in an aliphatic hydrocarbon as reaction medium at from 30.degree. to 100.degree. C., using a radical forming initiator, and the graft polymerization product obtained as a sedimenting suspension of particles having an average diameter of from 5 to 1,000 .mu.m is isolated.

    摘要翻译: 本发明涉及一种在(B)5〜60重量份的(B)的部分或不饱和单体的存在下(A)95重量份至40重量份的至少一种烯属不饱和单体的接枝聚合方法 完全交联的橡胶,其中一种或多种胶乳形式的单体(A)和橡胶(B)或在有机溶剂中的分散体在脂肪族烃中作为反应介质在30℃下聚合 至100℃,使用自由基形成引发剂,分离得到作为平均直径为5〜1000μm的颗粒的沉降悬浮液得到的接枝聚合产物。

    ABS moulding compositions
    49.
    发明授权

    公开(公告)号:US4009226A

    公开(公告)日:1977-02-22

    申请号:US570350

    申请日:1975-04-22

    摘要: Moulding compositions containingA. 6 to 30 parts by weight of graft polymer obtained by grafting 20 to 60 parts by weight of a mixture of styrene and acrylonitrile in a ratio by weight of 95 : 5 to 60 : 40 onto 80 to 40 parts by weight of polybutadiene or a butadiene copolymer with a butadiene content of at least 30% with an average particle diameter of 0.26 to 0.65.mu. and a grafting degree of 0.15 to 0.7;B. 14 to 45 parts by weight of a graft polymer obtained by polymerizing 40 to 60 parts by weight of a mixture of styrene and acrylonitrile in a ratio by weight of 95 : 5 to 60 : 40 onto 60 to 40 parts by weight of polybutadiene or a butadiene copolymer with a butadiene content of at least 30%, with an average particle diameter of 0.05 to 0.25.mu. and a grafting degree of 0.4 to 0.9; andC. 25 to 80 parts by weight of a copolymer of styrene and/or .alpha.-methyl styrene on the one hand and acrylonitrile on the other hand in a ratio by weight of 80 : 20 to 60 : 40 and an average molecular weight (mean weight) M.sub.w of 50,000 to 200,000 and a molecular heterogeneity of U = 4.5 to 1.0.