Polycarbonates with end groups containing double bonds which can be
crosslinked by UV light
    41.
    发明授权
    Polycarbonates with end groups containing double bonds which can be crosslinked by UV light 失效
    具有端基的聚碳酸酯含有双键,其可以通过UV光交联

    公开(公告)号:US4221645A

    公开(公告)日:1980-09-09

    申请号:US50899

    申请日:1979-06-21

    摘要: High molecular weight aromatic polycarbonates having molecular weights M.sub.w (weight average) of between about 10,000 and 200,000, which are based on diphenols and monofunctional chain stoppers, which correspond to the general formula ##STR1## in which Z denotes the radical of a diphenol,n denotes an integer from 20 to 400,E denotes ##STR2## m is 0 or 1 and R denotes a hydrogen atom or a C.sub.1 to C.sub.3 alkyl group, and in which between about 0.5 and 5 mol % of Z are radicals of aromatic dihydroxyketones. These polycarbonates share mechanical and thermal properties with known polycarbonates but in addition are suitable for crosslinking, for example in the presence of photoinitiators and optionally photo-reducing agents and under irradiation with UV light. When crosslinked they are resistant to organic solvents and insensitive to stress-cracking, and have particularly good flame-repellent properties when additionally incorporating flameproofing agents.

    摘要翻译: 分子量Mw(重均分子量)在10,000和200,000之间的高分子量芳族聚碳酸酯,它们基于二酚和单官能链终止剂,其对应于通式(I),其中Z表示 二苯酚,n表示20〜400的整数,E表示m为0或1,R表示氢原子或C1〜C3烷基,其中约0.5〜5摩尔%的Z为 芳族二羟基酮。 这些聚碳酸酯与已知的聚碳酸酯共享机械和热性能,但另外适用于交联,例如在光引发剂和任选的光还原剂的存在下,并且在用UV光照射下。 当交联时,它们对有机溶剂具有耐受性并且对应力开裂不敏感,并且当额外加入防火剂时具有特别好的阻燃性能。

    Process for the production of aromatic carboxylic acid chlorides
    44.
    发明授权
    Process for the production of aromatic carboxylic acid chlorides 失效
    芳香族羧酸氯化物的制备方法

    公开(公告)号:US4382898A

    公开(公告)日:1983-05-10

    申请号:US312224

    申请日:1981-10-19

    CPC分类号: C07C51/60

    摘要: A single-stage process for the production of pure, particularly sulphur-free, aromatic carboxylic acid chlorides by reacting an aromatic carboxylic acid containing from 1 to 3 carboxyl groups or a corresponding mixture of aromatic carboxylic acids with thionyl chloride in the presence of a catalyst, wherein tertiary phosphine oxides or their reaction products with thionyl chloride and/or the acid chloride to be formed are used as catalysts, and the use of the aromatic dicarboxylic acid dichlorides and tricarboxylic acid trichlorides obtained for the production of polycondensates.

    摘要翻译: 通过在催化剂存在下使含有1至3个羧基的芳族羧酸或芳族羧酸的相应混合物与亚硫酰氯反应生产纯的,特别是无硫的芳族羧酸氯化物的单阶段方法 其中使用叔膦氧化物或其与亚硫酰氯和/或酰氯的反应产物作为催化剂,并且使用获得的芳族二羧酸二氯化物和三羧酸三氯化物来制备缩聚物。

    COMPOSITIONS COMPRISING POLYPHOSPHONATES AND ADDITIVES THAT EXHIBIT AN ADVANTAGEOUS COMBINATION OF PROPERTIES, AND METHODS RELATED THERETO
    46.
    发明申请
    COMPOSITIONS COMPRISING POLYPHOSPHONATES AND ADDITIVES THAT EXHIBIT AN ADVANTAGEOUS COMBINATION OF PROPERTIES, AND METHODS RELATED THERETO 审中-公开
    包含有优势组合的聚磷酸酯和添加剂的组合物及其相关方法

    公开(公告)号:US20120175573A1

    公开(公告)日:2012-07-12

    申请号:US13345539

    申请日:2012-01-06

    摘要: Disclosed are new compositions consisting of polyphosphonates and specific additive compositions that exhibit superior resistance to degradation due to exposure to air, high temperature and air, moisture or combinations thereof. Also disclosed are polymer mixtures or blends comprising these polyphosphonates/additive compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, fiber-reinforced articles, or any combination thereof.

    摘要翻译: 公开了由多聚膦酸盐和特定添加剂组合物组成的新组合物,其显示出优异的抗暴露于空气,高温和空气,水分或其组合的降解性。 还公开了包含这些聚膦酸盐/添加剂组合物的聚合物混合物或共混物以及由其制备的商品和工程塑料和制品。 进一步公开的是由这些材料制成的制品,例如纤维,薄膜,涂覆的基材,模制品,泡沫,纤维增强制品或其任何组合。

    Method for the production of block copolycarbonate/phosphonates and compositions therefrom
    48.
    发明授权
    Method for the production of block copolycarbonate/phosphonates and compositions therefrom 有权
    制备嵌段共聚碳酸酯/膦酸酯的方法及其组合物

    公开(公告)号:US07838604B2

    公开(公告)日:2010-11-23

    申请号:US11563941

    申请日:2006-11-28

    申请人: Dieter Freitag

    发明人: Dieter Freitag

    IPC分类号: C08G79/04 C08F283/02

    摘要: Disclosed is a new method and compositions from the method consisting of block copolycarbonate/phosphonates that exhibit an excellent combination of flame resistance, hydrolytic stability, high Tg, low melt viscosity, low color and high toughness. Also disclosed are polymer mixtures or blends comprised of these block copolycarbonate/phosphonate compositions and commodity and engineering plastics and articles produced therefrom. Further disclosed are articles of manufacture produced from these materials, such as fibers, films, coated substrates, moldings, foams, adhesives and fiber-reinforced articles, or any combination thereof.

    摘要翻译: 公开了一种新的方法和组合物,该方法和组合物由嵌段共聚碳酸酯/膦酸酯组成,其显示出阻燃性,水解稳定性,高Tg,低熔体粘度,低颜色和高韧性的优异组合。 还公开了由这些嵌段共聚碳酸酯/膦酸酯组合物和商品和工程塑料以及由其制备的制品组成的聚合物混合物或共混物。 进一步公开的是由这些材料制成的制品,例如纤维,薄膜,涂覆的基材,模制品,泡沫,粘合剂和纤维增强制品,或其任何组合。