Thermochromic dye compositions and method for preparing same

    公开(公告)号:US11524515B2

    公开(公告)日:2022-12-13

    申请号:US16376261

    申请日:2019-04-05

    申请人: Xerox Corporation

    摘要: A thermochromic composition including a dye molecule; a matrix, wherein the matrix comprises a material having a defined melting point; and an optional developer. A process for preparing a thermochromic composition, including providing a dye; heating a matrix above its melting point; adding the heated matrix to the dye until the dye dissolves in the matrix; optionally, adding a developer; wherein the thermochromic composition exhibits a first color at a first temperature and a second color at a second temperature; wherein the first color and the second color are different; and wherein the first temperature and the second temperature are different.

    Thermochromic Dye Compositions And Method For Preparing Same

    公开(公告)号:US20200316975A1

    公开(公告)日:2020-10-08

    申请号:US16376261

    申请日:2019-04-05

    申请人: Xerox Corporation

    IPC分类号: B41M5/28 C09B11/06 C09B11/08

    摘要: A thermochromic composition including a dye molecule; a matrix, wherein the matrix comprises a material having a defined melting point; and an optional developer. A process for preparing a thermochromic composition, including providing a dye; heating a matrix above its melting point; adding the heated matrix to the dye until the dye dissolves in the matrix; optionally, adding a developer; wherein the thermochromic composition exhibits a first color at a first temperature and a second color at a second temperature; wherein the first color and the second color are different; and wherein the first temperature and the second temperature are different.

    Super low melt toner having small molecule plasticizers
    46.
    发明授权
    Super low melt toner having small molecule plasticizers 有权
    具有小分子增塑剂的超低熔点调色剂

    公开(公告)号:US09069272B2

    公开(公告)日:2015-06-30

    申请号:US14077024

    申请日:2013-11-11

    申请人: XEROX CORPORATION

    IPC分类号: G03G9/097 G03G9/08 G03G9/087

    摘要: An emulsion aggregation (EA) toner includes an amorphous polymeric resin, optionally a colorant, and a small molecule crystalline organic compound having molecular weight less than 1,000 g/mol and melting point less than the fusing temperature of the EA toner, wherein a mixture of the resin and the small molecule compound is characterized by a reduction in glass transition temperature from that of the resin and by the lack of a significant solid to liquid phase transition peak for the small molecule compound as determined by differential scanning calorimetry, the enthalpy of fusion for the small molecule compound in the mixture being measured to be less than 10% of the enthalpy of fusion of the compound in pure form. Furthermore, the EA toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner.

    摘要翻译: 乳液聚集(EA)调色剂包括无定形聚合物树脂,任选的着色剂和分子量小于1,000g / mol且熔点低于EA调色剂的熔融温度的小分子结晶有机化合物,其中混合物 树脂和小分子化合物的特征在于玻璃化转变温度从树脂的降低以及通过差示扫描量热法测定的小分子化合物的显着固体与液相转变峰的缺乏,熔融焓 因为被测量的混合物中的小分子化合物的含量小于纯化合物的熔融焓的10%。 此外,EA调色剂可以被配置为具有小于或等于基准超低熔点乳液聚集调色剂的折痕固定MFT的折痕固定最小定影温度(MFT)。

    Super low melt toner having crystalline imides
    47.
    发明授权
    Super low melt toner having crystalline imides 有权
    具有结晶酰亚胺的超低熔点调色剂

    公开(公告)号:US09034546B1

    公开(公告)日:2015-05-19

    申请号:US14076712

    申请日:2013-11-11

    申请人: Xerox Corporation

    IPC分类号: G03G9/08 G03G9/097

    摘要: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline imide having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline imide may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline imide as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline imide in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline imide in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline imides may include N-alkyl and N-aryl imides, such as N-benzylphthalimide.

    摘要翻译: 调色剂包括聚合物树脂,任选的着色剂和分子量小于1,000g / mol的小分子结晶酰亚胺。 聚合物树脂可以是无定形树脂,并且无定形树脂和结晶酰亚胺的混合物的特征在于玻璃化转变温度从树脂的温度降低,并且结晶酰亚胺的熔点缺乏由差分测定 扫描量热法测定混合物中结晶酰亚胺的熔融焓低于纯形式的结晶酰亚胺熔融焓的10%。 此外,调色剂可以被配置为具有小于或等于基准超低熔点乳液聚集调色剂的折痕固定MFT的折痕固定最小定影温度(MFT)。 合适的结晶酰亚胺可以包括N-烷基和N-芳基酰亚胺,例如N-苄基邻苯二甲酰亚胺。

    SUPER LOW MELT TONER HAVING CRYSTALLINE IMIDES
    48.
    发明申请
    SUPER LOW MELT TONER HAVING CRYSTALLINE IMIDES 有权
    超低熔体熔体具有晶体管

    公开(公告)号:US20150132692A1

    公开(公告)日:2015-05-14

    申请号:US14076712

    申请日:2013-11-11

    申请人: XEROX CORPORATION

    IPC分类号: G03G9/08

    摘要: A toner includes a polymeric resin, optionally a colorant, and a small molecule crystalline imide having a molecular weight less than 1,000 g/mol. The polymeric resin may be an amorphous resin and a mixture of the amorphous resin and the crystalline imide may be characterized by a reduction in glass transition temperature from that of the resin and by the lack of a melting point for the crystalline imide as determined by differential scanning calorimetry, the enthalpy of fusion for the crystalline imide in the mixture being measured to be less than 10% of the enthalpy of fusion of the crystalline imide in pure form. Furthermore, the toner may be configured to have a crease fix minimum fusing temperature (MFT) less than or equal to the crease fix MFT of a benchmark ultra-low-melt emulsion aggregation toner. Suitable crystalline imides may include N-alkyl and N-aryl imides, such as N-benzylphthalimide.

    摘要翻译: 调色剂包括聚合物树脂,任选的着色剂和分子量小于1,000g / mol的小分子结晶酰亚胺。 聚合物树脂可以是无定形树脂,并且无定形树脂和结晶酰亚胺的混合物的特征在于玻璃化转变温度从树脂的温度降低,并且结晶酰亚胺的熔点缺乏由差分测定 扫描量热法测定混合物中结晶酰亚胺的熔融焓低于纯形式的结晶酰亚胺熔融焓的10%。 此外,调色剂可以被配置为具有小于或等于基准超低熔点乳液聚集调色剂的折痕固定MFT的折痕固定最小定影温度(MFT)。 合适的结晶酰亚胺可以包括N-烷基和N-芳基酰亚胺,例如N-苄基邻苯二甲酰亚胺。

    Phase change inks containing oligomeric rosin esters
    50.
    发明授权
    Phase change inks containing oligomeric rosin esters 有权
    相变油墨含有低聚松香酯

    公开(公告)号:US08778069B2

    公开(公告)日:2014-07-15

    申请号:US13680271

    申请日:2012-11-19

    申请人: Xerox Corporation

    IPC分类号: C09D11/02

    CPC分类号: C09D11/34 C09D11/102

    摘要: Disclosed is a phase change ink comprising an ink carrier which comprises a crystalline component and an amorphous rosin ester. In specific embodiments, the crystalline component can be a trans-cinnamic diester, a diester of tartaric acid, or a diurethane. In specific embodiments, the ink exhibits a peak melting point of no more than about 150° C., an onset crystallization temperature of no less than about 60° C., a melt viscosity within the temperature range of from about 100° C. to about 130° C. of from about 5 cps to about 22 cps, a peak solidification viscosity at about 50° C. of no less than about 1×106 cps, and a hardness at about 25° C. of at least about 70.

    摘要翻译: 公开了一种相变油墨,其包含含有结晶成分和无定形松香酯的油墨载体。 在具体实施方案中,结晶成分可以是反式肉桂酸二酯,酒石酸二酯或二氨基甲酸酯。 在具体实施方案中,油墨的峰值熔点不超过约150℃,起始结晶温度不低于约60℃,熔体粘度在约100℃至 约130℃,约5cps至约22cps,约50℃下的峰值固化粘度为不小于约1×10 6 cps,硬度约25℃至少约70。