Preparation of functionalized alkoxyamine initiator and its use
    41.
    发明授权
    Preparation of functionalized alkoxyamine initiator and its use 失效
    官能化烷氧基胺引发剂的制备及其用途

    公开(公告)号:US06686424B2

    公开(公告)日:2004-02-03

    申请号:US10464927

    申请日:2003-06-19

    IPC分类号: C08F400

    摘要: A one-pot process for the preparation of functional alkoxyamines of the general formula (I), is disclosed. The process entails (1) reacting an oxidizing agent with a sterically hindered secondary amine to produce an aqueous phase and a nitroxyl radical (2) removing the aqueous phase and adding to the nitroxyl radical one or more vinyl monomer(s) conforming to a formula and a system which produces free radicals. Also disclosed is a process of polymerizing monomers using the functional alkoxyamine.

    摘要翻译: 公开了用于制备通式(I)的官能烷氧基胺的一锅法。 该方法包括(1)使氧化剂与空间位阻仲胺反应以产生水相和硝酰基(2)除去水相,并向硝酰基加入一种或多种符合式 以及产生自由基的系统。 还公开了使用官能烷氧基胺聚合单体的方法。

    Super-absorbent polymers
    44.
    发明授权
    Super-absorbent polymers 失效
    超吸收性聚合物

    公开(公告)号:US5496890A

    公开(公告)日:1996-03-05

    申请号:US391506

    申请日:1995-02-21

    CPC分类号: C08F8/44

    摘要: A process for the production of super-absorbent polymers with a swelling capacity in water-containing liquids of up to 1,000 g/g in which aqueous emulsions of particularly high molecular weight polymers of acrylonitrile are partly hydrolyzed by reaction with aqueous solutions of alkali metal and/or alkaline earth metal hydroxides, the polymers are precipitated in powder form by addition of water-miscible organic solvents, separated off, dried and then optionally heated for a short time. The super-absorbent polymers are used as water-storing materials, for example in sanitary articles, in agriculture or in the sheathing of electrical cables.

    摘要翻译: 一种生产具有高达1,000g / g的含水液体的溶胀能力的超吸收性聚合物的方法,其中丙烯腈特别高分子量聚合物的水性乳液通过与碱金属的水溶液反应而部分水解, /或碱土金属氢氧化物,通过加入水混溶性有机溶剂将聚合物粉末形式沉淀,分离出来,干燥,然后任选地加热短时间。 超吸收聚合物用作储水材料,例如卫生用品,农业或电缆护套中。

    Branched (co)polyamide by polycondensation in the presence of lysine
component polycarboxylic acid mixture
    48.
    发明授权
    Branched (co)polyamide by polycondensation in the presence of lysine component polycarboxylic acid mixture 失效
    在赖氨酸组分多元羧酸混合物存在下,通过缩聚进行支化(共)聚酰胺

    公开(公告)号:US5028689A

    公开(公告)日:1991-07-02

    申请号:US402617

    申请日:1989-09-05

    CPC分类号: C08G69/16 C08G69/20 C08G69/28

    摘要: This invention relates to thermoplastically mouldable slightly branched aliphatic (co)polyamides of high molecular weight with increased melt viscosities and a marked structural viscosity prepared by accelerated polycondensation of suitable monomer melts in the presence of small quantities of lysine components and approximately equivalent quantities of a polycarboxylic acid optionally followed by a thermal after-condensation reaction, and to a process for the polycondensation. The lysine components used are lysine, lysine hydrate, esters of lysine with low alcohols or lysine hydrochlorides (the latter in the presence of approximately equivalent quantities of bases added at the same time to bind the HCl).

    摘要翻译: 本发明涉及具有增加的熔体粘度和通过在少量赖氨酸组分和大约相当量的多元羧酸的存在下合适的单体熔体的加速缩聚制备的显着的结构粘度的高分子量的热塑性可塑轻微支化的脂族(共)聚酰胺 酸,随后进行热后冷凝反应,以及缩聚方法。 使用的赖氨酸成分是赖氨酸,赖氨酸水合物,赖氨酸与低级醇或赖氨酸盐酸盐的酯(后者在大约等量的碱的存在下同时加入以结合HCl)。